Method and apparatus for transfer of liquid

Patent metadata

Field	Value
Publication number	US-11828532-B2
Application number	US-202017138927-A
Country	US
Kind code	B2
Filing date	Dec 31, 2020
Priority date	Dec 31, 2020
Publication date	Nov 28, 2023
Grant date	Nov 28, 2023

Abstract

A method and apparatus for transferring a first liquid removed from an outlet of a first distillation column to an inlet of a second distillation column is provided. The second distillation column operates at a higher pressure than the first distillation column, and the inlet of the second distillation column is at higher elevation as compared to the outlet of the first distillation column. The method advantageously transfers the first liquid from the outlet to the inlet by mixing with a sufficient amount of a lower density second liquid that results in a mixed liquid having a reduced density as compared to the first liquid.

First claim

I claim:

1. A method for operating an air separation plant having a higher-pressure column, a lower-pressure column, and an argon column, the air separation plant having a first mode of operation and a second mode of operation, the method comprising the steps of:
withdrawing an argon-enriched fluid from the lower-pressure column and introducing said argon-enriched fluid to the argon column;
withdrawing an argon-enriched liquid from a first location of the argon column; and
withdrawing a liquid nitrogen stream from a third location of the higher-pressure column and introducing the liquid nitrogen stream, after expansion in a valve, to a second location of the lower-pressure column, wherein the second location is at a higher elevation than the third location,
wherein during first mode of operation, the method further comprises the step of sending the argon-enriched liquid withdrawn from the first location of the argon column to a liquid storage tank or to a fourth column configured to further refine the argon-enriched liquid,
wherein during the second mode of operation, the method further comprises the steps of mixing the argon-enriched liquid from the first location of the argon column with the liquid nitrogen stream at a mixing location that is at a lower elevation than the first location to form a mixed fluid and then introducing the mixed fluid to the second location, wherein the mixed fluid is introduced to the second location without the use of a pump,
wherein the method is switched from the first mode of operation to the second mode of operation by closing an argon production valve and opening a previously closed second valve for mixing the argon-enriched liquid with the nitrogen-enriched liquid.

2. The method as claimed in claim 1 , wherein the step of mixing the argon-enriched liquid further comprises adjusting a flow rate of the argon-enriched liquid being mixed with the liquid nitrogen stream at the mixing location using the second valve.

3. The method as claimed in claim 2 , wherein the second valve is disposed between the first location and the mixing location.

4. A method for operating an air separation plant having a higher-pressure column, a lower-pressure column, and an argon column, the air separation plant having a first mode of operation and a second mode of operation, the method comprising the steps of:
withdrawing an argon-enriched fluid from the lower-pressure column and introducing said argon-enriched fluid to the argon column;
withdrawing an argon-enriched liquid from a first location of the argon column; and
withdrawing a liquid nitrogen stream from a third location of the higher-pressure column and introducing the liquid nitrogen stream, after expansion in a valve, to a second location of the lower-pressure column, wherein the second location is at a higher elevation than the third location,
wherein during first mode of operation, the method further comprises the step of sending the argon-enriched liquid withdrawn from the first location of the argon column to a liquid storage tank or to a fourth column configured to further refine the argon-enriched liquid,
wherein during the second mode of operation, the method further comprises the steps of mixing the argon-enriched liquid from the first location of the argon column with the liquid nitrogen stream at a mixing location that is at a lower elevation than the first location to form a mixed fluid and then introducing the mixed fluid to the second location, wherein the mixed fluid is introduced to the second location without the use of a pump,
wherein the step of mixing the argon-enriched liquid further comprises adjusting a flow rate of the argon-enriched liquid being mixed with the liquid nitrogen stream at the mixing location using a second valve,
wherein the step of mixing the argon-enriched liquid further comprises adjusting a flow rate of the argon-enriched liquid sent from the first location of the argon column to the liquid storage tank or to the fourth column using an argon production valve.

5. The method as claimed in claim 1 , wherein the method is switched from the first mode of operation to the second mode of operation upon a determination that a reduction in liquid argon is desired.

6. The method as claimed in claim 4 , wherein the method is switched from the first mode of operation to the second mode of operation by closing an argon production valve and opening a previously closed second valve for mixing the argon-enriched liquid with the nitrogen-enriched liquid.

7. The method as claimed in claim 1 , wherein the liquid nitrogen stream is mixed with the argon-enriched liquid in an amount sufficient to lower the density of the mixed fluid thereby allowing the mixed fluid to move from the mixing location to the second location without the use of the pump.

8. The method as claimed in claim 1 , wherein the lower-pressure column is surmounted on the higher pressure column and the lower-pressure column and the higher-pressure column share a common condenser/reboiler.

9. An air separation plant configured to operate in a first mode of operation and a second mode of operation, the apparatus comprising:
a double column system having a higher-pressure column surmounted by a lower-pressure column, wherein a second location of the lower-pressure column is configured to receive a liquid nitrogen stream from a third location of the higher-pressure column following expansion in a valve;
an argon production unit in fluid communication with the lower-pressure column, wherein the argon production unit is configured to receive an argon-enriched fluid from the lower-pressure column, wherein the argon production unit is configured to operate at a lower pressure than the lower-pressure column, wherein the argon production unit comprises an argon column and liquid argon storage;
wherein during first mode of operation, the argon production unit is configured to transfer liquid argon to a liquid storage tank,
wherein during the second mode of operation, a first location of the argon production unit is configured to be in fluid communication with a mixing location, such that the air separation plant is configured to mix an argon-enriched fluid from the argon production unit with the liquid nitrogen stream from the higher-pressure column at the mixing location, wherein the mixing location is disposed between the second location and the third location, wherein the mixing location is at a lower elevation than the second location and the first location,
wherein the apparatus further comprises an absence of a pump disposed between the first location and the second location,
wherein the apparatus is switched from the first mode of operation to the second mode of operation by closing an argon production valve and opening a previously closed mixing valve for mixing the argon-enriched liquid with the nitrogen-enriched liquid.

10. The apparatus as claimed in claim 9 , wherein the mixing valve is configured to adjust the flow rate of the argon-enriched liquid to be mixed with the liquid nitrogen stream resulting in a mixed fluid that has sufficiently reduced density reduced density as compared to the argon-enriched liquid such that the mixed fluid can move from the mixing location to the second location without the use of the pump.

Assignees

• Air Liquide

Inventors

• Day Eric

Classifications

• F25J3/04812 Primary

  Different modes, i.e. "runs" of operation (F25J3/04472 takes precedence) · CPC title

• F25J3/048

  Argon recovery · CPC title

• F25J3/04666

  as a parallel working rectification column of the low pressure column in a dual pressure main column system · CPC title

• F25J2205/90

  Mixing of components · CPC title

• F25J2280/02

  Control in general, load changes, different modes ("runs"), measurements · CPC title