Expitaxial semiconductor/superconductor heterostructures
US-2021043824-A1 · Feb 11, 2021 · US
US11908689B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11908689-B2 |
| Application number | US-202118268949-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 29, 2021 |
| Priority date | Jul 15, 2021 |
| Publication date | Feb 20, 2024 |
| Grant date | Feb 20, 2024 |
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The present application discloses a method, a system, a device, and a storage medium for fabricating a GaN chip. The method includes: growing a Nb 2 N sacrificial layer on an original substrate, and growing a GaN insertion layer on the Nb 2 N sacrificial layer; growing a Ta 2 N sacrificial layer on the GaN insertion layer, and growing a semiconductor layer on the Ta 2 N sacrificial layer to form a GaN wafer; bonding the GaN wafer with a first surface of a temporary carrier, and removing the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer; and transferring remaining material after removal of the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer to a target substrate, and removing the temporary carrier from the remaining material to form the GaN chip.
Opening claim text (preview).
The invention claimed is: 1. A method for fabricating a GaN chip, comprising: growing a Nb 2 N sacrificial layer on an original substrate, and growing a GaN insertion layer on the Nb 2 N sacrificial layer; growing a Ta 2 N sacrificial layer on the GaN insertion layer, and growing a semiconductor layer on the Ta 2 N sacrificial layer to form a GaN wafer; bonding the GaN wafer with a first surface of a temporary carrier, and removing the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer; and transferring remaining material after removal of the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer to a target substrate, and removing the temporary carrier from the remaining material to form the GaN chip. 2. The method according to claim 1 , wherein growing the Nb 2 N sacrificial layer on the original substrate comprises: fabricating the Nb 2 N sacrificial layer with a thickness of 0-50 nm on the original substrate. 3. The method according to claim 1 , wherein growing the Ta 2 N sacrificial layer on the GaN insertion layer comprises: fabricating the Ta 2 N sacrificial layer with a thickness of 0-50 nm on the GaN insertion layer. 4. The method according to claim 1 , wherein bonding the GaN wafer with the first surface of the temporary carrier comprises: coating the first surface of the temporary carrier with an adhesive material, placing the temporary carrier on a hot plate for baking, and then cooling the temporary carrier. 5. The method according to claim 4 , wherein coating the first surface of the temporary carrier with the adhesive material comprises: coating the first surface of the temporary carrier with the adhesive material by a spin coating method, and controlling a rotation speed to be 1200-3000 rpm and a time to be 30-60 seconds. 6. The method according to claim 4 , wherein placing the temporary carrier on the hot plate for baking comprises: controlling the temperature of the hot plate to 120° C. and baking for 3 minutes; and controlling the temperature of the hot plate to 180° C. and baking for 4 minutes. 7. The method according to claim 1 , wherein bonding the GaN wafer with the first surface of the temporary carrier comprises: controlling a bonding temperature to 200-350° C. and a bonding force to 1000-2000 N. 8. The method according to claim 1 , wherein removing the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer comprises: removing the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer by etching with hydrochloric acid and hydrofluoric acid at a volume ratio of 1:1. 9. The method according to claim 1 , wherein transferring the remaining material after removal of the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer to the target substrate comprises: activating the remaining material and the target substrate with nitrogen or oxygen, aligning the activated target substrate with the activated remaining material for attachment, and carrying out annealing. 10. A chip, fabricated by the method according to claim 1 . 11. The method according to claim 1 , wherein the material of the original substrate is one of SiC, GaN, sapphire, diamond, Ga 2 O 3 and AlN. 12. The method according to claim 1 , wherein in the step of growing the Ta 2 N sacrificial layer on the GaN insertion layer, the Ta 2 N sacrificial layer with hexagonal crystal structure symmetry is grown on the GaN insertion layer by thin film deposition. 13. The method according to claim 1 , wherein in the step of bonding the GaN wafer with the first surface of the temporary carrier, the wafer bonding is carried out through a wafer bonding machine, a bonding temperature is 150-200° C., a bonding time is 5-10 min, and a pressure is 0.1 MPa. 14. The method according to claim 8 , wherein in the step of removing the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer, the Nb 2 N sacrificial layer and the Ta 2 N sacrificial layer are removed by a selective wet chemical etching, the original substrate is separated from the GaN insertion layer after etching. 15. The chip according to claim 10 , wherein growing the Nb 2 N sacrificial layer on the original substrate comprises: fabricating a Nb 2 N sacrificial layer with a thickness of 0-50 nm on the original substrate. 16. The chip according to claim 10 , wherein growing the Ta 2 N sacrificial layer on the GaN insertion layer comprises: fabricating the Ta 2 N sacrificial layer with a thickness of 0-50 nm on the GaN insertion layer. 17. The chip according to claim 10 , wherein bonding the GaN wafer with the first surface of the temporary carrier comprises: coating the first surface of the temporary carrier with an adhesive material, placing the temporary carrier on a hot plate for baking, and then cooling the temporary carrier. 18. The chip according to claim 17 , wherein coating the first surface of the temporary carrier with the adhesive material comprises: coating the first surface of the temporary carrier with the adhesive material by a spin coating method, and controlling a rotation speed to be 1200-3000 rpm and a time to be 30-60 seconds. 19. The chip according to claim 17 , wherein placing the temporary carrier on the hot plate for baking comprises: controlling the temperature of the hot plate to 120° C. and baking for 3 minutes; and controlling the temperature of the hot plate to 180° C. and baking for 4 minutes. 20. The chip according to claim 10 , wherein bonding the GaN wafer with the first surface of the temporary carrier comprises: controlling a bonding temperature to 200-350° C. and a bonding force to 1000-2000 N.
Separation of active layers from substrates · CPC title
using temporarily an auxiliary support · CPC title
by depositing on sacrificial masks, e.g. using lift-off · CPC title
Nitrides · CPC title
consisting of three or more layers · CPC title
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