Additives for winterization of paraffin inhibitors

Patent metadata

Field	Value
Publication number	US-11814575-B2
Application number	US-202218072647-A
Country	US
Kind code	B2
Filing date	Nov 30, 2022
Priority date	Jul 24, 2020
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

A winterized paraffin inhibitor, which is capable of being used for preventing the deposition of paraffins in hydrocarbon streams and capable of withstanding freezing or crystallization at freezing or sub-freezing temperatures, may be formed by adding an oxyalkylated branched aliphatic compound having 12 or more carbons to a high molecular weight aliphatic polymer paraffin inhibitor, the oxyalkylated branched aliphatic compound having 12 or more carbons being produced by the oxyalkylation of the branched aliphatic compound having 12 or more carbon atoms in which the branched aliphatic compound having 12 or more carbon atoms is grafted with a polyether via a ring-opening reaction, wherein the polyether is a polymer of ethylene oxide, propylene oxide, butylene oxide, and combinations thereof.

First claim

What is claimed is:

1. A winterized paraffin inhibitor formulation, the formulation comprising:
an oxyalkylated linear or branched aliphatic compound having 12 or more carbons; and
a high molecular weight aliphatic polymer paraffin inhibitor present in an amount ranging from 1 wt. % to about 70 wt. %, based on total weight of oxyalkylated linear or branched aliphatic compound and the high molecular weight aliphatic polymer paraffin inhibitor;

wherein the oxyalkylated linear or branched aliphatic compound is formed by the oxyalkylation of a linear or branched aliphatic compound having 12 or more carbon atoms that comprises grafting the linear or branched aliphatic compound having 12 or more carbon atoms with a polyether via a ring-opening reaction, and wherein the polyether is selected from a group consisting of a polymer of ethylene oxide, a polymer of propylene oxide, a polymer of butylene oxide, and combinations thereof, and
wherein the branched aliphatic compound comprises branches, each branch consists of aliphatic alkyl functional groups containing 2 to 28 carbon atoms and optionally functional groups selected from the group consisting of oxygen functional groups, nitrogen functional groups, sulfur functional groups, phosphorous functional groups, and combinations thereof, and
wherein the branched aliphatic compounds are grafted with a polyether is a crosslinked branched aliphatic compound, and wherein the branched aliphatic compound has 20 or more carbon atoms.

2. The winterized paraffin inhibitor formulation of claim 1 , wherein the formulation is a flowing liquid at a temperature of between about 0° C. and about −40° C.

3. The formulation of claim 2 , wherein the viscosity of the formulation ranges from about 5 cP at room temperature to about 60 cP at a temperature ranging from about −10° C. to about −30° C.

4. The winterized paraffin inhibitor formulation of claim 1 , wherein high molecular weight aliphatic polymer paraffin inhibitor is selected from a group consisting of olefin maleic esters, aliphatic olefin maleic imides, polyol-based polymers, acrylate-based polymers, methacrylate-based polymers, maleate-based polymers, and combinations thereof.

5. A method for inhibiting paraffin deposition in a crude oil stream containing paraffins, the method comprising:
introducing a winterized paraffin inhibitor comprising:
(1) an oxyalkylated linear or branched aliphatic compound having 12 or more carbons, wherein the oxyalkylated linear or branched aliphatic compound is formed by the oxyalkylation of a linear or branched aliphatic compound having 12 or more carbon atoms that comprises grafting the linear or branched aliphatic compound having 12 or more carbon atoms with a polyether via a ring-opening reaction, and wherein the polyether is selected from a group consisting of a polymer of ethylene oxide, a polymer of propylene oxide, a polymer of butylene oxide, and combinations thereof, and
wherein the branched aliphatic compound comprises branches, each branch consists of aliphatic alkyl functional groups containing 2 to 28 carbon atoms and optionally functional groups selected from the group consisting of oxygen functional groups, nitrogen functional groups, sulfur functional groups, phosphorous functional groups, and combinations thereof, and
wherein the branched aliphatic compounds are grafted with a polyether is a crosslinked branched aliphatic compound, and wherein the branched aliphatic compound has 20 or more carbon atoms; and

(2) a high molecular weight aliphatic polymer paraffin inhibitor to a hydrocarbon stream containing paraffins in an environment in which the temperature ranges from about 0° C. to −40° C., the high molecular weight aliphatic polymer paraffin inhibitor being present in an amount ranging from 1 wt. % to about 70 wt. %, based on total weight of oxyalkylated linear or branched aliphatic compound and the high molecular weight aliphatic polymer paraffin inhibitor; and

preventing paraffin deposition within the hydrocarbon stream.

6. The method of claim 5 where the high molecular weight aliphatic polymer paraffin inhibitor selected from the group consisting of olefin maleic esters, aliphatic olefin maleic imides, polyol-based polymers, acrylate-based polymers, methacrylate-based polymers and/or maleate-based polymers.

7. The method of claim 5 further comprising adding at least one other additive to the crude oil stream, where the at least one other additive is selected from the group consisting of coagulants, flocculants, corrosion inhibitors, viscosity reducers, winterizing agents different from the oxyalkylated linear or branched aliphatic compound, friction reducers, scale inhibitors, scale dissolvers, paraffin inhibitors, pour point depressants, asphaltene inhibitors, clay swelling inhibitors, biocides, antifoulants, flow back aids, surfactants, and combinations thereof.

Assignees

• Baker Hughes Oilfield Operations Llc

Inventors

• Mangadlao Joey Dacula
• Baron Holley
• Legaspi Felipe Mary Jane
• Zhang Lei

Classifications

• C09K8/524 Primary

  organic depositions, e.g. paraffins or asphaltenes · CPC title

• C08F265/04

  on to polymers of esters · CPC title

• C08F265/10

  on to polymers of amides or imides · CPC title

• C08F283/06

  on to polyethers, polyoxymethylenes or polyacetals {(C08F283/004 takes precedence)} · CPC title

• C08G59/20

  characterised by the epoxy compounds used · CPC title