Methods and systems for providing corrosion resistant surfaces in contaminant treatment systems

Patent metadata

Field	Value
Publication number	US-11819802-B2
Application number	US-202217843164-A
Country	US
Kind code	B2
Filing date	Jun 17, 2022
Priority date	Dec 31, 2018
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

Systems and apparatuses for neutralizing acidic compounds in flue gases emitted from a heat recovery coke oven. A representative system includes a spray dry absorber having a barrel that includes a plurality of wall plates that form sidewalls of the barrel. The wall plates include a steel plate and a corrosion resistant alloy cladded to the steel plate and the wall plates are oriented such that the corrosion resistant alloy faces toward and is in fluid communication with an interior area of the barrel. The alloy is resistant to corrosion caused by the acidic compounds in the flue gas and can prevent the steel plate from being corroded by these acidic compounds.

First claim

We claim:

1. A system for treating acidic compounds in flue gases, the system comprising:
a barrel having sidewalls that define an interior area, wherein—
the barrel comprises a plurality of wall plates that form the sidewalls,
each of the plurality of wall plates comprises a corrosion-resistant alloy,
the wall plates are oriented such that the corrosion-resistant alloy is in fluid communication with the interior area of the barrel, and
the wall plates are configured to be in contact with a flue gas comprising acidic compounds.

2. The system of claim 1 , wherein the corrosion-resistance alloy is resistant to corrosion caused by oxygen species and/or halogen species.

3. The system of claim 2 , wherein the halogen species comprises chlorine.

4. The system of claim 1 , wherein the barrel comprises an outlet and the system further comprises:
a baghouse downstream of the barrel and fluidly coupled to the outlet of the barrel,
wherein at least a portion of the baghouse includes the alloy.

5. The system of claim 4 wherein the baghouse further comprises:
a plurality of filter bags configured to receive dust and particulate matter, wherein the filter bags are attached to a shaker mechanism that, in operation, shakes the filter bags and releases the trapped particulates into a hopper.

6. The system of claim 1 , wherein the alloy comprises a duplex alloy or a super duplex alloy.

7. The system of claim 1 , wherein the barrel further comprises an inlet configured to receive the flue gas, the inlet including an atomizer configured to spray a neutralizing agent, wherein, in operation, the neutralizing agent reacts with the acidic compounds of the flue gas.

8. The system of claim 7 , wherein the neutralizing agent comprises an alkaline solution and/or lime.

9. The system of claim 7 , wherein the inlet is at an upper portion of the barrel and the barrel further comprises an outlet at a lower portion of the barrel.

10. The system of claim 1 , wherein the barrel comprises a first section including a first cross-sectional dimension, and a second section downstream of the first section and including a second cross-sectional dimension smaller than the first cross-sectional dimension.

11. A spray dry absorber for treating acidic gases, the absorber comprising:
a barrel configured to receive acidic gases from an upstream industrial process, the barrel comprising sidewalls that define an interior area, wherein—
the interior area includes a first portion, a second portion downstream of and fluidically coupled to the first portion, and a third portion downstream of and fluidically coupled to the second portion,
the first portion includes an inlet configured to receive the acidic gases;
the second portion includes first plates, and
the third portion includes second plates.

12. The spray dry absorber of claim 11 , wherein the first plates and/or the second plates comprise a corrosion-resistant alloy including an Inconel alloy, an Incoloy alloy, a Monel alloy or a Hastelloy alloy.

13. The spray dry absorber of claim 11 , wherein one of the first plates includes a first corrosion-resistant alloy and one of the second plates includes a second corrosion-resistant alloy different than the first corrosion-resistant alloy.

14. The spray dry absorber of claim 11 , wherein the first plates and the second plates are oriented such that the first corrosion-resistant alloy and the second corrosion-resistant alloy are in fluid communication with the interior area.

15. The spray dry absorber of claim 11 , wherein the first section includes an atomizer configured to disperse a neutralizing agent, wherein, in operation, the neutralizing agent reacts with the acidic gases.

16. The system of claim 15 , wherein the neutralizing agent comprises an alkaline solution and/or lime.

17. The system of claim 15 , wherein the first section is above the second section and the second section is above the third section.

18. The system of claim 11 , wherein the first section includes a first cross-sectional dimension and the second section includes a second cross-sectional dimension smaller than the first cross-sectional dimension.

Assignees

• Suncoke Tech & Development Llc

Inventors

• Quanci John Francis
• Fernandez Mayela Carolina
• Charles Daniel C

Classifications

• B01D53/504 Primary

  characterised by a specific device · CPC title

• B01D53/505

  in a spray drying process · CPC title

• B01D53/68

  Halogens or halogen compounds · CPC title

• B01D53/79

  Injecting reactants · CPC title

• B01D53/80

  Semi-solid phase processes, i.e. by using slurries · CPC title