Method for preparing high-entropy alloy composites reinforced by diamond particles

Patent metadata

Field	Value
Publication number	US-11761063-B2
Application number	US-202318097757-A
Country	US
Kind code	B2
Filing date	Jan 17, 2023
Priority date	Feb 12, 2022
Publication date	Sep 19, 2023
Grant date	Sep 19, 2023

Abstract

Disclosed is a method for preparing a high-entropy alloy composites reinforced by diamond particles, belonging to the technical field of metal composites preparation. A vacuum coating preparation equipment equipped with an in-situ heating sample stage is used to perform a treatment of high-entropy alloy metallizing coating on the surface of diamond particles to generate modified diamond particles, where the alloy of the coating includes any four, five or six elements among seven elements of Ti, Zr, Hf, Nb, Ta, W and Mo in an equal atomic proportion. The obtained coating generates carbide film in-situ with the surface layer of diamond particles, while the high-entropy alloy covers the carbide film, ensuring a strong bond with the diamond, and the high-entropy alloy composites reinforced by diamond particles are finally prepared.

First claim

What is claimed is:

1. A method for preparing a high-entropy alloy composites reinforced by diamond particles, comprising:
step 1, cleaning the diamond particles by boiling with diluted alkali solution and acid solution to remove oil, then washing with deionized water for 3-5 times to clean surfaces of the diamond particles to neutral, taking out and drying;
step 2, placing the diamond particles on a sample stage using a vacuum coating preparation equipment equipped with an in-situ heating sample stage, and performing high-entropy alloy metallizing coating on the surfaces of the diamond particles to obtain modified diamond particles, wherein the high-entropy alloy metallizing comprises elements of any four, five, or six of metal elements Ti, Zr, Hf, Nb, Ta, W, and Mo in an equal atomic ratio; and
step 3, adding the modified diamond particles obtained in the step 2 as a reinforcing phase into a high-entropy alloy matrix with same element types as the high-entropy alloy metallizing coating, then melting in a vacuum non-self-consuming arc melting furnace, evacuating the furnace to below 1.5×10 −3 pascal (Pa) and charging with argon to 0.5 atmosphere (atm), and dispersing the diamond particles uniformly and melting 6-8 times by electromagnetic stirring, then pouring and cooling to prepare the high-entropy alloy composites reinforced by diamond particles.

2. The method for preparing a high-entropy alloy composites reinforced by diamond particles according to claim 1 , wherein the alkali solution is 5 weight percentage (wt. %) NaOH, and the acid solution is 30 wt. % HNO 3 solution.

3. The method for preparing a high-entropy alloy composites reinforced by diamond particles according to claim 1 , wherein the diamond particles placed on the sample stage are heated to 400-900 degree Celsius (° C.) as applying the high-entropy alloy metallizing coating to the surfaces of the diamond particles.

4. The method for preparing a high-entropy alloy composites reinforced by diamond particles according to claim 1 , wherein the diamond particles placed on the sample stage are mechanically or electromagnetically vibrated for 30 seconds (s) to 1 minute (min) every 10 min-30 min.

Assignees

• Univ Taiyuan Technology

Inventors

• Wang Yongsheng
• Yu Shengwang
• Han Changxing
• Wang Naixu
• Zhou Bing
• Ma Yong
• Gao Jie
• Hei Hongjun
• Wu Yanxia

Classifications

• C22C1/101 Primary

  by coating · CPC title

• C23C14/223 Primary

  specially adapted for coating particles · CPC title

• C22C26/00 Primary

  Alloys containing diamond {or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes} · CPC title

• C22C1/1036

  starting from a melt · CPC title

• C22C30/00

  Alloys containing less than 50% by weight of each constituent · CPC title