Method for monitoring the level of an ethylene polymerization catalyst slurry

Patent metadata

Field	Value
Publication number	US-9839892-B2
Application number	US-201514677348-A
Country	US
Kind code	B2
Filing date	Apr 2, 2015
Priority date	Dec 18, 2009
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

An apparatus may include a mud pot and a reflectometer to monitor a level of an interface between liquid diluent and catalyst slurry in the mud pot using reflectometry. The apparatus may include a mixing tank and a conduit to transfer catalyst slurry from the mud pot to the mixing tank. The apparatus may include a polymerization reactor and a conduit to provide catalyst slurry from the mixing tank to the polymerization reactor.

First claim

The invention claimed is:

1. An apparatus comprising:
a mud pot comprising a frustoconical bottom portion and a catalyst inlet which is concentric with the central longitudinal axis of the mud pot, wherein the mud pot contains at least a catalyst slurry and a liquid diluent; and
a reflectometer disposed adjacent to the catalyst inlet, the reflectometer adapted to monitor a level of an interface between the liquid diluent and the catalyst slurry in the mud pot using reflectometry.

2. The apparatus of claim 1 , wherein the reflectometer is adapted to monitor the level of the interface between liquid diluent and catalyst slurry in the mud pot using Time Domain reflectometry.

3. The apparatus of claim 2 , wherein the reflectometer is adapted to monitor the level of the interface using radar based Time Domain reflectometry.

4. The apparatus of claim 1 , wherein the reflectometer is adapted to monitor the level of the interface using Frequency Domain reflectometry.

5. The apparatus of claim 1 , wherein the reflectometer is a reflex radar level gauge adapted to use Time Domain reflectometry.

6. The apparatus of claim 1 , wherein the reflectometer is adapted to measure electromagnetic energy having a power of at most 2 Watt reflected from the interface.

7. The apparatus of claim 1 , wherein the reflectometer is adapted to provide electromagnetic pulses of two nanoseconds.

8. The apparatus of claim 1 , wherein the reflectometer comprises
a transmitter adapted to transmit a short rise time pulse of electromagnetic energy into the mud pot;
a receiver adapted to receive a signal of reflected electromagnetic energy from solid catalyst particles in the mud pot; and
a processing unit, wherein the receiver is adapted to send the signal to the processing unit, and wherein the processing unit is adapted to compute a distance to the solid catalyst particles.

9. The apparatus of claim 1 , further comprising a propagation device adapted to guide electromagnetic energy from the reflectometer into the mud pot and to guide reflected electromagnetic energy from the mud pot to the reflectometer.

10. The apparatus of claim 1 , further comprising a flange connecting the reflectometer to the mud pot, wherein the flange is positioned between a sensor of the reflectometer and a propagation device of the reflectometer, and wherein the propagation device is adapted to guide electromagnetic energy from the reflectometer into the mud pot.

11. The apparatus of claim 1 , wherein the mud pot has a cylindrical body with a frustoconical bottom portion.

12. The apparatus of claim 11 , wherein the frustoconical bottom portion has an opening angel α of at most 65°.

13. The apparatus of claim 1 , wherein the mud pot has a length to width ratio of at least 3.

14. The apparatus of claim 1 , wherein the mud pot comprises a solid catalyst inlet that is concentric with a central longitudinal axis of the mud pot.

15. The apparatus of claim 1 , further comprising a catalyst supply vessel adapted to transfer catalyst to the mud pot through a solid catalyst inlet of the mud pot.

16. The apparatus of claim 1 , wherein the mud pot comprises a liquid diluent inlet vertically extending from a top of the mud pot into the catalyst slurry.

17. The apparatus of claim 1 , further comprising:
a mixing tank; and
a conduit adapted to transfer catalyst slurry from the mud pot to the mixing tank.

18. The apparatus of claim 17 , further comprising:
a polymerization reactor; and
one or more conduits adapted to provide catalyst slurry from the mixing tank to the polymerization reactor.

19. An apparatus comprising:
a mud pot comprising a frustoconical bottom portion and a catalyst inlet which is concentric with the central longitudinal axis of the mud pot, wherein the mud pot contains at least a catalyst slurry and a liquid diluent, wherein the catalyst slurry comprises a metallocene catalyst or a chromium catalyst; and
a reflectometer disposed adjacent to the catalyst inlet and which is adapted to monitor a level of an interface between the liquid diluent and the catalyst slurry in the mud pot using reflectometry.

20. An apparatus comprising:
a mud pot comprising a frustoconical bottom portion and a catalyst inlet which is concentric with the central longitudinal axis of the mud pot, where the mud pot contains at least a catalyst slurry and a liquid diluent, wherein the catalyst slurry comprises a metallocene catalyst or a chromium catalyst;
a reflectometer disposed adjacent to the catalyst inlet and which is adapted to monitor a level of an interface between the liquid diluent and the catalyst slurry in the mud pot using reflectometry;
a mixing tank and a conduit adapted to transfer catalyst slurry from the mud pot to the mixing tank; and
a polymerization reactor and one or more conduits adapted to provide catalyst slurry from the mixing tank to the polymerization reactor.

Assignees

• Total Res & Technology Feluy

Inventors

• Fouarge Louis
• Brusselle Alain

Classifications

• G01S13/88

  Radar or analogous systems specially adapted for specific applications (electromagnetic prospecting or detecting of objects, e.g. near-field detection, G01V3/00) · CPC title

• B01J8/228

  externally, i.e. the particles leaving the vessel and subsequently re-entering it · CPC title

• B01J8/0035

  Periodical feeding or evacuation · CPC title

• G01F23/284

  Electromagnetic waves · CPC title

• B01J2208/00769

  Details of feeding or discharging · CPC title