Method of producing metal oxides with increased electrical conductivity

Patent metadata

Field	Value
Publication number	US-11739438-B2
Application number	US-202016863078-A
Country	US
Kind code	B2
Filing date	Apr 30, 2020
Priority date	Apr 30, 2019
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

A method for increasing the conductivity of a metal oxide with crystal structure belonging to the 4/m 3 2/m point group is provided. Single crystal oxides with crystal structure belonging to 4/m 3 2/m point group are contacted with nitrogen gas, with oxygen gas, with nitrogen gas, with oxygen gas, then with nitrogen gas to increase the conductivity of the metal oxide with crystal structure belonging to the 4/m 3 2/m point group.

First claim

We claim:

1. A method for increasing the conductivity of an oxide with crystal structure belonging to the 4/m 3 2/m point group comprising:
(a) providing a single crystal metal oxide with crystal structure belonging to 4/m 3 2/m point group,
(b) contacting the single crystal metal oxide with crystal structure belonging to 4/m 3 2/m point group with nitrogen gas at a temperature in the range of at least ambient temperature to at most 80° C. thereby providing a first nitrogen contacted metal oxide;
(c) contacting the first nitrogen contacted metal oxide with oxygen gas at a temperature in the range of at least ambient temperature to at most 80° C. thereby providing a first oxygen contacted metal oxide;
(d) contacting the first oxygen contacted metal oxide with nitrogen gas at a temperature in the range of at least ambient temperature to at most 80° C. thereby providing a second nitrogen contacted metal oxide;
(e) contacting the second nitrogen contacted metal oxide with oxygen gas at a temperature in the range of at least 40° C. to at most 80° C. thereby providing a second oxygen contacted metal oxide; and
(f) contacting the second oxygen contacted metal oxide with nitrogen gas at a temperature in the range of at least 40° C. to at most 80° C. thereby providing an increased conductivity crystalline metal oxide with a crystal structure belonging to 4/m 3 2/m point group oxide.

2. The method of claim 1 wherein the single crystal metal oxide with crystal structure belonging to 4/m 3 2/m point group have a purity of at least 98%.

3. The method of claim 1 wherein the single crystal metal oxide with crystal structure belonging to 4/m 3 2/m point group contains an element selected from the group consisting of group 1, 2, 3, and 4 elements of the periodic table of elements.

4. The method of claim 2 wherein the single crystal metal oxide with crystal structure belonging to 4/m 3 2/m point group contains an element selected from the group consisting of group 1, 2, 3, and 4 elements of the periodic table of elements.

5. The method of claim 1 wherein in step (b) the nitrogen gas is contacted at a temperature in the range of at least 30° C. to at most 60° C.

6. The method of claim 5 wherein in step (c) the oxygen gas is contacted at a temperature in the range of at least 30° C. to at most 60° C.

7. The method of claim 6 wherein in step (d) the nitrogen gas is contacted at a temperature in the range of at least 40° C. to at most 60° C.

8. The method of claim 1 wherein the single crystal metal oxide with crystal structure belonging to 4/m 3 2/m point group is selected from the group consisting of sodium oxide, hafnium oxide, titanium oxide, nickel oxide, manganese oxide, and all the alkaline earth metal oxides.

9. The method of claim 2 wherein the single crystal metal oxide with crystal structure belonging to 4/m 3 2/m point group have a purity of at least 99%.

Assignees

• Shell Oil Co
• Shell Usa Inc

Inventors

• Kandianis Michael
• Pluemper Oliver

Classifications

• C30B33/02 Primary

  Heat treatment (C30B33/04, C30B33/06 take precedence) · CPC title

• C01F5/02

  Magnesia · CPC title

• C30B29/16

  Oxides · CPC title

• C01P2002/77

  by unit-cell parameters, atom positions or structure diagrams · CPC title

• C01P2006/40

  Electric properties · CPC title