Encapsulation of silica nanoparticle for release

Patent metadata

Field	Value
Publication number	US-11795107-B2
Application number	US-202016991845-A
Country	US
Kind code	B2
Filing date	Aug 12, 2020
Priority date	Aug 12, 2020
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

A method of producing a nanosilica-containing cement formulation, the method comprising the steps of mixing an amount of a determinant nanosilica particle and a functional coating; applying a dynamic initiator to trigger a reversible reaction of the functional coating to produce a reversible cage, where the reversible cage surrounds the determinant nanosilica particle to produce an encapsulated nanosilica; and mixing the encapsulated nanosilica and a cement formulation to produce the nanosilica-containing cement formulation.

First claim

That which is claimed is:

1. A method of using a nanosilica-containing cement in an well cementing operation, the method comprising the steps of:
mixing encapsulated nanosilica and a cement formulation to produce the nanosilica-containing cement formulation, where the encapsulated nanosilica comprises determinant nanosilica particles encapsulated by a reversible cage, where the reversible cage comprises a functional coating,
where the functional coating comprises a polyetheramine and a functional moiety selected from the group consisting of a furfuryl moiety, an anthracene moiety, a maleimide moiety, and combinations of the same,
where the reversible cage is formed through a reversible reaction selected from the group consisting of a reversible covalent reaction, a non-covalent reaction, and combinations of the same,
where the determinant nanosilica particles are selected from the group consisting of silica nanoparticles, functionalized silica nanoparticles, and combinations of the same;

pumping the nanosilica-containing cement formulation into the oil well;
increasing a temperature in the oil well to initiate the disintegration of the reversible cage, wherein the temperature is increased to greater than 130° C.;
exposing the determinant nanosilica particles due to the disintegration of the cage from the encapsulated nanosilica; and
reacting the determinant nanosilica particles with the cement formulation such that gelation of the cement formulation occurs.

2. The method of claim 1 , where the reversible reaction is a reversible covalent reaction selected from the group consisting of reversible hydrazone formation, reversible Schiff base formation, reversible aminal formation, reversible cyclization formations, reversible disulfide exchange, reversible dithioacetal exchange, reversibly dynamic boronic ester formation, reversible olefin metathesis, reversible metal-ligand association, and combinations of the same.

3. The method of claim 2 , where the reversible covalent reaction is a reversible cyclization formation comprising a reversible Diels-Alder condensation.

4. The method of claim 1 , where the reversible reaction is a non-covalent reaction selected from the group consisting of an electrostatic reaction, a hydrogen bonding reaction, a Van der Waals interaction, a charge-transfer complexation, ionic bonding interactions, and combinations of the same.

5. The method of claim 1 , where the polyetheramine is selected from the group consisting of a monoamine polyetheramine, a diamine polyetheramine, a triamine polyetheramine and combinations of the same.

6. The method of claim 1 , where the functionalized nanosilica particle comprises a functional compound and a silica nanoparticle, where the functional compound is selected from the group consisting of a maleimide moiety, a furfuryl moiety, an anthracene moiety, trimethoxysilanes, triethoxy silanes, trichlorosilanes, anyhydride functional silanes, epoxy functional silanes, isocyanate functional silanes, sulphur functional silanes, and combinations of the same.

Assignees

• Aramco Services Co
• Saudi Arabian Oil Co

Inventors

• Shanmugam Sivaprakash
• Boul Peter
• Thaemlitz Carl

Classifications

• C04B20/1037 Primary

  obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C01B33/18

  Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof (preparation of aerogels by dehydrating gels C01B33/158; treatment to enhance the pigmenting or filling properties C09C) · CPC title

• C04B14/062

  Microsilica, e.g. colloïdal silica (preparing microsilica slurries or suspensions C04B18/148) · CPC title

• C04B28/04

  Portland cements · CPC title

• C04B40/0032

  Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value (B28C7/00 takes precedence) · CPC title