Polarizing plate composition, polarizing plate protective film, polarizer, polarizing plate, liquid crystal display device, and compound used in the liquid crystal display device

Patent metadata

Field	Value
Publication number	US-2016369115-A1
Application number	US-201615254649-A
Country	US
Kind code	A1
Filing date	Sep 1, 2016
Priority date	Mar 5, 2014
Publication date	Dec 22, 2016
Grant date	—

Abstract

Provided are a polarizing plate composition, a polarizing plate protective film, a polarizer, a polarizing plate, and a liquid crystal display device, which contain a compound represented by the following Formula (I), and a compound.

In Formula (I), each of R 1 and R 2 represents a substituent. X represents an electron-withdrawing group, and Y represents a substituent having a heteroatom or a carbon atom as an atom bonded to a carbon atom substituted with —OR 1 . Y and X may form a ring by being bonded to each other.

First claim

What is claimed is:

1 . A polarizing plate composition comprising a compound represented by the following Formula (I),

wherein in Formula (I), each of R 1 and R 2 independently represents a substituent: X represents an electron-withdrawing group; Y represents a substituent having a heteroatom or a carbon atom as an atom bonded to a carbon atom substituted with —OR 1 ; and Y and X may form a ring by being bonded to each other.

2 . The polarizing plate composition according to claim 1 ,
wherein R 1 is a methylene group substituted with a heteroatom, an ethylene group substituted with an electron-withdrawing group, an acyl group, a carbamoyl group in which at least one of hydrogen atoms is substituted with a group independently selected from an alkyl group, a cycloalkyl group, or an aryl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a silyl group, or an alkylsulfonyl or arylsulfonyl group.

3 . The polarizing plate composition according to claim 1 ,
wherein R 2 is an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, a nitro group, a heterocyclic group, or a halogen atom.

4 . The polarizing plate composition according to claim 1 ,
wherein the compound represented by Formula (I) is represented by the following Formula (II),

in Formula (II), each of R 1 and R 2 has the same definition as each of R 1 and R 2 in Formula (I); each of Ya and Yb independently represents —C(R x1 )(R x2 )—, —N(Ra)—, —O—, or —S—; each of R x1 and R x2 independently represents a hydrogen atom or a substituent; Ra represents a hydrogen atom or a substituent; R x1 , R x2 , and Ra may form a ring by being bonded to L; Xa represents —C(═O)—, —SO 2 —, —SO—, or *—P(═O)(ORb)O—; * represents a position of bonding to a carbon atom to which R 2 is bonded; Rb represents a substituent; L represents a single bond or a divalent linking group; and each of these groups may be further substituted with a substituent.

5 . The polarizing plate composition according to claim 1 ,
wherein the compound represented by Formula (I) is represented by the following Formula (III),

in Formula (III), L has the same definition as L in Formula (II); R 1a represents a methylene group substituted with a heteroatom, an ethylene group substituted with an electron-withdrawing group, an acyl group, a carbamoyl group in which at least one of hydrogen atoms is substituted with a group independently selected from an alkyl group, a cycloalkyl group, or an aryl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a silyl group, or an alkylsulfonyl or arylsulfonyl group; R 2a represents an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, a nitro group, a heterocyclic group, or a halogen atom: each of Y a1 and Y a2 independently represents —C(R x1 )(R x2 )—, —N(Ra)—, —O—, or —S—, and at least one of Y a1 and Y a2 is —N(Ra)—; each of R x1 and R x2 independently represents a hydrogen atom or a substituent; Ra represents a hydrogen atom or a substituent; R x1 , R x2 , and Ra may form a ring by being bonded to L; and each of these groups may be further substituted with a substituent.

6 . The polarizing plate composition according to claim 1 ,
wherein the compound represented by Formula (I) is represented by the following Formula (IV),

in Formula (IV), each of R 1a and R 2a has the same definition as each of R 1a and R 2a in Formula (III); L 1 represents a single bond, —C(═O)—, —C(═S)—, an alkylene group, or an arylene group; each of R 3a and R 4a independently represents a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, or an aryl group; and each of the groups represented by R 1a , R 2a, R 3a , and R 4a may further have a substituent.

7 . The polarizing plate composition according to claim 1 ,
wherein any one of Y, X, and R 2 in Formula (I) is a group having at least one cyclic structure.

8 . The polarizing plate composition according to claim 1 ,
wherein the compound represented by any one of Formulae (I) to (IV) has a water-soluble functional group.

9 . The polarizing plate composition according to claim 1 , further comprising a resin,
wherein the amount of the compound represented by Formula (I) added is 0.01 parts by mass to 30 parts by mass with respect to 100 parts by mass of the resin.

10 . The polarizing plate composition according to claim 1 , further comprising a compound represented by the following Formula (A).

wherein in Formula (A), each of Ya 1 , Yb 1 , and L has the same definition as each of Ya 1 , Yb 1 , and L in Formula (III); and R 2 has the same definition as R 2 in Formula (I).

11 . The polarizing plate composition according to claim 1 , further comprising cellulose acylate, polyvinyl alcohol, or acylated or ketalized polyvinyl alcohol.

12 . The polarizing plate composition according to claim 1 , further comprising:
polyvinyl alcohol or acylated or ketalized polyvinyl alcohol; and a metal compound colloid.

13 . The polarizing plate composition according to claim 1 , further comprising:
polyvinyl alcohol or acylated or ketalized polyvinyl alcohol; and a dichroic colorant.

14 . The polarizing plate composition according to claim 1 , further cellulose acylate.

15 . A polarizing plate protective film composed of the polarizing plate composition according to claim 1 .

16 . A polarizer composed of the polarizing plate composition according to claim 1 .

17 . A polarizing plate comprising an adhesive layer or a pressure sensitive adhesive layer composed of the polarizing plate composition according to claim 1 .

18 . A polarizing plate comprising the polarizing plate protective film according to claim 15 .

19 . A polarizing plate comprising the polarizer according to claim 16 .

20 . A liquid crystal display device comprising the polarizing plate according to claim 17 .

21 . A compound represented by the following Formula (III),

wherein in Formula (III), R 1a represents a methylene group substituted with a heteroatom, an ethylene group substituted with an electron-withdrawing group, an acyl group, a carbamoyl group in which at least one of hydrogen atoms is substituted with a group independently selected from an alkyl group, a cycloalkyl group, or an aryl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a silyl group, or an alkylsulfonyl or arylsulfonyl group, and R 2a represents an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, a nitro group, a heterocyclic group, or a halogen atom; each of Ya 1 and Yb 1 independently represents —C(R x1 )(R x2 )—, —N(Ra)—, —O—, or —S—; at least one of Ya 1 and Yb 1 is —N(Ra)—; each of R x1 and R x2 independently represents a hydrogen atom or a substituent; Ra represents a hydrogen atom or a substituen

Assignees

• Fujifilm Corp

Inventors

• Shimoju Naoya
• Yoshida Aiko
• Nojiri Mayumi

Classifications

• G02B1/00

  Optical elements characterised by the material of which they are made; Optical coatings for optical elements · CPC title

• C07D231/52

  Oxygen atom in position 3 and nitrogen atom in position 5, or vice versa · CPC title

• C07D239/60

  Three or more oxygen or sulfur atoms · CPC title

• C07F5/025

  Boronic and borinic acid compounds · CPC title

• C09J11/06 Primary

  organic · CPC title