Methods and system for manufacturing a redox flow battery system by roll-to-roll processing

Patent metadata

Field	Value
Publication number	US-11791479-B2
Application number	US-201916536259-A
Country	US
Kind code	B2
Filing date	Aug 8, 2019
Priority date	Aug 10, 2018
Publication date	Oct 17, 2023
Grant date	Oct 17, 2023

Abstract

Methods and systems are provided for manufacturing a membrane separator for a redox flow battery. In one example, the membrane separator is fabricate by a calendering process. The membrane separator may be configured with a polymer network to provide selectivity for ion transport across the membrane separator. The membrane separator may be further adapted with an integrated spacer in contact with a negative electrolyte.

First claim

The invention claimed is:

1. A method for manufacturing a redox flow battery, comprising:
combining and treating chemical ingredients configured to form a sheet of a membrane separator via a first roll-to-roll calendering process, the first roll-to-roll calendering process comprising:
forming the sheet from the combined chemical ingredients;
molding ribs onto a surface of the sheet, the ribs extending along a vertical axis of the membrane separator relative to placement of the membrane separator within a negative electrode compartment of the redox flow battery, wherein the ribs are configured to increase turbulence in electrolyte flow between the membrane separator and a negative electrode of the negative electrode compartment, and wherein the ribs extend one or more of at an angle to the vertical axis and sinuously across the membrane separator; and
infiltrating the sheet with a cross-linked polymer network by chemically activating a dilute solution of a cross-linked polymer gel stored in pores of the sheet followed by curing the chemically activated cross-linked polymer gel of the dilute solution, wherein the dilute solution includes a monomer of the cross-linked polymer gel, and wherein the monomer is one of 2-acrylamido-2-methylpropane sulfonic acid or a sodium 4-vinyl benzene sulfonate salt; and

arranging the membrane separator in a cell of the redox flow battery on a side of a positive electrode opposite of a bipolar plate, the bipolar plate formed by a second roll-to-roll calendering process with the positive electrode bonded thereto, wherein the bipolar plate is formed of a plurality of layers that are sewn together.

2. The method of claim 1 , wherein combining the chemical ingredients of the membrane separator includes adding the chemical ingredients to a twin-screw extruder.

3. The method of claim 2 , wherein treating the chemical ingredients of the membrane separator includes heating and compounding the chemical ingredients within the twin-screw extruder.

4. The method of claim 2 , wherein combining and treating the chemical ingredients includes adding an ultrahigh molecular weight polyethylene, silica, a plasticizer, and an ionomer to the twin-screw extruder.

5. The method of claim 4 , further comprising submerging the sheet in a solvent bath to remove the plasticizer prior to infiltrating the sheet with the cross-linked polymer network.

6. The method of claim 2 , wherein combining and treating the chemical ingredients includes adding the monomer of the cross-linked polymer gel to the twin-screw extruder.

7. The method of claim 6 , wherein chemically activating the dilute solution of the cross-linked polymer gel includes chemically activating a solution of less than 10 wt % of the monomer.

8. The method of claim 1 , wherein forming the sheet from the combined chemical ingredients includes extruding the chemical ingredients through a flat sheet die, and wherein forming the sheet further comprises cooling and pressing the sheet to have a uniform thickness.

9. The method of claim 8 , wherein molding ribs on the surface of the sheet includes passing the sheet through a set of calender rolls, at least one roll of the set of calender rolls including a textured outer surface, and wherein passing the sheet through the set of calender rolls imprints texture of the textured outer surface onto the surface of the sheet.

10. The method of claim 9 , wherein molding the ribs on the surface of the sheet includes molding a negative spacer of the redox flow battery onto the surface of the sheet, the negative spacer formed of a same material as the sheet.

11. The method of claim 1 , wherein infiltrating the sheet with the cross-linked polymer network includes submerging the sheet in the dilute solution of the cross-linked polymer gel, and wherein curing the polymerized cross-linked polymer gel includes forming a resin within pores of the membrane separator, the resin comprising the cross-linked polymer network.

12. The method of claim 1 , wherein curing the chemically activated cross-linked polymer gel includes one or more of heating the sheet and exposing the sheet to UV light.

13. The method of claim 1 , wherein the positive electrode is thermally bonded to one side of the bipolar plate.

14. The method of claim 1 , wherein a side of the bipolar plate, opposite of the positive electrode, is a negative electrode of the cell, and wherein the negative electrode is formed by prepregnating one of a carbon fiber sheet or a metallic mesh of the bipolar plate.

15. The method of claim 1 , wherein the plurality of layers of the bipolar plate comprises a first layer formed of carbon paper, a second layer formed of a thermoplastic, and a third layer formed of a felt, the second layer positioned between the first layer and the third layer.

16. The method of claim 15 , wherein the plurality of layers are sewn together using a conductive thread, and wherein the conductive thread forms conductive paths through the second layer.

17. The method of claim 16 , wherein heat is applied to the plurality of layers after the plurality of layers are sewn together to melt and seal the thermoplastic around the conductive thread and to bond each of the first layer and the third layer to the second layer.

Assignees

• Ess Technology Inc

Inventors

• Song Yang
• Evans Craig E

Classifications

• H01M8/0254 Primary

  corrugated or undulated · CPC title

• H01M8/0215

  Glass; Ceramic materials · CPC title

• H01M8/0221

  Organic resins; Organic polymers · CPC title

• H01M8/0226

  in the form of mixtures · CPC title

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title