Powder and solid alkaline cleaning compositions and use thereof for removing greasy soils

Patent metadata

Field	Value
Publication number	US-11441107-B2
Application number	US-201916451790-A
Country	US
Kind code	B2
Filing date	Jun 25, 2019
Priority date	Jun 26, 2018
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

Powder and cast solid alkaline cleaning compositions are disclosed. Powders and/or solidification of a highly alkaline detergent composition are provided including sodium hydroxide beads and/or liquid and sodium carbonate in combination with water conditioning polymers. Methods of cleaning for soil removal of baked on, greasy soils, including those found in ovens, are also disclosed.

First claim

What is claimed is:

1. A solid alkaline cleaning composition comprising:
at least one alkali metal hydroxide alkalinity source;
a first polycarboxylic acid polymer or salt or derivative thereof comprising a phosphorus end group according to the formula:

wherein R 1 is a phosphino (—PH(═O)(OH)) or phosphono (—P(═O)(OH) 2 ) end group, wherein m is an integer of 0 or larger, and wherein n is an integer of 2 or larger;
a second polycarboxylic acid polymer or salt or derivative thereof without a phosphorus end group and comprising a polyacrylic acid polymer and having a molecular weight of between about 2,500 g/mol and about 5,000 g/mol; and
from about 0.1 wt-% to about 5 wt-% of a processing aid comprising a propylene glycol and/or a hexylene glycol;
wherein the solid composition is free of sodium carbonate and surfactants.

2. The solid composition of claim 1 , wherein the alkali metal hydroxide comprises sodium hydroxide.

3. The solid composition of claim 1 , comprising two alkali metal hydroxide alkalinity sources.

4. The solid composition of claim 3 , wherein the first alkali metal hydroxide alkalinity source is a liquid and the second alkali metal hydroxide alkalinity source is a solid.

5. The solid composition of claim 4 , wherein the ratio of the first liquid alkali metal hydroxide alkalinity source to the second solid alkali metal hydroxide alkalinity source is from about 1:2 to about 1:6.

6. The solid composition of claim 1 , wherein the composition comprises between about 60 wt-% and about 95 wt-% of the alkali metal hydroxide alkalinity source, optionally between about 5 wt-% and about 20 wt-% of a first liquid alkali metal hydroxide alkalinity source and between about 40 wt-% and about 90 wt-% of a second solid alkali metal hydroxide alkalinity source, and between about 10 wt-% and about 40 wt-% of the first and second polycarboxylic acid polymers or salts or derivatives thereof.

7. The solid composition of claim 1 , wherein the solid composition at a temperature of 120° F. is dimensionally stable and has a growth exponent of less than 3%.

8. The solid composition of claim 1 , wherein the composition excludes additional functional ingredients.

9. A method of cleaning comprising:
contacting a hard surface in need of cleaning with a use solution of the solid cleaning composition of claim 1 ; and
removing soils from the surface,
wherein the solid cleaning composition provides at least equivalent cleaning performance to a highly alkaline liquid cleaning composition.

10. The method of claim 9 , wherein the contacting is for a period of at least 2 hours.

11. The method of claim 9 , wherein the soils removed include greasy and/or fatty soils.

12. The method of claim 9 , wherein the method does not require use of a dispenser to provide the solid cleaning composition to the hard surface.

Assignees

• Ecolab Usa Inc

Inventors

• Hammel Devon Beau
• Rapp Grace Marie

Classifications

• C11D17/06

  Powder; Flakes; Free-flowing mixtures; Sheets · CPC title

• C11D17/0008

  aqueous liquid non soap compositions (C11D3/0015, C11D3/3947, C11D3/3956 take precedence) · CPC title

• C11D3/044

  Hydroxides or bases · CPC title

• C11D7/265 Primary

  Carboxylic acids or salts thereof · CPC title

• C11D7/06

  Hydroxides · CPC title