Integrating cavity of monolithic fumed silica

Patent metadata

Field	Value
Publication number	US-11761883-B2
Application number	US-202117245932-A
Country	US
Kind code	B2
Filing date	Apr 30, 2021
Priority date	Apr 30, 2021
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

A fumed silica monolithic integrating cavity device. The device is configured to facilitate optical measurements taken from a sample positioned within a cavity of the device. The cavity is defined by a fumed silica monolith with the added feature of a fused quartz lining on the surface of the monolith. This provides an intermediate surface that allows for cleaning and reuse of the highly effective diffuse light scattering fumed silica monolith. Furthermore, the lining may be placed under pressure or vacuum to structurally enhance mechanical integrity of the underlying monolith. Thus, continued or reliably repeated use of the device may be appreciated as well as use in more industrial environments that are prone to vibration.

First claim

We claim:

1. An integrating cavity device to facilitate optical measurements of a sample item therein, the device comprising:
an outer housing to attain light from an external source;
a diffusely reflective monolithic fumed silica accommodated by the outer housing and including a surface defining a cavity within the device, the cavity to receive the light; and
a substantially transparent liner of fused quartz on the surface of the fumed silica defining the cavity and in air-tight sealing communication therewith.

2. The integrating cavity device of claim 1 wherein the air-tight sealing communication of the liner to the fumed silica monolith supplies mechanical reinforcement thereto.

3. The integrating cavity device of claim 1 wherein the air-tight sealing communication of the liner to the fumed silica monolith is supplied under vacuum pressure relative the underlying monolith.

4. The integrating cavity device of claim 1 wherein the fumed silica monolith is rated at greater than 99.5% reflective over a spectrum of between about 220 nm and about 1,300 nm and greater than 99.8% between about 400 nm and about 700 nm.

5. The integrating cavity device of claim 1 wherein the outer housing comprises a primary body and a sample tray body, the monolithic fumed silica comprising a first and second monolithic fumed silica bodies with the liners thereon and accommodated by the primary and sample tray bodies respectively, the primary and sample tray bodies joining together to define the cavity between the monolithic fumed silica bodies.

6. The integrating cavity of claim 5 wherein the liner at the surface of the fumed silica monolith for the sample tray body is substantially translucent.

7. The integrating cavity of claim 6 wherein the liner at the surface of the fumed silica monolith for the sample tray body is one of frosted and opaque to mitigate light migration at a gap between the primary and sample tray bodies constituting the outer housing.

8. A measurement system for ascertaining optical characteristics of a sample item, the system comprising:
an integrating cavity device with a cavity defined by a light scattering monolithic comprised of one of fumed silica, barium sulfate and magnesium fluoride, the monolith having a substantially transparent liner of fused quartz thereover to further define the cavity and accommodate the sample item;
a light source to supply light to the cavity for the light scattering; and
a spectral detector to acquire scattered light readings from the cavity for sample item analysis.

9. The measurement system of claim 8 wherein the light source is a laser assembly accommodating a diode laser.

10. The measurement system of claim 8 wherein the supply of light to the cavity and the acquired light from the cavity are routed over fiber optics.

11. The measurement system of claim 10 further comprising a light pipe to the cavity to serve as an optical conduit.

12. The measurement system of claim 11 wherein the light pipe is a rod that is one of round, square, rectangular, tapered and hexagonal.

13. The measurement system of claim 11 wherein the light pipe is one of collimating and homogenizing.

14. The measurement system of claim 11 wherein the light pipe is of fused quartz.

15. A method of acquiring optical characteristics of a sample item, the method comprising:
projecting a light toward an integrating cavity device from an external source;
routing the light into a cavity of the device defined by a fumed silica monolith;
utilizing the fumed silica monolith to diffusely scatter the light across a transparent liner positioned over the monolith and accommodating the sample item;
acquiring the scattered light from the cavity; and
analyzing the acquired light to ascertain the optical characteristics of the sample item.

16. The method of claim 15 wherein the analyzing further comprises one of optical photometry, metrology and spectroscopy.

17. The method of claim 15 further comprising:
completing the acquiring of the scattered light;
removing the sample item from the cavity at the transparent liner;
cleaning the liner;
positioning another sample item within the cavity at the transparent liner; and
repeating each of the routing of the light, the utilizing of the fumed silica to diffusely scatter the light, the acquiring the scattered light and the analyzing of the acquired light to ascertain the optical characteristics of the other sample item.

18. The method of claim 15 further comprising fabricating the fumed silica monolith in a manner comprising:
packing a structure of fumed silica particles ranging from about 20 nm to about 50 nm in particle size into a monolith;
baking the monolith under pressure at between about 800 and about 1,000° C.; and
forming a cavity defining morphology into the monolith.

19. The method of claim 15 further comprising employing the liner to impart a vacuum on the underlying fumed silica monolith.

20. The method of claim 19 further comprising subjecting the integrating cavity device to a vibration condition during one of transport and use in an industrial environment.

Assignees

• Moore Thomas
• Retherford Kurt D
• Phillips Lander Charity
• Southwest Res Inst

Inventors

• Moore Thomas
• Retherford Kurt D
• Phillips-Lander Charity

Classifications

• G01N21/474 Primary

  Details of optical heads therefor, e.g. using optical fibres · CPC title

• G01N21/05 Primary

  Flow-through cuvettes (G01N21/09 takes precedence; handling fluid samples G01N1/10) · CPC title

• G01N2201/065

  Integrating spheres · CPC title

• G01N2201/08

  Optical fibres; light guides · CPC title

• G01N21/51

  inside a container, e.g. in an ampoule (G01N21/53 takes precedence) · CPC title