Solution composition and method for single-bath post treatment of substrate
US-2018274119-A1 · Sep 27, 2018 · US
US11939693B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11939693-B2 |
| Application number | US-202117352059-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 18, 2021 |
| Priority date | Jan 26, 2015 |
| Publication date | Mar 26, 2024 |
| Grant date | Mar 26, 2024 |
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There is provided a surface-treated steel sheet ( 1 ) comprising: a tin-plated steel sheet ( 10 ) obtained by tin-plating a steel sheet ( 11 ); a phosphate compound layer ( 20 ) containing tin phosphate formed on the tin-plated steel sheet ( 10 ); and an aluminum-oxygen compound layer ( 30 ) on the phosphate compound layer ( 20 ), a main constituent of the aluminum-oxygen compound layer ( 30 ) being an aluminum-oxygen compound; wherein, when the 3d 5/2 spectrum of tin in the aluminum-oxygen compound layer ( 30 ) is determined using an X-ray photoelectron spectroscopy, the ratio of the integration value of the profile derived from tin oxide to the integration value of the profile derived from tin phosphate (tin oxide/tin phosphate) is 6.9 or more.
Opening claim text (preview).
The invention claimed is: 1. A method for producing a surface-treated steel sheet comprising: forming a phosphate compound layer on a tin-plated steel sheet by means of cathode electrolytic treatment, wherein the tin-plated steel sheet is obtained by tin-plating a steel sheet; and forming an aluminum-oxygen compound layer on the phosphate compound layer by means of electrolytic treatment using an electrolytic treatment liquid containing aluminum, wherein the electrolytic treatment liquid has a phosphate content of 0.11 g/L or less in terms of phosphorus atom and an aluminum ion content of 1 to 10 g/L in terms of aluminum atom, the electrolytic treatment for forming the aluminum-oxygen compound layer is performed by an intermittent electrolysis method where a cycle of energization and stop of energization is repeated, and a total energization time for forming the aluminum-oxygen compound layer is 1.5 seconds or less. 2. The method for producing a surface-treated steel sheet according to claim 1 , wherein the phosphate compound layer is formed on the tin-plated steel sheet by means of the cathode electrolytic treatment after anode electrolytic treatment is conducted. 3. The method for producing a surface-treated steel sheet according to claim 1 , wherein the phosphate compound layer is formed by immersing the tin-plated steel sheet in a treatment liquid containing phosphate ions to generate divalent tin ions from dissolved tin of the tin-plated steel sheet, and performing the cathode electrolytic treatment so that the divalent tin ions react with the phosphate ions so as to be deposited on the tin-plated steel sheet as tin phosphate.
on light metals · CPC title
Layered products comprising a {layer of a} particular substance not covered by groups B32B11/00 - B32B29/00 · CPC title
comprising metal as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a bituminous or tarry layer B32B11/08; next to a water-setting substance layer B32B13/06; next to a glass layer B32B17/061; next to a cellulosic plastic layer B32B23/042)} · CPC title
of metal (B32B15/01 takes precedence) · CPC title
of synthetic resin · CPC title
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