Phosphonite compounds as process stabilizers

Patent metadata

Field	Value
Publication number	US-11767413-B2
Application number	US-202017431446-A
Country	US
Kind code	B2
Filing date	Feb 20, 2020
Priority date	Feb 21, 2019
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

The present invention relates to a composition comprising one or more (co)polymers and one or more phosphonite compounds that contain cardanol moieties. Moreover, the present invention also refers to the use of the phosphonite compounds as process stabilizers, in particular refers to the use of such compounds for stabilizing and/or reducing the Yellowness Index of a (co)polymer composition exposed to heat and/or mechanical stress.

First claim

The invention claimed is:

1. A composition comprising:
A) one or more (co)polymers as component A;
B) one or more phosphonite compounds of formula (I) as component B

wherein, independently of one another
each R1 is independently from another a linear C13-17-alkyl;
R2 is selected from the group consisting of hydrogen, linear or branched C 1-18 -alkyl, linear or branched C 1-12 -alkoxy; and
R3 is selected from the group consisting of hydrogen, linear or branched C 1-18 -alkyl, linear or branched C 1-12 -alkoxy; and

C) optionally one or more (co)polymer additives as component C.

2. The composition of claim 1 , wherein R2 and R3 are independently from each other selected from the group consisting of hydrogen, linear or branched C 1-4 -alkyl, linear or branched C 1-4 -alkoxy.

3. The composition of claim 1 , wherein R2 and R3 are both hydrogen.

4. The composition of claim 1 , wherein R2 and R3 are both hydrogen and each R1 is a linear C 15 -alkyl.

5. The composition of claim 1 , wherein said composition comprises 300 to 2000 ppm of component B, based on the sum of components A, B and C in the composition.

6. The composition of claim 1 , wherein said composition is a thermoplastic molding mass.

7. The composition of claim 1 , wherein the (co)polymer component A is selected from the group consisting of polyolefins, styrene (co)polymers, polyurethanes, polyesters, polyamides, polyacetals and blends of two or more thereof.

8. The composition of claim 1 , wherein said composition comprises or consists of:
A) 89.8 to 99.97% by weight of one or more (co)polymers as component A;
B) 0.03 to 0.2% by weight of one or more phosphonite compounds of formula (I) as component B; and
C) 0 to 10% by weight of one or more (co)polymer additives as component C.

9. The composition of claim 1 , wherein said composition comprises or consists of:
A) 94.95 to 99.9% by weight of one or more (co)polymers as component A;
B) 0.05 to 0.1% by weight of one or more phosphonite compounds of formula (I) as component B, wherein, independently of one another
each R1 is independently from another a linear C 15 -alkyl;
R2 and R3 are both equal and are selected from the group consisting of hydrogen and linear or branched C 1-4 -alkyl; and

C) 0 to 5% by weight of one or more (co)polymer additives as component C.

10. The composition of claim 1 , wherein said composition comprises 500 to 700 ppm of component B, based on the sum of components A, B and C in the composition.

11. The composition of claim 1 , wherein said composition further comprises one or more (co)polymer additives as component C selected from the group consisting of antioxidants, acid scavengers UV stabilizers, UV absorbers, UV quenchers, antistatics, flame retardants, lubricants, plasticizers, nucleating agents, metal deactivators, biocides, impact modifiers, fillers, dyes, and pigments.

12. A method for stabilizing and/or reducing the Yellowness Index of a (co)polymer composition exposed to heat and/or mechanical stress during processing, wherein said method comprises the steps of:
(i) providing one or more (co)polymers as component A and one or more phosphonite compounds of formula (I) as component B according to claim 1 , and optionally one or more (co)polymer additives; and
(ii) melt processing the one or more (co)polymers of component A in the presence of component B.

13. The method of claim 12 , wherein 300 to 2000 ppm of component B, based on the sum of components A, B and C in the composition, are used.

14. The method of claim 12 , wherein the (co)polymer composition comprises one or more polyolefins as component A.

Assignees

• Clariant Int Ltd

Inventors

• Steffanut Pascal
• Bellemin-Laponnaz Stephane
• Bissessar Damien
• Achard Thierry

Classifications

• C08K5/5393 Primary

  Phosphonous compounds, e.g. R—P(OR')2 · CPC title

• C08K5/5333 Primary

  Esters of phosphonic acids · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L2207/062

  HDPE · CPC title

• C08L23/12

  Polypropene · CPC title