Determining composition of a sample

Patent metadata

Field	Value
Publication number	US-11726038-B2
Application number	US-202017076566-A
Country	US
Kind code	B2
Filing date	Oct 21, 2020
Priority date	Aug 21, 2017
Publication date	Aug 15, 2023
Grant date	Aug 15, 2023

Abstract

A single-wavelength light source is configured to generate an excitation light source. A sample holder that defines an inner cavity is capable of holding a sample and includes a surface transparent to the excitation light source. One or more mounts are attached to at least one of the light source or the sample holder. The mounts are configured to change an incident angle of the excitation light source on the surface. One or more optical components are positioned in a path of a fluorescence emission emitted from the surface and guide the fluorescence emission to a detector. A detector detects an intensity of the fluorescence emission.

First claim

What is claimed is:

1. A method comprising:
receiving a fluid sample by a sample holder defining an inner cavity configured to hold a sample and including a surface transparent to an excitation light source;
inducing fluorescence in the fluid sample by a light produced by a single-wavelength light source;
changing an angle of incidence between the surface of the sample holder and the light; and
detecting a change in fluorescence intensity by a detector as the angle of incidence is changed.

2. The method of claim 1 , further comprising:
plotting a plot of fluorescence intensity vs. the angle of incidence;
comparing the plot to a library of plots; and
determining a content of the fluid sample in response to comparing the plot.

3. The method of claim 1 , wherein changing the angle of incidence comprises rotating the sample holder.

4. The method of claim 3 , wherein rotating the sample holder comprises rotating the sample holder about an axis of rotation of the sample holder that is positioned vertically through the center of the sample holder.

5. The method of claim 3 , wherein rotating the sample holder comprises rotating the sample holder about an axis of rotation of the sample holder that is positioned vertically through the center of a face of the sample holder.

6. The method of claim 1 , wherein changing an angle of incidence is controlled by a microprocessor.

7. The method of claim 1 , wherein the fluid sample comprises hydrocarbon fluid.

8. The method of claim 1 , wherein changing the angle of incidence comprises varying the angle between 0°-80°.

9. A fluid identification system comprising:
a sample holder filled with an unknown fluid, the sample holder being transparent to a specified wavelength of light;
a laser configured to direct a laser beam towards a face of the sample holder;
a detector directed towards the face of the sample holder, the detector configured to detect florescent emissions from the unknown fluid within the sample holder;
a microprocessor; and
a computer-readable storage medium storing instructions executable by the microprocessor, the instructions comprising;
emitting a laser beam from a laser at the face of the sample holder;
inducing fluorescence in the fluid by the laser beam produced by a laser at a specified wavelength;
changing an angle of incidence between the face of the sample holder and the laser beam;
detecting a change in fluorescence intensity as the angle of incidence is changed;
plotting a plot of fluorescence intensity vs. the angle of incidence;
comparing the plot to a library of plots; and
determining a composition of the fluid in response to comparing the plot.

10. The fluid identification system of claim 9 , wherein the unknown fluid comprises a hydrocarbon fluid.

11. The fluid identification system of claim 9 , wherein rotating the sample holder comprises rotating the sample holder about an axis of rotation of the sample holder that is positioned vertically through the center of the sample holder.

12. The fluid identification system of claim 9 , wherein rotating the sample holder comprises rotating the sample holder about an axis of rotation of the sample holder that is positioned vertically through the center of a surface of the sample holder.

Assignees

• Saudi Arabian Oil Co

Inventors

• Hegazi Ezzat
• Cunningham Vincent

Classifications

• G01N21/6428 Primary

  Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" (in vivo A61B5/00; immunoassay G01N33/53) · CPC title

• G01N21/645 Primary

  Specially adapted constructive features of fluorimeters · CPC title

• G01N21/33

  using ultraviolet light (G01N21/39 takes precedence) · CPC title

• G01N21/6456

  Spatial resolved fluorescence measurements; Imaging · CPC title

• G01N33/225

  Gaseous fuels, e.g. natural gas · CPC title