Carbon dioxide electrolytic device

Patent metadata

Field	Value
Publication number	US-11851774-B2
Application number	US-202117405336-A
Country	US
Kind code	B2
Filing date	Aug 18, 2021
Priority date	Mar 18, 2021
Publication date	Dec 26, 2023
Grant date	Dec 26, 2023

Abstract

A carbon dioxide electrolytic device according to an embodiment includes: an electrolysis cell including a reduction electrode, an oxidation electrode, a gas flow path supplying gas containing CO 2 to the reduction electrode, a liquid flow path supplying an electrolytic solution containing water to the oxidation electrode, and a diaphragm separating the reduction electrode from the oxidation electrode; a first supply path connected to the gas flow path; a first discharge path connected to the gas flow path; a first moisture content detecting unit installed in the first discharge path to detect a moisture content in the gas flowing in the first discharge path; a moisture content adjusting unit configured to adjust a moisture content supplied to the reduction electrode; and a control unit configured to control the moisture content adjusting unit based on a detection signal of the first moisture content detecting unit.

First claim

What is claimed is:

1. A carbon dioxide electrolytic device comprising:
a first electrolysis cell including a reduction electrode, an oxidation electrode, a gas flow path to supply gas containing carbon dioxide to the reduction electrode, a liquid flow path to supply an electrolytic solution containing water or water vapor to the oxidation electrode, and a diaphragm separating the reduction electrode from the oxidation electrode;
a first supply path connected to the gas flow path to supply the gas to the reduction electrode;
a first discharge path connected to the gas flow path to discharge at least products produced at the reduction electrode;
a first moisture content detecting unit installed in the first discharge path to detect a moisture content in the gas flowing in the first discharge path;
a moisture content adjusting unit configured to adjust a moisture content supplied to the reduction electrode; and
a control unit configured to control the moisture content adjusting unit based on a detection signal of the first moisture content detecting unit, wherein
the moisture content adjusting unit includes a flow rate adjusting unit configured to adjust an amount of the electrolytic solution supplied to the oxidation electrode.

2. The device according to claim 1 , further comprising:
a second moisture content detecting unit installed in the first supply path to detect a moisture content in the gas flowing in the first supply path.

3. The device according to claim 1 , wherein
the moisture content adjusting unit further includes a humidity regulator configured to regulate humidity in the gas flowing through the first supply path.

4. The device according to claim 1 , wherein
the moisture content adjusting unit further includes a temperature regulator configured to regulate a temperature of the first electrolysis cell.

5. The device according to claim 1 , wherein
the first moisture content detecting unit includes a dew-point meter.

6. The device according to claim 1 , wherein
the first moisture content detecting unit includes a hygrometer and a thermometer.

7. The device according to claim 1 , further comprising:
a second electrolysis cell including a reduction electrode, an oxidation electrode, a gas flow path to supply gas containing carbon dioxide to the reduction electrode, a liquid flow path to supply an electrolytic solution containing water or water vapor to the oxidation electrode, and a diaphragm separating the reduction electrode from the oxidation electrode, and being stacked on or disposed in parallel with the first electrolysis cell, wherein
the gas flow path of the second electrolysis cell is connected to the first supply path and the first discharge path.

8. A carbon dioxide electrolytic device comprising:
a first electrolysis cell including a reduction electrode, an oxidation electrode, a gas flow path to supply gas containing carbon dioxide to the reduction electrode, a liquid flow path to supply an electrolytic solution containing water or water vapor to the oxidation electrode, and a diaphragm separating the reduction electrode from the oxidation electrode;
a first supply path connected to the gas flow path to supply the gas to the reduction electrode;
a first discharge path connected to the gas flow path to discharge at least products produced at the reduction electrode;
a first moisture content detecting unit installed in the first discharge path to detect a moisture content in the gas flowing in the first discharge path;
a moisture content adjusting unit configured to adjust a moisture content supplied to the reduction electrode;
a control unit configured to control the moisture content adjusting unit based on a detection signal of the first moisture content detecting unit:
a second supply path connected to the liquid flow path to supply the electrolytic solution to the oxidation electrode:
a second discharge path connected to the liquid flow path to discharge products produced at the oxidation electrode together with the electrolytic solution; and
a pump to circulate the electrolytic solution through the second supply path, the liquid flow path, and the second discharge path, wherein
the moisture content adjusting unit includes the pump, and
the control unit is configured to adjust a flow rate of the pump based on the detection signal of the first moisture content detecting unit.

9. The device according to claim 8 , further comprising:
a second moisture content detecting unit installed in the first supply path to detect a moisture content in the gas flowing in the first supply path.

10. The device according to claim 8 , wherein
the first moisture content detecting unit includes a dew-point meter.

11. The device according to claim 8 , wherein
the first moisture content detecting unit includes a hygrometer and a thermometer.

12. A carbon dioxide electrolytic device comprising:
a first electrolysis cell including a reduction electrode, an oxidation electrode, a gas flow path to supply gas containing carbon dioxide to the reduction electrode, a liquid flow path to supply an electrolytic solution containing water or water vapor to the oxidation electrode, and a diaphragm separating the reduction electrode from the oxidation electrode;
a first supply path connected to the gas flow path to supply the gas to the reduction electrode;
a first discharge path connected to the gas flow path to discharge at least products produced at the reduction electrode;
a first moisture content detecting unit installed in the first discharge path to detect a moisture content in the gas flowing in the first discharge path;
a moisture content adjusting unit configured to adjust a moisture content supplied to the reduction electrode;
a control unit configured to control the moisture content adjusting unit based on a detection signal of the first moisture content detecting unit;
a cooling water flow path disposed to be adjacent to the reduction electrode with a porous conductive material therebetween to adjust a temperature of the first electrolysis cell; and
a cooling water pump configured to introduce cooling water into the cooling water flow path, wherein
the moisture content adjusting unit includes the cooling water pump, and
the control unit is configured to adjust a flow rate of the cooling water pump based on a detection signal of the first moisture content detecting unit.

13. The device according to claim 12 , further comprising:
a second moisture content detecting unit installed in the first supply path to detect a moisture content in the gas flowing in the first supply path.

14. The device according to claim 12 , wherein
the first moisture content detecting unit includes a dew-point meter.

15. The device according to claim 12 , wherein
the first moisture content detecting unit includes a hygrometer and a thermometer.

Assignees

• Toshiba Kk

Inventors

• Kitagawa Ryota
• Kofuji Yusuke
• Ono Akihiko
• Kudo Yuki
• Tamura Jun
• Mikoshiba Satoshi

Classifications

• C25B1/23 Primary

  Carbon monoxide or syngas · CPC title

• C25B1/02

  Hydrogen or oxygen · CPC title

• C25B9/19

  with diaphragms · CPC title

• C25B9/67

  Heating or cooling means · CPC title

• C25B9/70

  Assemblies comprising two or more cells · CPC title