Method and plant for preparing vinyl chloride from 1,2-dichloroethane

Patent metadata

Field	Value
Publication number	US-11845706-B2
Application number	US-202017607262-A
Country	US
Kind code	B2
Filing date	Apr 22, 2020
Priority date	Apr 30, 2019
Publication date	Dec 19, 2023
Grant date	Dec 19, 2023

Abstract

Disclosed is a method for preparing vinyl chloride by catalytic thermal cracking of 1,2-dichloroethane, in which method the heat required for the thermal cracking is supplied via a liquid or condensing heat transfer medium, wherein, the heat transfer medium is heated at least in part by means of waste heat from a plant for combusting liquid and/or gaseous residues of a chemical plant. The invention also relates to a plant for preparing vinyl chloride by catalytic thermal cracking of 1,2-dichloroethane. The heat required for thermal cracking can be obtained from cheaply available waste heat. For example, it is possible to temporarily heat the heat transfer medium exclusively by means of the second heating device operated by waste heat, wherein said waste heat can, for example, be waste heat from a plant for preparing vinyl chloride.

First claim

The invention claimed is:

1. A method for producing vinyl chloride by catalytic thermal cleavage of 1,2-dichloroethane, in which heat required for thermal cleavage is supplied via a liquid or condensing heat transfer medium, wherein the heat transfer medium is at least temporarily and/or at least partially or completely heated by a waste heat from a plant for the incineration of liquid and/or gaseous residues from a chemical plant, wherein at least one first heating device operated by combustion of at least one fuel and additionally at least one second heating device operated via waste heat are utilized to heat the liquid heat transfer medium.

2. The method according to claim 1 , wherein the 1,2-dichloroethane is preheated and/or evaporated and/or overheated by the heat transfer medium.

3. The method according to claim 1 , wherein the heat transfer medium is heated at least temporarily and/or at least partially by the combustion of at least one fuel and partially by heating it via waste heat.

4. The method according to claim 1 , wherein at least one first heating device operated by combustion of at least one fuel and additionally at least one second heating device operated via waste heat are utilized to heat the liquid heat transfer medium.

5. The method according to claim 1 , wherein at least one first heating device and at least one second heating device operated via waste heat are connected in series in the circuit.

6. The method according to claim 1 , wherein the heat transfer medium is conducted in a circuit into which a reactor is integrated, in which the catalytic thermal cleavage of 1,2-dichloroethane is carried out, wherein a heat exchange takes place between the reaction medium of the reactor and the heat transfer medium.

7. The method according to claim 6 , wherein the heat transfer medium is conveyed in the circuit in countercurrent to the flow of the reaction medium through the reactor.

8. The method according to claim 5 , wherein the second heating device operated via waste heat is operated at least temporarily by energy obtained from the waste heat from a plant for producing vinyl chloride.

9. The method according to claim 1 , wherein the thermal cleavage of the 1,2-dichloroethane is carried out in a temperature range from 200° C. to 400° C.

10. A plant for producing vinyl chloride by catalytic thermal cleavage of 1,2-dichloroethane, in which heat required for preheating, evaporation, overheating and thermal cleavage of 1,2-dichloroethane is supplied via a liquid or condensing heat transfer medium, comprising at least one reactor in which the thermal cleavage takes place and at least one first heating device by which the reaction medium in the reactor is heated by the heat transfer medium, wherein the system further comprises at least one second heating device operated by waste heat from a plant for the incineration of liquid and/or gaseous residues of a chemical plant for heating the reaction medium, wherein the reactor is integrated into a circuit of the heat transfer medium, wherein additionally the at least one first heating device operated via a fuel and further the at least one second heating device operated by means of waste heat are integrated into the circuit of the heat transfer medium.

11. The plant according to claim 10 , wherein the circuit of the heat transfer medium comprises a pump integrated into a line system, at least one first heating device operated via a fuel, at least one second heating device operated by waste heat, and the reactor, wherein provisions are made for transferring heat from the heat transfer medium to a reaction medium flowing through the reactor.

12. The plant according to claim 10 , wherein the first heating device operated via a fuel and the second heating device operated by waste heat are arranged in series or in parallel in the circuit of the heat transfer medium.

13. The plant according to claim 10 , wherein the reactor comprises a tube bundle heat exchanger in which the tubes are filled with catalyst.

14. The plant according to claim 13 , wherein the heat transfer medium flows through a jacket space of the reactor in a circuit.

15. The plant according to claim 10 , wherein at least one device for preheating and/or evaporating and/or overheating of the 1,2-dichloroethane is integrated into the circuit of the heat transfer medium.

Assignees

• Thyssenkrupp Ag
• Thyssenkrupp Ind Solutions Ag
• Westlake Vinnolit Gmbh & Co Kg
• Thysenkrupp Ind Solutions Ag

Inventors

• Poppe Alexander
• Kammerhofer Peter
• Krejci Klaus

Classifications

• C07C17/25 Primary

  by splitting-off hydrogen halides from halogenated hydrocarbons · CPC title

• B01J19/2415

  Tubular reactors · CPC title

• B01J2219/00092

  Tubes · CPC title

• B01J2219/00094

  Jackets · CPC title

• B01J2219/00157

  by means of a burner · CPC title