Polymers for use in fibers and nonwoven fabrics, articles thereof, and composites thereof
US-11261544-B2 · Mar 1, 2022 · US
US11903531B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11903531-B2 |
| Application number | US-201917756533-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 20, 2019 |
| Priority date | Dec 20, 2019 |
| Publication date | Feb 20, 2024 |
| Grant date | Feb 20, 2024 |
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A cleansing wipe may be formed from a nonwoven and includes a first ethylene/alpha-olefin interpolymer and a second ethylene/alpha-olefin interpolymer. The cleansing wipe may also have a SaMbSc configuration, wherein the M, meltblown layer, is formed from the first ethylene/alpha-olefin interpolymer and the second ethylene/alpha-olefin interpolymer. The cleansing wipe may be formed a nonwoven comprising bicomponent fibers that incorporate the first ethylene/alpha-olefin interpolymer and the second ethylene/alpha-olefin interpolymer.
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We claim: 1. A cleansing wipe formed from a nonwoven comprising: a first ethylene/alpha-olefin interpolymer having (i) a density of from 0.911 to 0.939 g/cc, (ii) a Brookfield viscosity from 5,000 cP to 40,000 cP, (iii) a crystallization temperature (Tc) from 85° C. to 105° C., (iv) a melting temperature (Tm) wherein the first ethylene/alpha-olefin interpolymer has a temperature differential between the Tm and the Tc of less than 12° C. (ΔTm−Tc<12), and (v) a molecular weight distribution (M w ,cc/M n ,cc) of 1.8 to 3.5; and from 2.5 wt. % to 25 wt. % of a second ethylene/alpha-olefin interpolymer having a density of less than 0.900 g/cc and a melt index (I2) of at least 10 g/10 min. 2. A cleansing wipe having a S a M b S c configuration, wherein S is a spunbond nonwoven and M is a meltblown layer, a and c are the number of layers of S and are independent integers ranging from 0 to 5, and b is the number of layers of M and is an independent integer ranging from 1 to 5; and wherein M comprises a first ethylene/alpha-olefin interpolymer having (i) a density of from 0.911 to 0.939 g/cc, (ii) a Brookfield viscosity from 5,000 cP to 40,000 cP, (iii) a crystallization temperature (Tc) from 85° C. to 105° C., (iv) a melting temperature (Tm) wherein the first ethylene/alpha-olefin interpolymer has a temperature differential between the Tm and the Tc of less than 12° C. (ΔTm−Tc<12), and (v) a molecular weight distribution (M w,CC /M n,CC ) of 1.8 to 3.5; and from 2.5 wt. % to 25 wt. % of a second ethylene/alpha-olefin interpolymer having a density of less than 0.900 g/cc and a melt index (I2) of at least 10 g/10 min. 3. A cleansing wipe formed from a nonwoven comprising a bicomponent fiber, wherein: the bicomponent fiber has a first region and a second region, the first region is formed from a first composition comprising at least 75 wt. % of a polypropylene; the second region is formed from a second composition comprising a first ethylene/alpha-olefin interpolymer having (i) a density of from 0.911 to 0.939 g/cc, (ii) a Brookfield viscosity from 5,000 cP to 40,000 cP, (iii) a crystallization temperature (Tc) from 85° C. to 105° C., (iv) a melting temperature (Tm) wherein the first ethylene/alpha-olefin interpolymer has a temperature differential between the Tm and the Tc of less than 12° C. (ΔTm−Tc<12), and (v) a molecular weight distribution (M w,CC /M n,CC ) of 1.8 to 3.5; and from 2.5 wt. % to 25 wt. % of a second ethylene/alpha-olefin interpolymer having a density of less than 0.900 g/cc and a melt index (I2) of at least 10 g/10. 4. The cleansing wipe of claim 1 , wherein the second ethylene/alpha-olefin interpolymer has a density from 0.850 to 0.890 g/cc and a melt index (I2) of from 10 g/10 min to 600 g/10 min. 5. The cleansing wipe of claim 1 , wherein the second ethylene/alpha-olefin interpolymer is an ethylene/alpha-olefin block copolymer. 6. The cleansing wipe of claim 1 , wherein the first ethylene/alpha-olefin interpolymer has an M z,cc /M n,cc less than 3.5. 7. The cleansing wipe of claim 1 , wherein the first ethylene/alpha-olefin interpolymer has a weight fraction (w) of molecular weight greater than 10 5 g/mole, based on the total weight of the first ethylene/alpha-olefin interpolymer, as determined by conventional gel permeation chromatography, of less than 2.5%, or alternatively, less than 1.0%. 8. The cleansing wipe of claim 1 , wherein the first ethylene/alpha-olefin interpolymer has a comonomer distribution breadth index of from 50% to 85%. 9. The cleansing wipe of claim 1 , wherein the moisture content (%) of the cleaning wipe after hangin for 20 minutes is greater than 800%. 10. The cleansing wipe of claim 1 , wherein the cleansing wipe further comprises one or more spunbond nonwovens.
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