Powder and solid alkaline cleaning compositions and use thereof for removing greasy soils

Patent metadata

Field	Value
Publication number	US-11920112-B2
Application number	US-202217819045-A
Country	US
Kind code	B2
Filing date	Aug 11, 2022
Priority date	Jun 26, 2018
Publication date	Mar 5, 2024
Grant date	Mar 5, 2024

Abstract

Powder and cast solid alkaline cleaning compositions are disclosed. Powders and/or solidification of a highly alkaline detergent composition are provided including sodium hydroxide beads and/or liquid and sodium carbonate in combination with water conditioning polymers. Methods of cleaning for soil removal of baked on, greasy soils, including those found in ovens, are also disclosed.

First claim

What is claimed is:

1. A powder alkaline cleaning composition comprising:
an alkali metal hydroxide alkalinity source;
from about 20 wt-% to 35 wt-% of an alkali metal carbonate alkalinity source;
a first polycarboxylic acid polymer or salt or derivative thereof comprising a phosphorus end group according to the formula:

wherein R 1 is a phosphino (—PH(═O)(OH)) or phosphono (—P(═O)(OH) 2 ) end group, wherein m is an integer of 0 or larger, and wherein n is an integer of 2 or larger;
a second polycarboxylic acid polymer or salt or derivative thereof without a phosphorus end group and comprising a polyacrylic acid polymer and having a molecular weight of between about 2,500 g/mol and about 5,000 g/mol; and
a processing aid comprising an organic solvent,
wherein the composition is a free-flowing powder that does not clump and wherein the composition does not contain surfactants.

2. The powder composition of claim 1 , wherein the alkali metal hydroxide comprises sodium hydroxide, and wherein the alkali metal carbonate comprises sodium carbonate.

3. The powder composition of claim 2 , wherein the alkali metal hydroxide alkalinity source is a solid source.

4. The powder composition of claim 1 , wherein the processing aid is propylene glycol.

5. The powder composition of claim 1 , wherein the composition is free of phosphonates.

6. The powder composition of claim 1 , wherein the composition comprises between about 40 wt-% and about 70 wt-% of the alkali metal hydroxide alkalinity source.

7. The powder composition of claim 1 , further comprising at least one additional functional ingredient that is an additional alkalinity source, detergent builder, chelant, corrosion inhibitor, water conditioning agent, flow aid or combinations thereof.

8. The powder composition of claim 1 , wherein the composition excludes additional functional ingredients.

9. The powder composition of claim 1 , wherein the composition comprises between about 20 wt-% and about 30 wt-% of the alkali metal carbonate alkalinity source.

10. The powder composition of claim 1 , Wherein the composition comprises between about 5 wt-% and about 20 wt-% of the first polycarboxylic acid polymer or salt or derivative thereof.

11. The powder composition of claim 1 , wherein the composition comprises between about 0.1 wt-% and about 5 wt-% of the processing aid.

12. An alkaline cleaning composition comprising:
from about 20 wt-% to 35 wt-% of at least one alkali metal carbonate alkalinity source;
a first polycarboxylic acid polymer or salt or derivative thereof comprising a phosphorus end group according to the formula:

wherein R 1 is a phosphino (—PH(═O)(OH)) or phosphono (—P(═O)(OH) 2 ) end group, wherein m is an integer of 0 or larger, and wherein n is an integer of 2 or larger;
a second polycarboxylic acid polymer or salt or derivative thereof without a phosphorus end group and comprising a polyacrylic acid polymer and having a molecular weight of between about 2,500 g/mol and about 5,000 g/mol; and
a processing aid and wherein the composition does not contain surfactants.

13. The composition of claim 12 , wherein the composition comprises between about 20 wt-% and about 30 wt-% of the alkali metal carbonate alkalinity source, and between about 10 wt-% and about 40 wt-% of the first polycarboxylic acid polymer or salt or derivative thereof.

14. The composition of claim 12 , wherein the composition is phosphate free.

15. The composition of claim 12 , wherein the solid composition if heated at a temperature of 120° F. is dimensionally stable and has a growth exponent of less than 3%.

16. The composition of claim 12 , wherein the composition excludes additional functional ingredients.

17. A method of cleaning comprising:
contacting a hard surface in need of cleaning with a use solution of the solid cleaning compositions of claim 1 ; and
removing soils from the surface,
wherein the solid cleaning composition provides at least equivalent cleaning performance to a highly alkaline liquid cleaning composition.

18. The method of claim 17 , wherein the contacting is for a period of at least 2 hours.

19. The method of claim 17 , wherein the soils removed include greasy and/or fatty soils.

20. The method of claim 17 , wherein the method does not require use of a dispenser to provide the solid cleaning composition to the hard surface.

Assignees

• Ecolab Usa Inc

Inventors

• Hammel Devon Beau
• Rapp Grace Marie

Classifications

• C11D7/265 Primary

  Carboxylic acids or salts thereof · CPC title

• B08B3/08

  the liquid having chemical or dissolving effect · CPC title

• C11D7/06

  Hydroxides · CPC title

• C11D11/0023

  Chemistry & Metallurgy · mapped topic

• C11D17/0008

  aqueous liquid non soap compositions (C11D3/0015, C11D3/3947, C11D3/3956 take precedence) · CPC title