Polarizing plate protective film, polarizing plate, and liquid crystal display device

Patent metadata

Field	Value
Publication number	US-11733435-B2
Application number	US-202016822367-A
Country	US
Kind code	B2
Filing date	Mar 18, 2020
Priority date	Sep 29, 2017
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

Provided are a polarizing plate protective film including a resin and a coloring agent having an absorption maximum wavelength in a range of 560 to 620 nm or 460 to 520 nm in an amount of 0.1 parts by mass or more with respect to 100 parts by mass of the resin, in which a film thickness is 1 to 18 μm, and a moisture content is 0.5% by mass or less, a polarizing plate in which the protective film is used, and a liquid crystal display device in which the polarizing plate is used.

First claim

What is claimed is:

1. A polarizing plate protective film comprising:
a resin; and
a coloring agent having an absorption maximum wavelength in a range of 560 to 620 nm or 460 to 520 nm in an amount of 0.1 parts by mass or more with respect to 100 parts by mass of the resin,
wherein a film thickness is 2 to 8 μm, and a moisture content is 0.5% by mass or less, and
wherein the coloring agent is a squarine-based coloring agent represented by General Formula (3)

wherein in General Formula (3), R 1 and R 2 each independently represent a hydrogen atom or a substituent, B 1 to B 4 each independently represent a carbon atom or a nitrogen atom, and R 3 and R 4 each independently represent a hydrogen atom or a substituent.

2. The polarizing plate protective film according to claim 1 ,
wherein the polarizing plate protective film contains an electron-donating quencher, and a HOMO energy level of the coloring agent and a HOMO energy level of the electron-donating quencher satisfy a relational expression [A-1] below,
E Hq −E Hd ≤0.40 eV  relational expression [A-1]:

here, E Hd and E Hq each represent values below,
E Hd : HOMO energy level of coloring agent
E Hq : HOMO energy level of electron-donating quencher.

3. The polarizing plate protective film according to claim 1 ,
wherein the polarizing plate protective film contains an electron-accepting quencher, and a LUMO energy level of the coloring agent and a LUMO energy level of the electron-accepting quencher satisfy a relational expression [B-1] below,
E Ld −E Lq ≤0 eV  relational expression [B-1]:

here, E Ld and E Lq each represent values below,
E Ld : LUMO energy level of coloring agent
E Lq : LUMO energy level of electron-accepting quencher.

4. The polarizing plate protective film according to claim 1 ,
wherein the resin satisfies a relational expression [C] below,
0.80 ≤fd ≤0.95  relational expression [C]:

here, an fd value is defined by a relational expression I below,
fd=δd /(δ d+δp+δh )  relational expression I:

in the relational expression I, δd, δp, and δh each represent a term corresponding to the London dispersion force, a term corresponding to the dipole-dipole force, and a term corresponding to the hydrogen bond force relative to a solubility parameter δt computed by the Hoy method.

5. The polarizing plate protective film according to claim 1 , wherein the resin includes a polystyrene resin.

6. The polarizing plate protective film according to claim 1 , wherein the resin includes a cyclic polyolefin resin.

7. A polarizing plate comprising:
the polarizing plate protective film according to claim 1 .

8. A liquid crystal display device comprising:
the polarizing plate according to claim 7 .

9. The liquid crystal display device according to claim 8 ,
wherein the polarizing plate protective film in the polarizing plate is disposed between a liquid crystal cell and a polarizer.

Assignees

• Fujifilm Corp

Inventors

• Fukagawa Nobutaka
• Naito Yu
• Kuwahara Hiroki
• Sasaki Daisuke
• Furuyama Hidetomo
• Chikushi Natsuru

Classifications

• G02B1/14 Primary

  Protective coatings, e.g. hard coatings · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08K5/3445

  Five-membered rings · CPC title

• G02F1/133528

  Polarisers · CPC title

• C08J2325/06

  Polystyrene · CPC title