Cathode for metal-air battery, preparing method thereof, and metal-air battery comprising the same

Patent metadata

Field	Value
Publication number	US-11909028-B2
Application number	US-202016852677-A
Country	US
Kind code	B2
Filing date	Apr 20, 2020
Priority date	Oct 23, 2019
Publication date	Feb 20, 2024
Grant date	Feb 20, 2024

Abstract

A cathode for a metal-air battery, the cathode including a mixed conductor; and first pores having a size of about 1 micrometer (μm) or greater, wherein an amount of the first pores is about 30 volume percent (volume %) or greater, with respect to a total volume of pores in the cathode, and a total porosity of the cathode is about 50% or greater, based on a total volume of the cathode.

First claim

What is claimed is:

1. A cathode for a metal-air battery, the cathode comprising:
a mixed conductor; and
first pores having a size of about 1 micrometer or greater,
wherein an amount of the first pores is about 30 volume percent to about 95 volume percent, with respect to a total volume of pores in the cathode, and
a total porosity of the cathode is about 70 percent to about 95 percent, based on a total volume of the cathode,
wherein the mixed conductor is a perovskite compound represented by Formula 5:
Li x Al y G1 z O 3−δ   Formula 5

wherein, in Formula 5,
A1 is at least one of La, Ce, Pr, Gd, Ca, Sr, or Ba,
G1 is at least one of Mn, Ru, Cr, Co, Ir, Fe, Pd, Pb, Rh, Sn, V, Re, Ge, W, Mo, Hf, or Bi, and
0.2<x≤0.5, 0.4<y≤0.6, 0<x+y<1, 0.8<z≤1.2, and 0≤δ≤0.4.

2. The cathode of claim 1 , wherein the mixed conductor has an electronic conductivity of about 1×10 −6 Siemens per centimeter or greater.

3. The cathode of claim 1 , wherein the mixed conductor has an ionic conductivity of about 1×10 −8 Siemens per centimeter or greater.

4. The cathode of claim 1 , wherein the mixed conductor has a particle size of about 10 nanometers to about 500 nanometers.

5. The cathode of claim 1 , wherein the size of the first pores is about 1 micrometer to about 100 micrometers.

6. The cathode of claim 1 , wherein the cathode has a thickness of about 5 micrometers to about 100 micrometers.

7. The cathode of claim 1 , wherein
G1 is Ru, and
δ is oxygen vacancy.

8. The cathode of claim 1 , wherein the mixed conductor is Li 0.34 La 0.55 RuO 3 .

9. The cathode of claim 1 , wherein the mixed conductor has an oxidation potential that is greater than an oxidation potential of carbon and a reduction potential that is less than a reduction potential of carbon.

10. The cathode of claim 1 , wherein the mixed conductor has a stability to being decomposed by an electrochemical reaction that is greater than a stability of carbon to being decomposed by an electrochemical reaction.

11. A metal-air battery comprising:
the cathode according to claim 1 ;
an anode; and
an electrolyte disposed between the cathode and the anode.

12. The metal-air battery of claim 11 , wherein the electrolyte comprises a solid electrolyte.

13. The metal-air battery of claim 11 , wherein the anode comprises at least one of lithium, magnesium, iron, aluminum, or zinc, or an alloy thereof.

14. A method of manufacturing the cathode for a metal-air battery of claim 1 , the method comprising:
mixing the mixed conductor, organic particles having a size of about 1 micrometer or greater, and a solvent to prepare a composition;
coating the composition on a substrate to provide a coated substrate; and then
thermally treating the coated substrate to manufacture the cathode.

15. The method of claim 14 , wherein the composition further comprises a binder.

16. The method of claim 14 , wherein the thermally treating comprises thermally treating at a temperature of 450° C. to 800° C.

17. The method of claim 14 , wherein an amount of the organic particles is about 5 parts by weight to about 60 parts by weight, with respect to 100 parts by weight of the mixed conductor.

18. A cathode for a metal-air battery, the cathode consisting of:
a mixed conductor; and
first pores having a size of about 1 micrometer or greater,
wherein an amount of the first pores is about 30 volume percent or greater, with respect to a total volume of pores in the cathode, and
a total porosity of the cathode is about 50 percent or greater, based on a total volume of the cathode,
wherein the mixed conductor is a perovskite compound represented by Formula 5:
Li x Al y G1 z O 3−δ   Formula 5

wherein, in Formula 5,
A1 is at least one of La, Ce, Pr, Gd, Ca, Sr, or Ba,
G1 is at least one of Mn, Ru, Cr, Co, Ir, Fe, Pd, Pb, Rh, Sn, V, Re, Ge, W, Mo, Hf, or Bi, and 0.2<x≤0.5, 0.4<y≤0.6, 0<x+y<1, 0.8<z≤1.2, and 0≤δ≤0.4.

19. A cathode for a metal-air battery, the cathode comprising:
a mixed conductor; and
first pores having a size of about 1 micrometer or greater,
wherein an amount of the first pores is about 30 volume percent to about 95 volume percent, with respect to a total volume of pores in the cathode, and
a total porosity of the cathode is about 70 percent to about 95 percent, based on a total volume of the cathode,
wherein the mixed conductor is a perovskite compound represented by Formula 5:
LixAlyG1zO3−δ  Formula 5

wherein, in Formula 5,
Al is at least one of La, Ce, Pr, Gd, Ca, Sr, or Ba,
G1 is at least one of Mn, Ru, Cr, Co, Ir, Fe, Pd, Pb, Rh, Sn, V, Re, Ge, W, Mo, Hf, or Bi, and 0.2<x≤0.5, 0.4<y≤0.7, 0<x+y<1, 0.8<z≤1.2, and 0≤δ≤1, and
wherein the cathode comprises about 70 parts to about 100 parts by weight of the mixed conductor, with respect to 100 parts by weight of the cathode.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Lee Hyunpyo
• Kim Mokwon
• Kim Taeyoung
• Choi Wonsung

Classifications

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/0442

  Anodisation, Oxidation (electrolytic coating by anodisation C25D9/00) · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title