External loop slurry reactor

Patent metadata

Field	Value
Publication number	US-11738318-B2
Application number	US-201916976442-A
Country	US
Kind code	B2
Filing date	Sep 24, 2019
Priority date	Sep 19, 2019
Publication date	Aug 29, 2023
Grant date	Aug 29, 2023

Abstract

The present invention discloses an external loop slurry reactor, comprising a gas-liquid integrated distributor, a riser, a degassing zone, a solid-liquid separation circulation unit, and a storage tank. When the reactor works, reactants are injected into the riser through the gas-liquid integrated distributor; the slurry mixes and flows upwards to the degassing zone at the top for gas removal, and a large number of bubbles are removed. The slurry with catalyst particles then enters a downcomer and flows downwards. The slurry flows into a first-stage hydrocyclone and a multi-stage hydrocyclone in sequence for solid-liquid separation. The diameter of the first-stage hydrocyclone is larger than that of the multi-stage hydrocyclone. The separated solid particles flow back into the riser to continue to participate in the reaction.

First claim

What is claimed is:

1. An external loop slurry reactor, comprising a gas-liquid integrated distributor, a riser, a degassing zone, at least one solid-liquid separation circulation unit, and a storage tank, wherein: the gas-liquid integrated distributor is provided under the degassing zone; two ends of the riser are connected to the gas-liquid integrated distributor and the degassing zone, respectively; a diameter of the degassing zone is larger than that of the riser; each of the at least one solid-liquid separation circulation unit comprises a downcomer, a first-stage hydrocyclone, and a multi-stage hydrocyclone; a lower end of the downcomer of one solid-liquid separation circulation unit of the at least one solid-liquid separation circulation unit is connected to an inlet of the first-stage hydrocyclone, and an upper end of the downcomer of the one solid-liquid separation circulation unit is connected to the degassing zone when the at least one solid-liquid separation circulation unit comprises the one solid-liquid separation circulation unit; when the at least one solid-liquid separation circulation unit comprises two or more solid-liquid separation circulation units, the two or more solid-liquid separation circulation units are provided in an axial direction of the riser in sequence, and the one solid-liquid separation circulation unit is at a top, and the upper end of the downcomer of the one solid-liquid separation circulation unit is connected to the degassing zone while an upper end of the downcomer of each of remaining ones of the two or more solid-liquid separation circulation units is connected to the riser; a first overflow port at a top of the first-stage hydrocyclone is connected to an inlet of the multi-stage hydrocyclone; a second overflow port at a top of the multi-stage hydrocyclone is connected to the storage tank; a first underflow ports at a bottom of the first-stage hydrocyclone and a second underflow port at a bottom of the multi-stage hydrocyclone are both connected to the riser, and a diameter of the first-stage hydrocyclone is larger than that of the multi-stage hydrocyclone.

2. The external loop slurry reactor according to claim 1 , wherein the riser and the downcomer of each of the at least one solid-liquid separation circulation unit are each provided with a heat exchangers.

3. The external loop slurry reactor according to claim 1 , wherein: a circulating pump is provided between the multi-stage hydrocyclone of each of the at least one solid-liquid separation circulation unit and the storage tank.

4. The external loop slurry reactor according to claim 1 , wherein: the downcomer of each of the at least one solid-liquid separation circulation unit comprises an inclined section and a vertical section which are connected; the vertical section is connected to the inlet of the first-stage hydrocyclone; the inclined section is connected to the degassing zone or the riser, and the inclined section is provided obliquely downward from the degassing zone or the riser toward the vertical section.

5. The external loop slurry reactor according to claim 4 , wherein: the first-stage hydrocyclone and the multi-stage hydrocyclone are connected to the riser through two connecting pipelines, respectively; the two connecting pipelines are provided obliquely downward from the first-stage hydrocyclone or the multi-stage hydrocyclone toward the riser.

6. The external loop slurry reactor according to claim 1 , wherein: the degassing zone comprises a circular truncated cone section and a cylindrical section which are connected; a small-diameter end of the circular truncated cone section is connected to the riser, and a large-diameter end of the circular truncated cone section is connected to the cylindrical section.

7. The external loop slurry reactor according to claim 1 , wherein: the multi-stage hydrocyclone comprises a plurality of hydrocyclone groups; the plurality of hydrocyclone groups are connected in series and diameters of the plurality of hydrocyclone groups gradually decreases, and each of the plurality of hydrocyclone groups comprises a plurality of hydrocyclones with a same diameter connected in parallel.

8. The external loop slurry reactor according to claim 2 , wherein: the multi-stage hydrocyclone comprises a plurality of hydrocyclone groups; the plurality of hydrocyclone groups are connected in series and diameters of the plurality of hydrocyclone groups are gradually reduced, and each of the plurality of hydrocyclone groups comprises a plurality of hydrocyclones with a same diameter connected in parallel.

9. The external circulation slurry bed reactor according to claim 3 , wherein: the multi-stage hydrocyclone comprises a plurality of hydrocyclone groups; the plurality of hydrocyclone groups are connected in series and diameters of the plurality of hydrocyclone groups are gradually reduced, and each of the plurality of hydrocyclone groups comprises a plurality of hydrocyclones with a same diameter connected in parallel.

10. The external circulation slurry bed reactor according to claim 4 , wherein: the multi-stage hydrocyclone comprises a plurality of hydrocyclone groups; the plurality of hydrocyclone groups are connected in series and diameters of the plurality of hydrocyclone groups are gradually reduced, and each of the plurality of hydrocyclone groups comprises a plurality of hydrocyclones with a same diameter connected in parallel.

11. The external circulation slurry bed reactor according to claim 5 , wherein: the multi-stage hydrocyclone comprises a plurality of hydrocyclone groups; the plurality of hydrocyclone groups are connected in series and diameters of the plurality of hydrocyclone groups are gradually reduced, and each of the plurality of hydrocyclone groups comprises a plurality of hydrocyclones with a same diameter connected in parallel.

12. The external circulation slurry bed reactor according to claim 6 , wherein: the multi-stage hydrocyclone comprises a plurality of hydrocyclone groups; the plurality of hydrocyclone groups are connected in series and diameters of the plurality of hydrocyclone groups are gradually reduced, and each of the plurality of hydrocyclone group comprises a plurality of hydrocyclones with a same diameter connected in parallel.

Assignees

• Qingdao Inst Bioenergy & Bioprocess Tech Cas
• Inst Process Eng Cas

Inventors

• Huang Qingshan
• Chen Aqiang
• Geng Shujun
• Xiao Hang
• Yang Chao

Classifications

• B01J8/228 Primary

  externally, i.e. the particles leaving the vessel and subsequently re-entering it · CPC title

• B01J8/0055

  using cyclones · CPC title

• B01J8/1836

  Heating and cooling the reactor (B01J8/42 takes precedence) · CPC title

• B01J19/2435

  Loop-type reactors · CPC title

• B01J2208/00548

  Flow · CPC title