Thin film electroluminescent device, preparation method thereof, and electronic device

Patent metadata

Field	Value
Publication number	US-11818908-B2
Application number	US-201916971058-A
Country	US
Kind code	B2
Filing date	Sep 29, 2019
Priority date	Jul 5, 2019
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

A thin film electroluminescent device, a preparation method thereof, and an electronic device are provided. The thin film electroluminescent device includes a first electrode, a functional structural layer disposed on the first electrode, a second electrode disposed on the functional structural layer, and a cover layer disposed on a side of the second electrode away from the first electrode. The cover layer includes an ionic compound having a chemical formula of AX2, wherein A is selected from divalent metal, and X is selected from halogen.

First claim

What is claimed is:

1. A thin film electroluminescent device, comprising:
a first electrode;
a functional structural layer disposed on the first electrode;
a second electrode disposed on the functional structural layer; and
a cover layer disposed on a side of the second electrode away from the first electrode, wherein the cover layer comprises an ionic compound having a chemical formula of AX 2 , wherein A is selected from a divalent metal, and X is selected from halogen;

wherein the light emitting layer comprises a host material and a dopant material, the host material has the following structural formula:

the doping material has the following structural formula:

and
a mass ratio of the host material to the dopant material is 7:1: −9:1.

2. The thin film electroluminescent device according to claim 1 , wherein the divalent metal is one of zinc, magnesium, and tin, and the halogen is one of fluorine, chlorine, bromine, and iodine.

3. The thin film electroluminescent device according to claim 1 , wherein the cover layer has an extinction coefficient of visible light of 0.1 or less and a transmittance of visible light of 70% or more.

4. The thin film electroluminescent device according to claim 1 , further comprising a light extraction layer disposed between the second electrode and the cover layer, wherein the cover layer is vacuum evaporated on the light extraction layer on a side of the light extraction layer away from the second electrode, and material for the light extraction layer comprises at least one selected from the group consisting of the ionic compound, a carbazole derivative, a diphenylfuran derivative, an arylamine derivative, and a triazine derivative.

5. The thin film electroluminescent device according to claim 1 , wherein material for the first electrode and material of the second electrode comprise at least one of metal or a compound thereof, metal alloy, and conductive polymer.

6. The thin film electroluminescent device according to claim 1 , wherein the functional structural layer comprises:
a hole injection layer disposed on the first electrode;
a hole transport layer disposed on the hole injection layer;
a light emitting layer disposed on the hole transport layer;
an electron transport layer disposed on the light emitting layer;
an electron injection layer disposed on the electron transport layer; and
the second electrode disposed on the electron injection layer.

7. A preparation method for preparing the thin film electroluminescent device according to claim 1 , comprising:
providing a conductive glass having the first electrode on a surface of the conductive glass;
forming, by vacuum evaporation, the functional structural layer on the surface of the conductive glass having the first electrode;
forming, by vacuum evaporation, the second electrode on a side of the functional structure layer away from the first electrode; and
forming, by vacuum evaporation, the cover layer on the side of the second electrode away from the first electrode;
wherein the cover layer comprises the ionic compound having the chemical formula of AX 2 , wherein A is selected from the divalent metal, and X is selected from halogen.

8. The method according to claim 7 , wherein providing the conductive glass comprises sequentially ultrasonically washing the conductive glass using deionized water, acetone, or isopropanol, and then washing the conductive glass using a plasma cleaner, and forming the functional structure layer comprising sequentially forming a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer by vacuum evaporation.

9. An electronic device comprising the thin film electroluminescent device according to claim 1 .

Assignees

• Wuhan China Star Optoelectronics Semiconductor Display Tech Co Ltd
• Guangzhou Chinaray Optoelectronic Mat Ltd

Inventors

• Wang Xu
• Zhang Yue
• Li Xianjie
• Lee Munjae
• Li Tao
• Pan Junyou
• Tan Jiahui
• Yang Xi

Classifications

• H10K50/12 Primary

  comprising dopants · CPC title

• H10K50/858 Primary

  comprising refractive means, e.g. lenses · CPC title

• H10K50/15

  Hole transporting layers · CPC title

• H10K50/16

  Electron transporting layers · CPC title

• H10K50/171

  Electron injection layers · CPC title