High luminescence plastic scintillators

Patent metadata

Field	Value
Publication number	US-11795388-B2
Application number	US-202217881859-A
Country	US
Kind code	B2
Filing date	Aug 5, 2022
Priority date	Nov 21, 2018
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

A plastic scintillator includes a polymeric matrix comprising a primary fluorophore capable of forming an amorphous glass in its pure form. The primary fluorophore is also capable of generating luminescence in the presence of ionizing radiation and includes: a central species including silicon; a luminescent organic group bonded to the central species or to an optional organic linker group, the luminescent organic group including fluorene or an analog thereof; and the optional organic linker group, if present, is bonded to the central species and the luminescent organic group.

First claim

It is claimed:

1. A plastic scintillator comprising:
a polymeric matrix; and
a primary fluorophore;
wherein the primary fluorophore includes:
a central species including silicon; and
a luminescent organic group bonded to the central species or to an optional organic linker group, and the luminescent organic group includes a fluorene or an analog thereof; and

an anti-fog agent, wherein the anti-fog agent is a chemical species that includes:
a cyclic central group, which is aromatic, hetero-aromatic, aliphatic or hetero-aliphatic;
an oxygen-containing functional group; and
an optional linking group selected from the group consisting of: a C1 to C20 alkyl group, an ethylene glycol group, or polyethylene glycol group;
wherein if the optional linking group is not present, the cyclic central group is bonded directly to the oxygen-containing functional group; and if the optional linking group is present, the cyclic central group is bonded to the optional linking group, and the oxygen-containing functional group is also bonded to the optional linking group.

2. The plastic scintillator of claim 1 , wherein the polymeric matrix is selected from one or more polymers from the following group: a vinylaromatic polymer, and a polymer containing one or more carbonate groups.

3. The plastic scintillator of claim 1 , wherein the primary fluorophore is selected from the group consisting of one or more silyl-fluorene based molecules functionalized one or more times at one or more of the 2-, 7-, or 9-positions of the fluorene group.

4. The plastic scintillator of claim 3 , wherein the silyl group is attached to the 2-position of the fluorene group and other functional groups, if present, are selected from the group consisting of: aliphatic alkanes or alkenes, aromatic hydrocarbons, methoxy, hydroxy, amine, alkylamine, phenylamine, or analogs thereof, wherein alkyl chains in any of the functional groups have 1 to 20 carbon atoms.

5. The plastic scintillator of claim 1 , wherein the plastic scintillator includes the primary fluorophore in a range of 0.5% to 50% by weight of the plastic scintillator.

6. The plastic scintillator of claim 1 , wherein the plastic scintillator includes the primary fluorophore in a range of 50% to 99% by weight of the plastic scintillator.

7. The plastic scintillator of claim 1 , further comprising a 10 B-containing or an 6 Li containing compound including a group selected from the group consisting of:
carborane, boronic acid, boronic ester, boronic pinacol ester, borane, a lithium salt of an aliphatic or aromatic acid, lithium benzoate, or Li-oxazolecarboxylate, lithium benzoate, lithium biphenylcarboxylate, lithium salicylate, lithium phenylsalicylate, lithium alkoxybenzoic acid, or analogs thereof.

8. The plastic scintillator of claim 1 , further comprising an organometallic compound selected from the group of: metalloalkyl compounds, alkylmetallomethacrylates, alkylmetalloacrylates, metallomethacrylates, alkylmetallostyrenes, metalloacrylates, and metallostyrenes.

9. The plastic scintillator of claim 1 , wherein the plastic scintillator is capable of neutron and gamma pulse-shape discrimination at 1 keVee to 30 MeVee.

10. The plastic scintillator of claim 1 , wherein the plastic scintillator is capable of gamma-ray spectroscopy at 5 keVee to 1.3 MeVee.

11. A method of making a plastic scintillator comprising:
dissolving a primary fluorophore in a monomer;
then in-situ polymerizing the monomer via a radical addition mechanism or a condensation reaction;
wherein the primary fluorophore is capable of generating luminescence in the presence of ionizing radiation and is capable of forming an amorphous glass in its pure form, and includes:
a central species including silicon; and
a luminescent organic group bonded to the central species or to an optional organic linker group, the luminescent organic group including a fluorene or an analog thereof.

12. A method of making a scintillator comprising:
blending a polymer and a primary fluorophore with one or more of mechanical mixing, heating, or co-dissolution in a solvent to form a blended material; and
thermally processing the scintillator into a desired shape;
wherein the primary fluorophore is capable of generating luminescence in the presence of ionizing radiation and is capable of forming an amorphous glass in its pure form, and includes:
a central species including silicon; and
a luminescent organic group bonded to the central species or to an optional organic linker group, the luminescent organic group including fluorene or an analog thereof.

13. The method of claim 12 , wherein the thermally processing step comprises extruding or injection molding the polymer and primary fluorophor.

14. The method of claim 11 , wherein an anti-fog agent is dissolved in or mixed with the monomer prior to polymerizing.

15. The method of claim 11 , wherein the in-situ polymerizing of the monomer is conducted via a radical addition mechanism by addition of a radical initiator.

16. The method of claim 11 , comprising controlling a temperature and stirring of the polymerized monomer and primary fluorophore to achieve an unreacted monomer content of less than 2% by weight.

17. The method of claim 12 , comprising controlling a temperature and stirring of the polymer and primary fluorophore to achieve an unreacted monomer content of less than 2% by weight.

18. The method of claim 11 , wherein the primary fluorophore is selected from the group consisting of one or more silyl-fluorene based molecules functionalized one or more times at one or more of the 2-, 7-, or 9-positions of the fluorene group.

19. The method of claim 12 , wherein the primary fluorophore is selected from the group consisting of one or more silyl-fluorene based molecules functionalized one or more times at one or more of the 2-, 7-, or 9-positions of the fluorene group.

20. The method of claim 12 , further comprising blending an an anti-fog agent, wherein the anti-fog agent is a chemical species that includes:
a cyclic central group, which is aromatic, hetero-aromatic, aliphatic or hetero-aliphatic;
an oxygen-containing functional group; and
optionally, a linking group selected from the group consisting of: a C1 to C20 alkyl group, an ethylene glycol group, or polyethylene glycol group;
wherein if the optional linking group is not present, the cyclic central group is bonded directly to the oxygen-containing functional group; and if the optional linking group is present, the cyclic central group is bonded to the optional linking group, and the oxygen-containing functional group is also bonded to the optional linking group.

21. The method of claim 14 , wherein the anti-fog agent is a chemical species that includes:
a cyclic central group, which is aromatic, hetero-aromatic, aliphatic or hetero-aliphatic;
an oxygen-containing functional group; and
optionally, a linking group selected from the group consisting of: a C1 to C20 alkyl group, an ethylene glycol group, or polyethylene glycol group;
wherein if the optional linking group is not present, the cyclic central group is bonded directly to the oxygen-containing functional group; and if the optional linking group is present, the cyclic central group is bonded to the optional linking group, and the oxygen-containing functional group is also bonded to the optional linking group.

Assignees

• Nat Tech & Eng Solutions Sandia Llc

Inventors

• Myllenbeck Nicholas
• Feng Patrick L
• Carlson Joseph

Classifications

• C09K11/06 Primary

  containing organic luminescent materials · CPC title

• C09K11/025 Primary

  non-luminescent particle coatings or suspension media · CPC title

• G01T1/2033

  Selection of materials · CPC title

• C09K2211/1011

  Condensed systems · CPC title

• C09K2211/1014

  bridged by heteroatoms, e.g. N, P, Si or B · CPC title