High reflectivity integrating cavity and optical amplification device

Patent metadata

Field	Value
Publication number	US-9927417-B2
Application number	US-201615001238-A
Country	US
Kind code	B2
Filing date	Jan 20, 2016
Priority date	Jan 16, 2015
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

Disclosed is a high reflectivity integrating cavity and device to amplify and detect luminescent emissions produced by small concentrations of materials to be analyzed. Femto or nano molar concentrations of a material can be placed within the high reflectivity integrating cavity. At least the interior surface of the high reflectivity integrating cavity can comprise a coating that, at a designated wavelength of electromagnetic radiation, is transparent and non-absorbing to such designated wavelengths of electromagnetic radiation. In addition to the isotropic field induced by the interior surface of the high reflectivity integrating cavity, the high reflectivity of the interior surface of the high reflectivity integrating cavity leads to very large effective optical path lengths within the interior of the high reflectivity integrating cavity, thereby amplifying the luminescent emissions produced by the sample.

First claim

We claim:

1. An apparatus for detecting compounds, the apparatus comprising:
a high reflectivity integrating cavity formed within the apparatus, the high reflectivity integrating cavity comprising an interior surface comprising a material that exhibits Lambertian behavior thereby generating an isotropic field within the high reflectivity integrating cavity, the isotropic field inducing a spectral emission in a volume of a sample placed within the high reflectivity integrating cavity, further comprising:
an upper portion with a first cavity formed into a bottom surface of the upper portion and a lower portion with a second cavity formed into an upper surface of the lower portion; and
wherein when the upper portion and the lower portion are stacked, the first cavity and the second cavity form the high reflectivity integrating cavity.

2. The apparatus of claim 1 , wherein at least the interior surface of the high reflectivity integrating cavity includes at least one of packed fumed silica, quartz powder, gold, and silver.

3. The apparatus of claim 2 , wherein the packed fumed silica, quartz powder, gold, or silver are deposited on the interior surface as a layer of nanoparticles to enhance scattering of radiation.

4. The apparatus of claim 1 , wherein at least the interior surface of the high reflectivity integrating cavity is comprised of a material that, at a designated wavelength of electromagnetic radiation, is transparent and non-absorbing and has a different index of refraction than air.

5. The apparatus of claim 1 , wherein the upper portion comprises an aperture formed through an upper surface of the upper portion.

6. The apparatus of claim 5 , wherein the lower portion comprises an aperture formed through a bottom surface of the lower portion.

7. The apparatus of claim 6 , further comprising:
a detector adapted to receive a spectral emission emitted by a material within the high reflectivity integrating cavity; and
wherein the detector, after receiving the spectral emission emitted by a material within the high reflectivity integrating cavity, can identify the material.

8. The apparatus of claim 7 , wherein the detector is a photomultiplier tube.

9. The apparatus of claim 5 , further comprising an input optical fiber coupled to the apparatus to introduce electromagnetic radiation into the high reflectivity integrating cavity.

10. The apparatus of claim 5 , further comprising:
an optical fiber to introduce light into the high reflectivity integrating cavity via the aperture and to sample an exponential decay of an irradiance on an interior surface of the high reflectivity integrating cavity;
a detector adapted to receive a spectral emission emitted by a material within the high reflectivity integrating cavity; and
wherein the detector facilitates identification of the material via the spectral emission.

11. The apparatus of claim 10 , wherein the detector is a photomultiplier tube.

12. The apparatus of claim 1 , wherein the spectral emission includes a Raman or a fluorescent emission.

Assignees

• Texas A & M Univ Sys

Inventors

• Yakovlev Vladislav Victorovich
• Fry Edward S
• Mason John David
• Bixler Joel Nathan
• Cone Michael Thomas
• Hokr Brett Harrison

Classifications

• G01N2201/0697

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• G01N2201/065

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• G01N2021/6469

  Cavity, e.g. ellipsoid · CPC title

• G01N21/39

  using tunable lasers · CPC title

• G01N33/1826 Primary

  Organic contamination in water · CPC title