Methods and systems for manufacturing lubrication oils

Patent metadata

Field	Value
Publication number	US-10385286-B2
Application number	US-201314104770-A
Country	US
Kind code	B2
Filing date	Dec 12, 2013
Priority date	Dec 12, 2013
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

Disclosed are methods and systems for manufacturing lubrication oils. In one embodiment, a method for manufacturing a lubrication oil includes the steps of receiving into an activated carbon guard bed unit an unconverted oil (UCO) feedstock, the UCO feedstock comprising polynuclear aromatic (PNA) compounds and contacting the UCO feedstock with activated carbon within the activated carbon guard bed unit to remove at least a portion of the PNA compounds, thereby forming a treated UCO feedstock.

First claim

What is claimed is:

1. A method for manufacturing a lubrication oil, the method comprising the steps of:
hydrocracking a gas oil feedstock to provide a hydrocracked unconverted oil (UCO);
receiving into an activated carbon guard bed unit said UCO feedstock, the UCO feedstock comprising polynuclear aromatic (PNA) compounds; and
contacting the UCO feedstock with activated carbon within the activated carbon guard bed unit to remove at least a portion of the PNA compounds, thereby forming a treated UCO feedstock; and
catalytically dewaxing the treated UCO feedstock directly following the contacting step.

2. The method of claim 1 , wherein dewaxing comprises contacting the treated UCO feedstock with a dewaxing catalyst.

3. The method of claim 1 , further comprising hydrofinishing the treated UCO feedstock.

4. The method of claim 3 , wherein hydrofinishing comprises contacting the treated UCO feedstock with an amorphous or crystalline metal oxide hydrofinishing catalyst.

5. The method of claim 1 , wherein contacting the UCO feedstock with activated carbon comprises contacting the UCO feedstock with activated carbon in a lead guard bed of a lead/lag guard bed unit, and wherein the UCO feedstock is not contacted with a lag guard bed of the lead/lag guard be unit.

6. The method of claim 1 , further comprising providing the UCO feedstock.

7. The method of claim 6 , wherein providing the UCO feedstock comprises providing a UCO feedstock having a normal boiling point of at least 600° F. (316° C.).

8. The method of claim 1 , wherein removing at least a portion of the PNA compounds comprises removing at least a portion of the PNA compounds having five or more aromatic rings.

9. A method for manufacturing a lubrication oil, the method comprising the steps of:
providing a UCO feedstock having a normal boiling point of at least 600° F. (316° C.) and selected from the group consisting of: gas oils and vacuum gas oils (VGO), hydrocracked gas oils and vacuum gas oils, deasphalted oils, slack waxes, foots oils, coker tower bottoms, reduced crude, vacuum tower bottoms, deasphalted vacuum residues, FCC tower bottoms and cycle oils and raffinates from a solvent extraction process, the UCO feedstock comprising polynuclear aromatic (PNA) compounds;
receiving into an activated carbon guard bed unit the unconverted oil (UCO) feedstock;
contacting the UCO feedstock with activated carbon within the activated carbon guard bed unit to remove at least a portion of the PNA compounds, thereby forming a treated UCO feedstock, wherein removing at least a portion of the PNA compounds comprises removing at least a portion of the PNA compounds having five or more aromatic rings, and wherein contacting the UCO feedstock with activated carbon comprises contacting the UCO feedstock with activated carbon in a lead guard bed of a lead/lag guard bed unit, and wherein the UCO feedstock is not contacted with a lag guard bed of the lead/lag guard be unit;
dewaxing the treated UCO feedstock directly following the contacting step by contacting the treated UCO feedstock with a dewaxing catalyst; and
hydrofinishing the treated UCO feedstock by contacting the treated UCO feedstock with an amorphous or crystalline metal oxide hydrofinishing catalyst.

10. A method for manufacturing a lubrication oil, the method comprising the steps of:
receiving into an activated carbon guard bed unit an unconverted oil (UCO) feedstock, the UCO feedstock comprising polynuclear aromatic (PNA) compounds; and
contacting the UCO feedstock with activated carbon within the activated carbon guard bed unit to remove at least a portion of the PNA compounds, thereby forming a treated UCO feedstock;
catalytically dewaxing the treated UCO feedstock directly following the contacting step; and
hydrofinishing the treated UCO feedstock.

11. The method of claim 10 , wherein dewaxing comprises contacting the treated UCO feedstock with a dewaxing catalyst.

12. The method of claim 10 , wherein hydrofinishing comprises contacting the treated UCO feedstock with an amorphous or crystalline metal oxide hydrofinishing catalyst.

13. The method of claim 10 , wherein contacting the UCO feedstock with activated carbon comprises contacting the UCO feedstock with activated carbon in a lead guard bed of a lead/lag guard bed unit, and wherein the UCO feedstock is not contacted with a lag guard bed of the lead/lag guard be unit.

14. The method of claim 10 , further comprising providing the UCO feedstock by hydrocracking gas oil.

15. The method of claim 10 , further providing the UCO feedstock comprising a normal boiling point of at least 600° F. (316° C.).

16. The method of claim 15 , wherein providing the UCO feedstock comprises providing a UCO feedstock selected from the group consisting of: gas oils and vacuum gas oils (VGO), hydrocracked gas oils and vacuum gas oils, deasphalted oils, slack waxes, foots oils, coker tower bottoms, reduced crude, vacuum tower bottoms, deasphalted vacuum residues, FCC tower bottoms and cycle oils and raffinates from a solvent extraction process.

17. The method of claim 10 , wherein removing at least a portion of the PNA compounds comprises removing at least a portion of the PNA compounds having five or more aromatic rings.

Assignees

• Uop Llc

Inventors

• Pintar Daniel James
• Roxas Pamela
• Thakkar Vasant P

Classifications

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title

• C10M2203/003

  used as base material · CPC title

• C10M2203/1085

  used as base material · CPC title

• C10G67/06

  including a sorption process as the refining step in the absence of hydrogen · CPC title

• C10G2300/201

  Impurities · CPC title