Method and apparatus for separating air by cryogenic distillation

Patent metadata

Field	Value
Publication number	US-10012435-B2
Application number	US-201314426489-A
Country	US
Kind code	B2
Filing date	Aug 28, 2013
Priority date	Sep 12, 2012
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

In a method for producing a first pressurized gas and a second gas on a one-off basis by cryogenic distillation of air, according to a first step, no fluid heats up or cools down in a second heat exchanger, and according to a second step, a flow of pressurized liquid from the double column heats up and vaporizes in the second exchanger to form a gas required on a one-off basis, a flow of air at the second pressure cools in the second exchanger.

First claim

The invention claimed is:

1. A process for producing a first pressurized gas and also occasionally a second gas by cryogenic distillation of air in a double column comprising a first column and a second column, the second column operating at lower pressure than the first column, the process comprising a first regime and a second regime, wherein:
i) according to the first regime, the process comprises the steps of:
cooling a first air flow at a first pressure, which is substantially the operating pressure of the first column, in a first heat exchanger;
sending the cooled first air flow to the first column;
heating a first nitrogen-rich gas flow originating from the first column and a second nitrogen-rich gas flow originating from the second column in the first heat exchanger, wherein none of the first air flow or the first and second nitrogen-rich gas flows are heated or cooled in a second heat exchanger;
cooling at least one second air flow at a second pressure in a third heat exchanger, the second pressure being above the first pressure;
vaporizing a first pressurized liquid in the third heat exchanger to form the first pressurized gas; and
heating a third nitrogen-rich gas flow originating from the second column in the third heat exchanger, and

ii) according to the second regime, the process comprises the steps of:
cooling the first air flow at the first pressure in the first heat exchanger;
sending the cooled first air flow to the first column;
heating the second nitrogen-rich gas flow originating from the second column in the first heat exchanger;
heating and vaporizing a second pressurized liquid flow originating from the double column in the second heat exchanger in order to form the occasionally produced second gas;
cooling a third air flow at the second pressure in the second heat exchanger, wherein the third air flow and the second pressurized liquid flow are the only fluids exchanging heat in the second heat exchanger,
cooling the second air flow at the second pressure in the third heat exchanger;
vaporizing the first pressurized liquid in the third heat exchanger; and
heating the nitrogen-rich gas flow originating from the second column in the third heat exchanger.

2. The process as claimed in claim 1 , wherein the second regime further comprises the step of cooling a fourth air flow at a third pressure in the third heat exchanger, wherein the third pressure is above the first pressure.

3. The process as claimed in claim 2 , wherein, during the second regime, the third pressure is greater than the second pressure.

4. The process as claimed in claim 2 , wherein, during the second regime, the fourth air flow is expanded in a turbine and sent to the first or second column.

5. The process as claimed in claim 4 , wherein, during the second regime, the flow sent to the turbine originates from a first booster compressor.

6. The process as claimed in claim 4 , wherein in the second regime an air flow selected from the group consisting of the second air flow and the third air flow originates from a second booster compressor driven by the turbine.

7. The process as claimed in claim 1 , wherein, during the second regime, the second nitrogen-rich gas flow originating from the second column is the only stream heated in the first heat exchanger.

8. The process as claimed in claim 1 , wherein an amount of liquid is produced as final product according to the first regime and no liquid is produced as final product according to the second regime.

9. The process as claimed in claim 1 , wherein an amount of liquid is produced as final product according to the first regime and an amount of liquid smaller than that produced in the first regime is produced as final product according to the second regime.

10. The process as claimed in claim 1 , wherein the first pressurized liquid flow is rich in nitrogen.

11. A facility for separating air by cryogenic distillation, the facility comprising:
a double column having a first column and a second column, the second column operating at lower pressure than the first column,
a first heat exchanger in fluid communication with the double column;
a second heat exchanger connected to feed ducts configured to enable an indirect heat exchange between only two fluids, wherein the second heat exchanger is in fluid communication with the double column;
a third heat exchanger in fluid communication with the double column;
means for sending a first air flow at a first pressure substantially equal to the operating pressure of the first column to the first heat exchanger and from the first heat exchanger to the first column;
means for sending a first fraction of air at a second pressure to the second heat exchanger through a first one of the feed ducts;
a valve configured to prevent the first fraction of air from being sent to the second heat exchanger during a first regime;
means for sending a second fraction of air at the second pressure to the third heat exchanger;
means for sending a first pressurized liquid from the double column to be vaporized in the third heat exchanger;
means for sending an occasionally produced liquid from the double column to be vaporized in the second heat exchanger through a second one of the feed ducts during a second regime;
a valve configured to prevent the occasionally produced liquid from being sent from the double column to the second heat exchanger during the first regime;
means for sending a first nitrogen-rich gas from the first column to be heated in the first heat exchanger;
a valve configured to prevent the first nitrogen-rich gas from being sent from the first column to the first heat exchanger during the second regime;
means for sending a second nitrogen-rich gas from the double column to the first heat exchanger; and
means for sending a third nitrogen-rich gas from the double column to the third heat exchanger.

12. The facility as claimed in claim 11 , wherein at least the first and third heat exchangers are brazed aluminum plate-fin heat exchangers.

13. The facility as claimed in claim 11 , further comprising means for sending a fourth air flow at a pressure above the first pressure to the third heat exchanger.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Cognard Marie
• Dubettier-Grenier Richard
• Gerard Sylvain

Classifications

• F25J3/0409

  of oxygen · CPC title

• F25J3/04412

  in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title

• F25J3/04187 Primary

  Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams (arrangements of cold exchangers F25J5/002) · CPC title

• F25J3/0443

  A main column system not otherwise provided, e.g. a modified double column flowsheet · CPC title

• F25J3/04812 Primary

  Different modes, i.e. "runs" of operation (F25J3/04472 takes precedence) · CPC title