Reciprocating freeze concentration for urine-based fertilizer production

Patent metadata

Field	Value
Publication number	US-11897822-B2
Application number	US-202017093123-A
Country	US
Kind code	B2
Filing date	Nov 9, 2020
Priority date	Nov 7, 2019
Publication date	Feb 13, 2024
Grant date	Feb 13, 2024

Abstract

A system for generating a concentrated product from a feedstock includes a reciprocating concentration system that includes first and second chambers to which the feedstock is alternately provided and from which the concentrated product is alternately removed, and a heat transfer system in thermal communication with the first and second chambers, the heat transfer system being configured to reversibly transfer heat between the first and second chambers such that the first chamber alternates between melting a frozen portion of the feedstock in the second chamber and having a frozen portion of the feedstock in the first chamber melted by the feedstock in the second chamber. The system further includes a heat dump system in thermal communication with the reciprocating concentration system, the heat dump system being configured to remove heat from the reciprocating concentration system.

First claim

What is claimed is:

1. A system for generating a concentrated product from a feedstock, the system comprising:
a reciprocating concentration system comprising:
first and second chambers to which the feedstock is alternately provided and from which the concentrated product is alternately removed; and
a heat transfer system in thermal communication with the first and second chambers, the heat transfer system being configured to reversibly transfer heat between the first and second chambers such that the first chamber alternates between melting a frozen portion of the feedstock in the second chamber and having a frozen portion of the feedstock in the first chamber melted by the feedstock in the second chamber; and

a heat dump system in thermal communication with the reciprocating concentration system, the heat dump system being configured to remove heat from the reciprocating concentration system;
wherein the heat dump system comprises a thermoelectric heat pump and a heat sink in thermal communication with the thermoelectric heat pump.

2. The system of claim 1 , wherein the heat dump system is in thermal communication with one of the first and second chambers or in alternating thermal communication with both of the first and second chambers.

3. The system of claim 1 , wherein the heat dump system is in thermal communication with the heat transfer system.

4. A system for generating a concentrated product from a feedstock, the system comprising:
a reciprocating concentration system comprising:
first and second chambers to which the feedstock is alternately provided and from which the concentrated product is alternately removed; and
a heat transfer system in thermal communication with the first and second chambers, the heat transfer system being configured to reversibly transfer heat between the first and second chambers such that the first chamber alternates between melting a frozen portion of the feedstock in the second chamber and having a frozen portion of the feedstock in the first chamber melted by the feedstock in the second chamber; and

a heat dump system in thermal communication with the reciprocating concentration system, the heat dump system being configured to remove heat from the reciprocating concentration system;
wherein the heat transfer system comprises a heat pump.

5. The system of claim 4 , wherein:
the heat pump is disposed between the first and second chambers; and
the heat transfer system further comprises cooling and warming shells adjacent the first and second chambers, each of the cooling and warming shells carrying a respective thermal transfer fluid.

6. The system of claim 5 , wherein:
the cooling shell is disposed along a respective upper portion of the first and second chambers such that the feedstock freezes from the upper portion downward; and
the warming shell is disposed along a respective lower portion of the first and second chambers such that the feedstock melts from the lower portion upward.

7. The system of claim 4 , wherein the heat transfer system further comprises first and second pairs of thermal transfer channels in thermal communication with the first and second chambers, respectively, each thermal transfer channel passing through the heat pump.

8. The system of claim 4 , wherein the heat pump comprises a thermoelectric heat pump.

9. A system for generating a concentrated product from a feedstock, the system comprising:
a reciprocating concentration system comprising:
first and second chambers to which the feedstock is alternately provided and from which the concentrated product is alternately removed; and
a heat transfer system in thermal communication with the first and second chambers, the heat transfer system being configured to reversibly transfer heat between the first and second chambers such that the first chamber alternates between melting a frozen portion of the feedstock in the second chamber and having a frozen portion of the feedstock in the first chamber melted by the feedstock in the second chamber;

a heat dump system in thermal communication with the reciprocating concentration system, the heat dump system being configured to remove heat from the reciprocating concentration system; and
insulation disposed between a heat sink of the heat dump system and the reciprocating concentration system.

10. A system for generating a concentrated product from a feedstock, the system comprising:
a reciprocating concentration system comprising:
first and second chambers to which the feedstock is alternately provided and from which the concentrated product is alternately removed; and
a heat transfer system in thermal communication with the first and second chambers, the heat transfer system being configured to reversibly transfer heat between the first and second chambers such that the first chamber alternates between melting a frozen portion of the feedstock in the second chamber and having a frozen portion of the feedstock in the first chamber melted by the feedstock in the second chamber; and

a heat dump system in thermal communication with the reciprocating concentration system, the heat dump system being configured to remove heat from the reciprocating concentration system;
wherein the heat transfer system comprises:
first and second thermally conductive blocks adjacent to the first and second chambers, respectively; and
a Peltier cell disposed between the first and second thermally conductive blocks.

11. A system for generating a concentrated product from a feedstock, the system comprising:
a reciprocating concentration system comprising:
first and second chambers to which the feedstock is alternately provided and from which the concentrated product is alternately removed; and
a heat transfer system in thermal communication with the first and second chambers, the heat transfer system being configured to reversibly transfer heat between the first and second chambers such that the first chamber alternates between melting a frozen portion of the feedstock in the second chamber and having a frozen portion of the feedstock in the first chamber melted by the feedstock in the second chamber; and

a heat dump system in thermal communication with the reciprocating concentration system, the heat dump system being configured to remove heat from the reciprocating concentration system;
wherein the first and second chambers are disposed in an inclined orientation.

12. A system for generating a concentrated product from a feedstock, the system comprising:
a reciprocating concentration system comprising:
first and second chambers to which the feedstock is alternately provided and from which the concentrated product is alternately removed; and
a heat transfer system in thermal communication with the first and second chambers, the heat transfer system being configured to reversibly transfer heat between the first and second chambers such that the first chamber alternates between melting a frozen portion of the feedstock in the second chamber and having a frozen portion of the feedstock in the first chamber melted by the feedstock in the second chamber; and

a heat dump system in thermal communication with the reciprocating concentration system, the heat dump system being configured to remove heat from the reciprocating concentration system;
wherein:
the reciprocating concentration system further comprises a third chamber to which the feedstock is provided and from which the concentrated product is removed; and
the heat transfer system in thermal communication with the third chamber such that the feedstock in the third chamber melts and freezes out of phase relative to both the first and second chambers

Assignees

• Univ Michigan Regents

Inventors

• Noe-Hays Abraham
• Love Nancy G

Classifications

• C05C3/00 Primary

  Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor · CPC title

• B01D9/0013

  by indirect heat exchange · CPC title

• C01C1/10

  Separation of ammonia from ammonia liquors, e.g. gas liquors {(as part of the ammonia synthesis process C01C1/04)} · CPC title

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title