Method for heat recovery in vinyl chloride monomer structures or in the structure composite dichloroethane/vinyl chloride, and device suitable for same

Patent metadata

Field	Value
Publication number	US-9334209-B2
Application number	US-201314760002-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Jan 10, 2013
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

Energy savings in an integrated DCE/VCM plant, optionally also containing a PVC plant, is accomplished by using at least part of the vapor from a DEC quenching column to supply heat to an HCl column. The DCE plant has a high boiler column operating at superatmospheric pressure, and heat is removed from an overhead stream and used to supply heat to other portions of the process.

First claim

The invention claimed is:

1. A process for preparing vinyl chloride by thermal dissociation of 1,2-dichloroethane in a vinyl chloride plant, comprising:
thermally dissociating 1,2-dichloroethane in a 1,2-dichloroethane pyrolysis unit;
cooling the dissociation gas produced thereby in a downstream quenching column and separating hydrogen chloride present in the dissociation gas in a downstream HCl column,
wherein the vinyl chloride plant is preceded by a 1,2-dichloroethane plant in which 1,2-dichloroethane is purified by distillation, and which is provided with at least one high-boiler column operated under superatmospheric pressure for separating substances having boiling points higher than that of 1,2-dichloroethane, the process further comprising recovering thermal energy from at least part of a vapor from the quenching column and heating the HCl column with the recovered thermal energy.

2. The process of claim 1 , wherein the high-boiler column is operated under a superatmospheric pressure in the range from 2.7 to 5.3 bar.

3. The process of claim 2 , wherein the high-boiler column is operated at temperatures in the range of 120-150° C. and at least part of an overhead stream from the high-boiler column is used for recovering thermal energy which is utilized in one or more heat sink(s) of a subplant for preparing 1,2-dichloroethane, heat sink(s) of a downstream subplant for producing vinyl chloride, and/or heat sink(s) of a downstream subplant for preparing polyvinyl chloride.

4. The process of claim 1 , wherein heating of the HCl column is effected by means of thermal energy which originates to an extent of at least 50% from vapor from the quenching column, the remainder provided by low-pressure steam.

5. The process of claim 1 , wherein heating of the HCl column is effected by means of thermal energy which originates to an extent of at least 70% from vapor from the quenching column, the remainder provided by low-pressure steam.

6. An apparatus for preparing vinyl chloride by thermal dissociation of 1,2-dichloroethane in a vinyl chloride plant, comprising the elements:
A) a 1,2-dichloroethane pyrolysis unit in which a 1,2-dichloroethane feed is thermally dissociated,
B) a quenching column located downstream from the 1,2-dichloroethane pyrolysis unit in which dissociation gas produced by pyrolysis is cooled and solids are scrubbed out,
C) an HCl column located downstream from the quenching column in which hydrogen chloride present in the dissociation gas is separated,
D) at least one heat exchanger in which thermal energy utilized for heating the HCl column is recovered from at least part of vapor from the quenching column,
E) a plant for preparing and purifying 1,2-dichloroethane which is located upstream of the vinyl chloride plant and has a 1,2-dichloroethane purifying distillation vessel and is
F) provided with at least one high-boiler column in which substances having boiling points higher than that of 1,2-dichloroethane are separated off, the high-boiler column being configured to operate at superatmospheric pressure.

7. The apparatus of claim 6 , further comprising at least one heat exchanger which is heated by vapor from the high-boiler column, wherein thermal energy recovered by the heat exchanger is used for heating heat sink(s) in the 1,2-dichloroethane plant, heat sink(s) in the vinyl chloride plant, and/or heat sink(s) in a polyvinyl chloride subplant located downstream of the vinyl chloride plant.

Assignees

• Thyssenkrupp Ind Solutions Ag
• Vinnolit Gmbh & Co Kg

Inventors

• Braun Manuel

Classifications

• C07C17/25 Primary

  by splitting-off hydrogen halides from halogenated hydrocarbons · CPC title

• C07C17/395 Primary

  by treatment giving rise to a chemical modification of at least one compound · CPC title

• B01J19/245

  placed in series · CPC title

• C01B7/0706

  of hydrogen chloride · CPC title

• C07C21/06

  Vinyl chloride · CPC title