Metal organic framework based water capture apparatus

Patent metadata

Field	Value
Publication number	US-11471857-B2
Application number	US-202016881281-A
Country	US
Kind code	B2
Filing date	May 22, 2020
Priority date	Aug 16, 2018
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

An apparatus for capturing a water content from a water containing gas, the apparatus comprising: a housing having an inlet into which the water containing gas can flow; a water adsorbent enclosed within the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas, the metal organic framework composite comprising: at least 50 wt % water adsorbent metal organic framework; from 0.2 to 10 wt % magnetic particles having a mean particle diameter of less than 200 nm; and at least 0.1 wt % hydrophilic binder comprising a hydrophilic cellulose derivative; and a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement comprising an alternating current (AC) magnetic field generator located within and/or around the water adsorbent configured to apply an AC magnetic field to the water adsorbent.

First claim

We claim:

1. An apparatus for capturing a water content from a water containing gas, the apparatus comprising:
a housing having an inlet into which the water containing gas can flow;
a water adsorbent enclosed within the housing, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas, the metal organic framework composite comprising: at least 50 wt % water adsorbent metal organic framework; from 0.2 to 10 wt % magnetic particles having a mean particle diameter of less than 200 nm; and at least 0.1 wt % hydrophilic binder comprising a hydrophilic cellulose derivative; and
a water desorption arrangement in contact with and/or surrounding the water adsorbent, the water desorption arrangement being selectively operable between (i) a deactivated state, and (ii) an activated state in which the arrangement is configured to apply heat to the water adsorbent to desorb a water content from the water adsorbent,
wherein the water desorption arrangement comprises an alternating current (AC) magnetic field generator located within and/or around the water adsorbent configured to apply an AC magnetic field to the water adsorbent.

2. The apparatus according to claim 1 , wherein the hydrophilic binder comprises an alkyl cellulose, hydroxyalkyl cellulose, or carboxyalkyl cellulose derivative.

3. The apparatus according to claim 1 , wherein the hydrophilic binder is selected from at least one of hydroxypropyl cellulose (HPC), hydroxypropyl cellulose, hydroxyethyl methyl cellulose, hydroxypropyl methyl cellulose (HPMC), ethyl hydroxyethyl cellulose, methyl cellulose, or carboxymethyl cellulose (CMC).

4. The apparatus according to claim 1 , wherein the alternating current magnetic field generator comprises at least one induction coil located within and/or around a packed bed of shaped water adsorbent composite bodies.

5. The apparatus according to claim 1 , wherein the magnetic particles comprises a metal chalcogenide comprising a compound, ionic, or elemental form of that compound including a metal M selected from Li, Na, K, Rb, Be, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, B, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi, combined with an element C selected from at least one of O, S, Se, Te.

6. The apparatus according to claim 5 , wherein the magnetic particles comprise at least one of MgFe 2 O 4 , Fe 3 O 4 , C-coated Co, CoFe 2 O 4 , NiFe 2 O 4 , Pyridine-2,6-diamine-functionalized SiO 2 , or Pyridine-2,6-diamine-functionalized Fe 3 O 4 .

7. The apparatus according to claim 1 , comprising between 0.5 and 7 wt % magnetic particles.

8. The apparatus of claim 1 , wherein the metal organic framework composite comprises shaped water adsorbent composite body having at least one mean dimension of greater than 0.5 mm.

9. The apparatus of claim 8 , wherein the shaped water adsorbent composite body comprises an elongate body having a circular, or regular polygonal cross-sectional shape.

10. The apparatus according to claim 1 , wherein the water adsorbent metal organic framework comprises at least one of aluminium fumarate, MOF-801, MOF-841, M 2 Cl 2 BTDD, Co 2 Cl 2 BTDD, Cr-soc-MOF-1, MIL-101(Cr), CAU-10, alkali metal (Li + , Na + ) doped MIL-101(Cr), MOF-303, MOF-573, MOF-802, MOF-805, MOF-806, MOF-808, and MOF-812.

11. The apparatus according to claim 1 , wherein the water adsorbent metal organic framework includes a metal ion and a plurality of multidentate ligands of which at least one ligand is selected from fumarate or 3,5-pyrazoledicarboxylic acid (H3PDC) based ligands.

12. The apparatus according to claim 11 , wherein the metal ion is selected from Fe 3+ , Li + , Na + , Ca 2+ , Zn 2+ , Zr 4+ , Al 3+ , K + , Mg 2+ , Ti 4+ , Cu 2+ , Mn 2+ to Mn 7+ , Ag + , or a combination thereof.

13. The apparatus according to claim 1 , comprising between 0.2 and 5 wt % hydrophilic binder.

14. The apparatus according to claim 1 , wherein the water adsorbent metal organic framework has a mean particle size of between 20 and 100 μm.

15. The apparatus according to claim 1 , further comprising less than 0.5 wt % lubricant.

16. The apparatus according to claim 1 , wherein the water adsorbent comprises shaped water adsorbent composite bodies located in a packed bed in the housing packed at a density from 0.10 to 1.0 kg/L.

17. The apparatus according to claim 1 , wherein the water containing gas comprises ambient air, wherein the relative humidity of the ambient air is between 25 to 100% at 22° C.

18. A method of capturing a water content from a water containing gas, comprising at least one cycle of:
feeding a water containing gas through the inlet of a housing and over a water adsorbent enclosed within the housing such that the water adsorbent adsorbs water from the water containing gas, the water adsorbent comprising at least one water adsorbent metal organic framework composite capable of adsorbing a water content from the water containing gas, the metal organic framework composite comprising: at least 50 wt % water adsorbent metal organic framework; from 0.2 to 10 wt % magnetic particles having a mean particle diameter of less than 200 nm; and at least 0.1 wt % hydrophilic binder comprising a hydrophilic cellulose derivative,
operating at least one water desorption arrangement to change from an inactive state to an activated state to apply an alternating current magnetic field to a packed bed of shaped water adsorbent composite bodies, thereby generating heat within the shaped water adsorbent composite bodies, so to release at least a portion of the adsorbed water therefrom into a product fluid flow, and
directing the product fluid flow to a condenser system to separate a water content from the product fluid flow,

wherein the water desorption arrangement is in contact with and/or surrounding the water adsorbent.

19. The method according to claim 18 , wherein the method has a cycle time of less than 2 hours.

20. The method according to claim 18 , wherein the alternating current magnetic field is applied when the packed bed has adsorbed moisture equivalent to at least 75% of the saturation point of the packed bed.

Assignees

• Commw Scient Ind Res Org

Inventors

• Mulet Xavier
• Konstas Kristina
• Thornton Aaron
• Hesselmann Matthias
• Herrmann Stefan

Classifications

• B01J20/28007

  with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like (carbon nanostructures B01J20/205) · CPC title

• F25B2321/02

  using Peltier effects; using Nernst-Ettinghausen effects · CPC title

• B01J20/103

  comprising silica · CPC title

• B01J20/3425

  of sorbents or filter aids comprising organic materials · CPC title

• B01J20/28011

  Other properties, e.g. density, crush strength · CPC title