Process of producing high-quality lube base oil by using refined oil fraction of waste lubricant

Patent metadata

Field	Value
Publication number	US-11873456-B2
Application number	US-202217890252-A
Country	US
Kind code	B2
Filing date	Aug 17, 2022
Priority date	Aug 17, 2021
Publication date	Jan 16, 2024
Grant date	Jan 16, 2024

Abstract

Proposed is a process of producing a high-quality lube base oil using a refined oil fraction obtained from waste lubricant as a feedstock. The process includes purifying waste lubricant to obtain a refined oil fraction, pretreating the refined oil fraction, and blending the pretreated refined oil fraction with unconverted oil (UCO), before or after vacuum distillation and catalytic dewaxing of the unconverted oil, or between the vacuum distillation and the catalytic dewaxing of the unconverted oil.

First claim

What is claimed is:

1. A process of producing a high-quality lube base oil using a refined oil fraction of waste lubricant, the process comprising:
preparing a refined oil fraction by refining waste lubricant;
pretreating the refined oil fraction; and
blending the pretreated refined oil fraction with unconverted oil before vacuum distillation and catalytic dewaxing of the unconverted oil, or between the vacuum distillation and the catalytic dewaxing,
wherein the vacuum distillation is performed before the catalytic dewaxing, and
wherein the unconverted oil refers to a heavy fraction remaining without being converted to fuel oil through a fuel oil hydrocracking process.

2. The process of claim 1 , wherein the preparing of the refined oil fraction comprises: centrifuging the waste lubricant; performing atmospheric distillation; performing vacuum distillation; or performing combinations thereof.

3. The process of claim 1 , wherein the pretreating of the refined oil fraction comprises solvent extracting or hydrotreating the refined oil fraction.

4. The process of claim 3 , wherein a solvent used for the solvent extraction is selected from the group consisting of N-methyl-2-pyrrolidone, Sulfolane, DMSO, furfural, phenol, acetone, and combinations thereof.

5. The process of claim 3 , wherein the solvent extraction is carried out at a temperature in a range of 40° C. to 120° C. and at a pressure in a range of atmospheric pressure to 10 kg/cm 2 .

6. The process of claim 3 , wherein the solvent extraction is carried out in a condition in which a volume ratio of solvent to oil is in a range of 1:1 to 6:1.

7. The process of claim 3 , wherein the hydrotreatment is carried out at a temperature in a range of 200° C. to 400° C. and at a pressure in a range of 100 to 200 kg/cm 2 .

8. The process of claim 1 , wherein the vacuum distillation is performed before the catalytic dewaxing.

9. The process of claim 1 , wherein the catalytic dewaxing is performed in the presence of a catalyst comprising an EU-2 zeolite carrier.

10. The process of claim 1 , wherein the amount of the refined oil fraction blended with the unconverted oil is 3% or more and 50% or less by volume.

11. The process of claim 1 , wherein a blended raw material obtained by blending the refined oil fraction with the unconverted oil has a sulfur content of less than 50 ppm, a nitrogen content of less than 10 ppm, and a chlorine content of less than 2 ppm.

12. The process of claim 1 , wherein the lube base oil has a viscosity index of 120 or more and a saturation degree of 90% or more.

13. The process of claim 12 , wherein the lube base oil has a Saybolt color value of 27 or more.

14. The process of claim 12 , wherein the lube base oil has a saturation degree of 99% or more.

15. The process of claim 12 , wherein the lube base oil contains sulfur, nitrogen, and chlorine each of which is contained in a concentration of less than 1 ppm.

Assignees

• Sk Innovation Co Ltd
• Sk Enmove Co Ltd
• Sk Innovation Co Ltd And Sk Enmove Co Ltd

Inventors

• Jeon Young Wook
• Ok Jin Hee
• Noh Kyung Seok
• Kim Do Woan

Classifications

• C10G69/02 Primary

  plural serial stages only · CPC title

• C10G61/04

  the refining step being an extraction · CPC title

• C10M101/02

  Petroleum fractions · CPC title

• C10M175/005

  using extraction processes; apparatus therefor · CPC title

• C10M175/0016

  with the use of chemical agents · CPC title