Multijunction organic photovoltaics incorporating solution and vacuum deposited active layers

Patent metadata

Field	Value
Publication number	US-11744089-B2
Application number	US-201314414933-A
Country	US
Kind code	B2
Filing date	Jul 19, 2013
Priority date	Jul 19, 2012
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

There is disclosed an organic photovoltaic device comprising at least one first subcell comprising at least one first small molecular weight material deposited by solution processing, and at least one second subcell comprising a weight at least one second small molecular material deposited by vacuum evaporation. Also disclosed herein is a method for preparing an organic photovoltaic device comprising at least one first subcell comprising at least one first small molecular weight material and at least one second subcell comprising at least one second small molecular weight material, the method comprising depositing at least one first small weight material by solution processing; and depositing at least one second small weight material by vacuum evaporation.

First claim

What is claimed is:

1. An organic photovoltaic device, comprising:
at least one first subcell comprising a first donor-acceptor heterojunction, wherein the first donor-acceptor heterojunction comprises at least one solution processed first small molecular weight material;
at least one second subcell comprising a second donor-acceptor heterojunction, wherein the second donor-acceptor heterojunction comprises at least one vacuum evaporated second small molecular weight material,
wherein the at least one first small molecular weight material comprises a squaraine;
wherein the at least one first and second small molecular weight materials do not comprise a polymer material,
wherein the at least one vacuum evaporated second small molecular weight material is thereafter exposed to chloroform, and
wherein the power conversion efficiency of the organic photovoltaic device is improved by over 50% compared to the power conversion efficiency of each of the at least one first subcell and the at least one second subcell.

2. The organic photovoltaic device of claim 1 , wherein the device comprises more than two subcells.

3. The organic photovoltaic device of claim 1 , wherein the device comprises a two-terminal series architecture.

4. The organic photovoltaic device of claim 1 , wherein the device comprises a three-terminal series architecture.

5. The organic photovoltaic device of claim 1 , wherein the device comprises a four-terminal series architecture.

6. The organic photovoltaic device of claim 1 , wherein the squaraine comprises 2,4-bis[4-(N,N-diphenylamino)-2,6-dihydroxyphenyl]squaraine (DPSQ).

7. The organic photovoltaic device of claim 1 , wherein the at least one first subcell further comprises a vacuum evaporated material.

8. The organic photovoltaic device of claim 7 , wherein the vacuum evaporated material of the at least one first subcell comprises an acceptor layer.

9. The organic photovoltaic device of claim 1 , wherein the at least one second subcell further comprises a solution processed material.

10. The organic photovoltaic device of claim 1 , wherein the at least one second small molecular weight material comprises at least one acceptor material.

11. The organic photovoltaic device of claim 10 , wherein the at least one acceptor material is chosen from fullerene, 3,4,9,10-perylenetetracarboxylicbis-benzimidazole (PTCBI), phenyl-C 61 -butyric-acid-methyl ester ([60]PCBM), phenyl-C 71 -butyric-acid-methyl ester ([70]PCBM), thienyl-C 61 -butyric-acid-methyl ester ([60]ThCBM), and hexadecafluorophthalocyanine (F 16 CuPc).

12. The organic photovoltaic device of claim 11 , wherein the at least one acceptor material comprises C 70 .

13. The organic photovoltaic device of claim 1 , wherein the at least one second small molecular weight material comprises a small molecule:fullerene layer.

14. The organic photovoltaic device of claim 13 , wherein the at least one second small molecular weight material comprises a SubPc:fullerene layer.

15. The organic photovoltaic device of claim 1 , wherein the at least one first subcell and/or the at least one second subcell further comprises an electron blocking layer.

16. The organic photovoltaic device of claim 15 , wherein the electron blocking layer comprises at least one of BCP, BPhen, PTCBI, TPBi, Ru(acac) 3 , and Alq 2 OPH.

17. The organic photovoltaic device of claim 1 , wherein the at least one first subcell and/or the at least one second subcell further comprises a buffer layer.

18. The organic photovoltaic device of claim 1 , further comprising a charge recombination or a charge transfer layer between the at least one first subcell and the at least one second subcell.

19. A method of preparing an organic photovoltaic device comprising at least one first subcell comprising a first donor-acceptor heterojunction, wherein the first donor-acceptor heterojunction comprises at least one first small molecular weight material, and at least one second subcell comprising a second donor-acceptor heterojunction, wherein the second donor-acceptor heterojunction comprises at least one second small molecular weight material, the method comprising:
depositing the at least one first small molecular weight material by solution processing;
depositing the at least one second small molecular weight material by vacuum evaporation; and
exposing the at least one vacuum evaporated second small molecular weight material to chloroform,
wherein the at least one first small molecular weight material comprises a squaraine; and
wherein the at least one first and second small molecular weight materials do not comprise a polymer material.

20. The method of claim 19 , wherein the solution processing is spin-coating, doctor-blading, spray-coating, inkjet printing, or transfer printing.

21. The method of claim 19 , wherein the vacuum evaporation is vacuum thermal evaporation or organic vapor phase deposition.

22. The method of claim 19 , wherein the squaraine comprises 2,4-bis[4-(N,N-diphenylamino)-2,6-dihydroxyphenyl]squaraine (DPSQ).

23. The method of claim 19 , wherein the at least one first subcell further comprises at least one acceptor material, the method further comprising depositing the at least one acceptor material by vacuum evaporation.

24. The method of claim 19 , wherein the at least one second small molecular weight material comprises a small molecule:fullerene layer.

Assignees

• Univ Michigan Regents

Inventors

• Forrest Stephen R
• Lassiter Brian

Classifications

• H10K30/50

  Photovoltaic [PV] devices · CPC title

• Y02E10/549

  Organic PV cells · CPC title

• H10K30/211 Primary

  comprising multiple junctions, e.g. double heterojunctions · CPC title

• H10K85/322

  comprising boron · CPC title

• H10K30/353

  comprising blocking layers, e.g. exciton blocking layers · CPC title