Dual-membrane on-line generator for acid or alkali solution

Patent metadata

Field	Value
Publication number	US-11827990-B2
Application number	US-201915734689-A
Country	US
Kind code	B2
Filing date	Jun 14, 2019
Priority date	Jul 5, 2018
Publication date	Nov 28, 2023
Grant date	Nov 28, 2023

Abstract

A dual-membrane on-line generator for an acid or alkali solution is provided, including an upper electrolytic cell body ( 3 ), a middle electrolytic cell body ( 4 ) and a lower electrolytic cell body ( 5 ) which are clamped by an upper fastening steel plate ( 1 ) and a lower fastening steel plate ( 2 ), an upper regeneration liquid channel (A), a middle eluent channel (B) and a lower regeneration liquid channel (C) being provided on the middle electrolytic cell body ( 4 ).

First claim

The invention claimed is:

1. A dual-membrane on-line generator for generating an acid or alkali solution comprising:
an upper fastening steel plate and a lower fastening steel plate,
an upper electrolytic cell body,
a middle electrolytic cell body and a
lower electrolytic cell body,
the upper electrolytic cell body, the middle electrolytic cell body and the lower electrolytic cell body being releasably secured in fluid-tight relation between the upper fastening steel plate and the lower fastening steel plate,
wherein the middle electrolytic cell body is provided with an upper regeneration liquid channel (A), a middle eluent channel (B) and a lower regeneration liquid channel (C),
the upper regeneration liquid channel having an inlet at one end and an outlet, at its opposite end, the upper regeneration liquid channel (A) inlet and the upper regeneration liquid channel outlet being arranged in the upper fastening steel plate;
a cathode electrode having one end positioned in the upper regeneration liquid channel (A), and the opposite end arranged on the upper fastening steel plate;
the middle eluent channel (B) having an inlet at one end and an outlet at the opposite end, the inlet and outlet being arranged on opposite sides of the middle electrolytic cell body;
the lower regeneration liquid channel (C) having a lower regeneration liquid channel inlet at one end and a lower regeneration liquid channel outlet at the opposite end, the lower regeneration liquid channel inlet and the lower regeneration liquid channel outlet being arranged in the lower fastening steel plate;
an anode electrode having one end positioned in the lower regeneration liquid channel (C), and the opposite end arranged on the lower fastening steel plate;
a porous cathode sheet, a first cation exchange membrane and a bipolar membrane operatively positioned between the upper regeneration liquid channel (A) and the middle eluent channel (B);
a porous anode sheet and a second cation exchange membrane operatively positioned between the middle eluent channel (B) and the lower regeneration liquid channel (C);
whereby pure water entering the generator via the middle eluent channel inlet, passes through the middle eluent channel (B) and flows out of the middle eluent channel outlet,
pure alkali regeneration liquid entering the upper regeneration liquid channel inlet passes through the upper regeneration liquid channel (A) and flows out of the upper regeneration liquid channel outlet and enters the lower regeneration liquid channel inlet, passes through the lower regeneration liquid channel (C) and out of the lower regeneration liquid channel outlet to for recovery as regeneration liquid.

2. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 1 , wherein the middle eluent channel (B) is filled with ion exchange screens or inert particles, or with monolithic columns or fibers.

3. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 1 , wherein multi-layer and overlapping first cation exchange membranes and bipolar membranes are operatively positioned between the upper regeneration liquid channel (A) and the middle eluent channel (B).

4. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 1 , wherein multi-layer and overlapping second cation exchange membranes are operatively positioned between the middle eluent channel (B) and the lower regeneration liquid channel (C).

5. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 3 , wherein the first cation exchange membrane, the second cation exchange membrane and the bipolar membrane are in the form of ion exchange plate membranes.

6. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 1 , wherein the cathode electrode and the anode electrode are in the form of porous platinum electrode structures.

7. A dual-membrane on-line generator for generating an acid or alkali solution comprising:
an upper fastening steel plate and a lower fastening steel plate,
an upper electrolytic cell body,
a middle electrolytic cell body
and a lower electrolytic cell body
the upper electrolytic cell body, the middle electrolytic cell body and the lower electrolytic cell body being releasably secured in fluid-tight relation between the upper fastening steel plate and the lower fastening steel plate;
wherein, the middle electrolytic cell body is provided with an upper regeneration liquid channel (A), a middle eluent channel (B) and a lower regeneration liquid channel (C), the upper regeneration liquid channel (A) having an inlet at one end and and an upper regeneration liquid channel outlet at its opposite end, the upper regeneration liquid channel inlet and the upper regeneration liquid channel outlet being arranged in the upper fastening steel plate;
an anode electrode having one end positioned in the upper regeneration liquid channel (A) and its opposite end arranged on the upper fastening steel plate, the anode electrode having a porous platinum electrode structure,
the middle eluent channel (B) having an inlet at one end and an outlet at its opposite end the middle eluent channel inlet and the middle eluent channel outlet being arranged on opposite sides of the middle electrolytic cell body;
the lower regeneration liquid channel (C), having a lower regeneration liquid channel inlet at one end and lower regeneration liquid channel outlet at its opposite end, the lower regeneration liquid channel inlet and lower regeneration liquid channel outlet being arranged in the lower fastening steel plate;
a cathode electrode having one end positioned in the lower regenerating liquid channel and its opposite end arranged on the lower fastening steel plate, the cathode electrode having a porous platinum electrode structure;
a porous anode sheet, a first anion exchange membrane and a bipolar membrane operatively positioned between the upper regeneration liquid channel (A) and the middle eluent channel (B); and
a porous cathode sheet and a second anion exchange membrane operatively positioned between the middle eluent channel (B) and the lower regeneration liquid channel (C);
whereby pure water entering the middle eluent channel inlet flows out of the middle eluent channel outlet after passing through the middle eluent channel (B),
pure acid regeneration liquid entering through the upper regeneration liquid channel inlet, and flows out of the upper regeneration liquid channel outlet after passing through the upper regeneration liquid channel (A) and enters the lower regeneration liquid channel inlet, passes through the lower regeneration liquid channel (C), flows out of the lower regeneration liquid channel outlet and is recovered as regeneration liquid.

8. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 7 , wherein the middle eluent channel (B) contains ion exchange screens or inert particles with a wide pH working range, or contains monolithic columns or fibers.

9. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 7 , wherein multi-layer and overlapping first anion exchange membranes and bipolar membranes are operatively positioned between the upper regeneration liquid channel (A) and the middle eluent channel (B).

10. The dual-membrane on-line generator for generating an acid or alkali solution according to claim 7 , wherein multi-layer and overlapping second anion exchange membranes ( 704 ) are operatively positioned between the middle eluent channel (B) and the lower regeneration liquid channel (C).

Assignees

• Univ East China Science & Tech
• Shimadzu China Co Ltd

Inventors

• Yang Bingcheng
• Zhang Feifang
• Lu Yifei
• Zhou Liting
• Huang Shujun

Classifications

• B01D61/465

  comprising the membrane sequence AB or BA, where B is a bipolar membrane · CPC title

• B01D61/466

  comprising the membrane sequence BC or CB · CPC title

• B01D61/445 Primary

  with bipolar membranes; Water splitting · CPC title

• C25B9/23 Primary

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title

• B01D61/46

  Apparatus therefor · CPC title