Lithium secondary battery

Patent metadata

Field	Value
Publication number	US-11936041-B2
Application number	US-201715841708-A
Country	US
Kind code	B2
Filing date	Dec 14, 2017
Priority date	Dec 16, 2016
Publication date	Mar 19, 2024
Grant date	Mar 19, 2024

Abstract

A lithium secondary battery includes a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle, an anode and a separator interposed between the cathode and the anode. The first cathode active material particle includes a lithium metal oxide including a continuous concentration gradient in at least one region between a central portion and a surface portion. The second cathode active material particle includes a lithium metal oxide including elements the same as those of the first cathode active material particle, and the second cathode active material particle has a uniform composition from a central portion to a surface.

First claim

What is claimed is:

1. A lithium secondary battery, comprising:
a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle;
an anode; and
a separator interposed between the cathode and the anode,
wherein the first cathode active material particle includes a lithium metal oxide including nickel (Ni), manganese (Mn) and cobalt (Co), and the first cathode active material particle includes a continuous concentration gradient layer in at least one region between a central portion and a surface portion,
wherein the second cathode active material particle includes a lithium metal oxide including nickel (Ni), manganese (Mn) and cobalt (Co), and each of Ni, Mn and Co in the second cathode active material particle has a uniform composition from a central portion to a surface,
wherein a nickel concentration or a nickel molar ratio at every point of the first cathode active material particle is 0.77 to 0.83,
wherein a nickel concentration or a nickel molar ratio at every point of the first cathode active material particle is higher than that of the second cathode active material particle,
wherein a cobalt concentration or a cobalt molar ratio at every point of the first cathode active material particle is 0.07 to 0.13,
wherein a manganese concentration or a manganese molar ratio at every point of the first cathode active material particle is 0.07 to 0.121,
wherein the concentration gradient layer of the first cathode active material particle includes a continuous concentration gradient,
wherein the central portion has a constant concentration composition, and the central portion and the surface portion have different concentration compositions from each other through the concentration gradient layer,
wherein the surface portion includes a constant concentration region,
wherein in the first cathode active material particle, Ni has a continuously decreasing concentration in a direction from the central portion to the surface portion in the concentration gradient layer,
wherein in the first cathode active material particle, Co has a constant concentration from the central portion to the surface portion, and Mn has a continuously increasing concentration in a direction from the central portion to the surface portion in the concentration gradient layer,
wherein an average diameter (D 50 ) of the first cathode active material particle is in a range from 3 μm to 15 μm,
wherein an average diameter (D 50 ) of the second cathode active material particle is in a range from 7 μm to 15 μm, and
wherein a blending weight ratio of the first cathode active material particle and the second cathode active material particle is in a range from 4:6 to 1:9.

2. The lithium secondary battery according to claim 1 , wherein the first cathode active material particle is represented by the following Chemical Formula 1:
Li x M1 a M2 b M3 c O y   [Chemical Formula 1]

wherein, in the Chemical Formula 1 above, M1, M2 and M3 each represents Ni, Mn and Co, respectively, and
0<x≤1.1, 2≤y≤2.02, 0.77≤a≤0.83 and 0.17≤b+c≤0.23.

3. The lithium secondary battery according to claim 1 , wherein the first cathode active material particle has the continuous concentration gradient throughout an entire region from the central portion to a surface thereof.

4. The lithium secondary battery according to claim 1 , wherein a concentration or a molar ratio of Ni is greater than that of each Mn and Co in the first cathode active material particle and the second cathode active material particle.

5. The lithium secondary battery according to claim 4 , wherein a concentration or a molar ratio of Mn and a concentration or a molar ratio of Co are the same in the first cathode active material particle, and a concentration or a molar ratio of Mn and a concentration or a molar ratio of Co are the same in the second cathode active material particle.

6. The lithium secondary battery according to claim 4 , wherein the concentration or the molar ratio of Ni is greater than a sum of concentrations or molar ratios of Mn and Co in the first cathode active material particle and the second cathode active material particle.

7. The lithium secondary battery according to claim 1 , wherein the second cathode active material particle is represented by the following Chemical Formula 2:
Li x M1′ a M2′ b M3′ c CO y   [Chemical Formula 2]

wherein, in the Chemical Formula 2 above, M1′, M2′ and M3′ are Ni, Mn and Co, respectively, and
0<x≤1.1, 2≤y≤2.02, 0.58≤a≤0.62, 0.18≤b≤0.22 and 0.18≤c≤0.22.

8. The lithium secondary battery according to claim 7 , wherein 0.59≤a≤0.61, 0.19≤b≤0.21 and 0.19≤c≤0.21 in the Chemical Formula 2.

9. The lithium secondary battery according to claim 1 , wherein the first cathode active material particle or the second cathode active material particle further includes a dopant or a coating that contains Al, Ti, Ba, Zr, Si, B, Mg or P.

10. The lithium secondary battery according to claim 1 , wherein the first cathode active material particle includes a primary particle having a rod-type shape.

11. A lithium secondary battery, comprising:
a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle;
an anode; and
a separator interposed between the cathode and the anode,
wherein the first cathode active material particle includes a lithium metal oxide including nickel (Ni), manganese (Mn) and cobalt (Co), and the first cathode active material particle includes a continuous concentration gradient layer in at least one region between a central portion and a surface portion,
wherein the second cathode active material particle includes a lithium metal oxide including nickel (Ni), manganese (Mn) and cobalt (Co), and each of Ni, Mn and Co in the second cathode active material particle has a uniform composition from a central portion to a surface,
wherein a nickel concentration or a nickel molar ratio at every point of the first cathode active material particle is 0.77 to 0.83,
wherein a nickel concentration or a nickel molar ratio at every point of the first cathode active material particle is higher than that of the second cathode active material particle,
wherein a cobalt concentration or a cobalt molar ratio at every point of the first cathode active material particle is 0.07 to 0.13,
wherein a manganese concentration or a manganese molar ratio at every point of the first cathode active material particle is 0.07 to 0.121,
wherein the concentration gradient layer of the first cathode active material particle includes a continuous concentration gradient,
wherein the central portion has a constant concentration composition, and the central portion and the surface portion have different concentration compositions from each other through the concentration gradient layer,
wherein the surface portion includes a constant concentration region,
wherein in the first cathode active material particle, Ni has a continuously decreasing concentration in a direction from the central portion to the surface portion in the concentration gradient layer,
wherein in the first cathode active material particle, Co has a constant concentration from the central portion to the surface portion, and Mn has a continuously increasing concentration in a direction from the central portion to the surface portion in the concentration gradient layer,
wherein an average diameter (D 50 ) of the first cathode active material particle is in a range from 3 μm to 15 μm,
wherein an average diameter (D 50 ) of the second cathode active material particle is 3 μm or more and less than 7 μm, and
whe

Assignees

• Sk Innovation Co Ltd
• Sk On Co Ltd

Inventors

• Han Kook Hyun
• Yoo Kyung Bin
• Hwang Duck Chul

Classifications

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/362

  Composites · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M10/052

  Li-accumulators · CPC title