Process for multistage hydroprocessing in a single reactor

Patent metadata

Field	Value
Publication number	US-11731094-B2
Application number	US-202217814929-A
Country	US
Kind code	B2
Filing date	Jul 26, 2022
Priority date	Jul 27, 2021
Publication date	Aug 22, 2023
Grant date	Aug 22, 2023

Abstract

The present invention provides a multistage single reactor system for hydroprocessing and a process of carrying out multistage hydroprocessing in the said reactor assembly consisting of, a fixed bed solid catalyst system, a feed injection system enabling axial flow of hydrogen saturated hydrocarbon feed, a hydrogen dispensing system inside the reactor enabling minimum required hydrogen flow in cross-flow pattern, also using multitudes of integrated separation and withdrawal limbs for continuous staging. The innovative reactor disclosed in the present invention enables continuous separation and withdrawal of gaseous products along the reactor length by means of combined horizontal reactor orientation and vertical separation limbs provided at the top of the horizontally oriented reactor. The advantage of the reactor assembly includes effective heat sink of exothermic reactions and lower severity of operation due to removal of inhibitory gaseous products.

First claim

What is claimed is:

1. A reactor system for a single phase, multistage hydroprocessing of a liquid hydrocarbon feed pre-saturated with hydrogen, the reactor system comprising:
a horizontal reactor with a feed inlet nozzle at one lateral end for an axial entry of a premixed mixture of the liquid hydrocarbon feed and gaseous hydrogen at a mixing point;
a fixed bed catalyst loaded inside the horizontal reactor throughout length of the horizontal reactor, wherein the horizontal reactor is a fixed bed reactor;
a longitudinal sparger running along a bottom portion of the horizontal reactor with a multitude of nozzles provided at a top periphery of the sparger to distribute the gaseous hydrogen;
a multitude of vertically oriented gas separation and withdrawal vertical separation limbs provided at a top of the horizontal reactor acting as micro separation vessels and as a withdrawal assembly, integrated with the horizontal reactor for removal of product gases comprising hydrogen sulfide (H 2 S), ammonia (NH 3 ) and dry gases that rise as bubbles against horizontally flowing liquid hydrocarbon feed, wherein the gas separation and withdrawal vertical separation limbs each are provided with pressure and level control devices to control pressure and levels of each portion, and wherein each vertical separation limb comprises a gas-liquid disengaging space and a gas withdrawal assembly; and
an outlet product collector provided with outlet collectors distributed uniformly along a cross section of the horizontal reactor designed to avoid accumulation of liquids at other lateral end of the horizontal reactor and enable removal of a liquid product depleted of heteroatoms, wherein the liquid product is Ultra Low Sulfur Gasoline (ULSG) or Ultra Low Sulfur Diesel (ULSD).

2. The reactor system as claimed in claim 1 , wherein the catalyst is a fixed bed catalyst system comprising two or more metals selected from base metals of Groups VI, and VII comprising nickel, cobalt, molybdenum, tungsten, boron, phosphorus, iron, in a sulfide form and is distributed on a support.

3. The reactor system as claimed in claim 1 , wherein a superficial velocity of the liquid hydrocarbon feed flowing horizontally ranges from 0.1 to 10 m/s.

4. The reactor system as claimed in claim 1 , wherein a horizontal length of the horizontal reactor ranges from 3 to 30 times a diameter of the horizontal reactor.

5. The reactor system as claimed in claim 1 , wherein the sparger is provided with a multitude of nozzles to maintain the liquid hydrocarbon feed saturated with hydrogen and the multitude of nozzles are provided with holes having a diameter ranging from 0.01 mm to 1.0 mm.

6. The reactor system as claimed in claim 1 , wherein a height of the vertical separation limb at the top of the horizontal reactor ranges from 5 to 20 times of a diameter of the vertical separation limbs.

7. The reactor system as claimed in claim 1 , wherein a diameter of the vertical separation limb ranges from 0.1 to 1 times a diameter of the horizontal reactor.

8. The reactor system as claimed in claim 1 , wherein the vertical separation limbs are equidistantly located along horizontal length of the horizontal reactor.

9. The reactor system as claimed in claim 1 , wherein a distance of the vertical separation limb just next to the feed inlet nozzle from a tangential length of the horizontal reactor is same as a distance between two consecutive vertical separation limbs, and a distance of the vertical separation limb just prior to the outlet product collector effluent nozzle from the tangential length of the horizontal reactor is same as distance between two consecutive vertical limbs.

10. The reactor system as claimed in claim 1 , wherein a total number of the vertical separation limbs present throughout the horizontal length of the horizontal reactor ranges from 1 to 10.

11. The reactor system as claimed in claim 1 , wherein the liquid product from the outlet product collector of the horizontal reactor is collected in a multitude of small outlet collectors distributed in uniform fashion horizontally along entire cross section of the horizontal reactor to avoid accumulation of liquids.

Assignees

• Indian Oil Corp Ltd

Inventors

• Gupta Yamini
• Arangarasu Arun
• Viswakarma Nepal
• Butley Ganesh Vitthalrao
• Kumar Sarvesh
• Sau Madhusudan
• Singh Gurpreet Kapur
• RAMAKUMAR Sankara Sri Venkata

Classifications

• B01J8/0221 Primary

  in a cylindrical shaped bed (B01J8/0214 takes precedence) · CPC title

• C10G45/22

  with hydrogen dissolved or suspended in the oil · CPC title

• C10G45/72

  Controlling or regulating · CPC title

• C10G47/10

  with catalysts deposited on a carrier · CPC title

• C10G65/12

  including cracking steps and other hydrotreatment steps · CPC title