Metal organic framework based water capture apparatus

Patent metadata

Field	Value
Publication number	US-11779903-B2
Application number	US-202217678780-A
Country	US
Kind code	B2
Filing date	Feb 23, 2022
Priority date	Aug 16, 2018
Publication date	Oct 10, 2023
Grant date	Oct 10, 2023

Abstract

An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent located in the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat, a reduced pressure or a combination thereof to the water adsorbent to desorb a water content from the water adsorbent.

First claim

The invention claimed is:

1. A water adsorbent configured to capture a water content from air, the water adsorbent comprising:
at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the air, wherein the at least one water adsorbent metal organic framework composite comprises at least 70 wt % water adsorbent metal organic framework and,
wherein the water adsorbent metal organic framework comprises:
a metal ion selected from the group consisting of Fe 3+ , Li + , Na + , Ca 2+ , Zn 2+ , Zr 4+ , Al 3+ , K + , Mg 2+ , Ti 4+ , Cu 2+ , Mn 2+ to Mn 7+ , Ag + , or combinations thereof; and
at least 0.1 wt % of a hydrophilic binder selected from the group consisting of an alkyl cellulose, a hydroxyalkyl cellulose, a carboxyalkyl cellulose derivative, or combinations thereof, and

wherein the at least one water adsorbent metal organic framework composite has an average surface area of at least 700 m 2 /g and is configured to adsorb a water content from the air.

2. The water adsorbent according to claim 1 , wherein the at least one metal organic framework composite comprises at least one of pellets, pills, spheres, granules, extrudates, honeycombs, meshes, hollow bodies, or combinations thereof.

3. The water adsorbent according to claim 1 , wherein the hydrophilic binder is selected from at least one of hydroxypropyl cellulose (HPC), hydroxypropyl cellulose, hydroxyethyl methyl cellulose, hydroxypropyl methyl cellulose (HPMC), ethyl hydroxyethyl cellulose, methyl cellulose, or carboxymethyl cellulose (CMC).

4. The water adsorbent according to claim 1 , comprising between 0.5 wt % and 3 wt % of the hydrophilic binder.

5. The water adsorbent according to claim 1 , comprising between 0.8 wt % and 2 wt % of the hydrophilic binder.

6. The water adsorbent according to claim 1 , wherein the at least one water adsorbent metal organic framework composite comprises at least one of a pellet, a coating, a plate, a sheet, or a strip.

7. The water adsorbent of according to claim 1 , wherein the at least one water adsorbent metal organic framework composite comprises a shaped water adsorbent composite body comprising an elongate body having a circular or regular polygonal cross-sectional shape.

8. The water adsorbent according to claim 1 , wherein the at least one water adsorbent metal organic framework comprises at least one of aluminium fumarate, MOF-801, MOF-841, CAU-10, MOF-303, MOF-573, MOF-802, MOF-805, MOF-806, MOF-808, MOF-812, or mixtures thereof.

9. The water adsorbent according to claim 1 , wherein the at least one water adsorbent metal organic framework composite has a particle size of less than 800 μm.

10. An apparatus for capturing a water content from air, the apparatus comprising:
a water adsorbent according to claim 1 ; and
a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat, a reduced pressure or a combination thereof to the water adsorbent to desorb a water content from the water adsorbent.

11. The apparatus of claim 10 , wherein the at least one water adsorbent metal organic framework composite comprises a coating applied to the surface of the water desorption arrangement or is in thermal conductive contact with the water desorption arrangement.

12. The apparatus according to claim 10 , wherein the water desorption arrangement includes at least one heat transfer arrangement in direct thermal conductive contact with the water adsorbent and the heat transfer arrangement is in thermal conductive contact with a heating device.

13. The apparatus according to claim 12 , wherein the heat transfer arrangement includes at least one heat transfer element that extends from the heating device to the water adsorbent.

14. The apparatus according to claim 12 , further including a condenser system for cooling the product gas flow from the water adsorbent, wherein the heating device comprises at least one peltier device, and each peltier device has a hot side and a cold side, with the hot side of each peltier device being in thermal communication with the at least one heat transfer arrangement, and the cold side of each peltier device forming part of the condenser system.

15. The apparatus of claim 14 , wherein the cold side of each peltier device is in thermal communication with at least one heat transfer arrangement.

16. The apparatus according to claim 14 , wherein the peltier device is capable of heating the packed bed to at least 50° C.

17. The apparatus according to claim 12 , wherein the water adsorbent is housed within or coated on at least part of the heat transfer arrangement.

18. A method of capturing a water content from air, comprising at least one cycle of:
feeding air over a water adsorbent according to claim 1 such that the water adsorbent adsorbs water from the air; and
applying heat, a reduced pressure or a combination thereof to the water adsorbent so to release at least a portion of the adsorbed water therefrom.

19. The method according to claim 18 , wherein the water adsorbent is a shaped water adsorbent metal organic framework having an average surface area of at least 700 m 2 /g.

Assignees

• Commw Scient Ind Res Org

Inventors

• Mulet Xavier
• Konstas Kristina
• Thornton Aaron
• Hesselmann Matthias
• Herrmann Stefan

Classifications

• B01J20/226 Primary

  Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF] (preparation of metal complexes containing carboxylic acid moieties C07C51/418; MOF's per se C07F) · CPC title

• B01D53/0423

  Beds in columns · CPC title

• B01D53/0438

  Cooling or heating systems · CPC title

• B01D53/261 Primary

  by adsorption · CPC title

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title