Determining composition of a sample

Patent metadata

Field	Value
Publication number	US-10845307-B2
Application number	US-201715682026-A
Country	US
Kind code	B2
Filing date	Aug 21, 2017
Priority date	Aug 21, 2017
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A single-wavelength light source is configured to generate an excitation light source. A sample holder that defines an inner cavity is capable of holding a sample and includes a surface transparent to the excitation light source. One or more mounts are attached to at least one of the light source or the sample holder. The mounts are configured to change an incident angle of the excitation light source on the surface. One or more optical components are positioned in a path of a fluorescence emission emitted from the surface and guide the fluorescence emission to a detector. A detector detects an intensity of the fluorescence emission.

First claim

What is claimed is:

1. A fluorescence-measurement apparatus, comprising:
a single-wavelength light source configured to generate an excitation light;
a sample holder defining an inner cavity configured to hold a sample and including a surface transparent to the excitation light, the light source and the sample holder spatially arranged such that, during a sample test, a portion of the excitation light incident on the surface passes through the surface and is incident on the sample in the sample holder at a depth from the surface, wherein the sample is configured to emit fluorescence in response to the portion of the excitation light incident on the sample at the depth from the surface;
one or more mounts attached to the light source and configured to actively change an incident angle of the excitation light incident on the surface during the sample test and responsively vary the depth from the surface at which the portion of the excitation light is incident on the sample, the one or more mounts configured to move relative to the sample holder to change the incident angle of the excitation light incident on the surface relative to the surface of the sample holder;
one or more optical components spatially arranged to receive a portion of the fluorescence emitted by the sample and passing through the surface and configured to guide the received fluorescence to a detector; and
the detector configured to detect an intensity of the fluorescence emission.

2. The fluorescence-measurement apparatus of claim 1 , wherein a range of incidence angles can range from 0°-80°.

3. The fluorescence-measurement apparatus of claim 1 further comprising an optical filter positioned between the surface of the sample holder and the detector, the optical filter configured to allow a specified range of wavelengths to pass through the filter.

4. The fluorescence-measurement apparatus of claim 1 further comprising:
a lens positioned between the surface of the sample holder and the detector, the lens configured to collect and direct light given off by a florescent emission towards the detector; and
a fiber optic cable connected between the lens and the detector, the fiber optic cable configured to direct light from the lens to the detector.

5. The fluorescence-measurement apparatus of claim 1 , wherein the sample comprises a hydrocarbon fluid.

6. The fluorescence-measurement apparatus of claim 1 , wherein the sample is opaque.

7. The fluorescence-measurement apparatus of claim 1 , wherein a wavelength of the light source comprises an ultra-violet wavelength.

Assignees

• Saudi Arabian Oil Co

Inventors

• Hegazi Ezzat
• Cunningham Vincent

Classifications

• G01N2201/129

  Using chemometrical methods · CPC title

• G01N2021/6484

  Optical fibres · CPC title

• G01N2021/6482

  Sample cells, cuvettes · CPC title

• G01N2021/392

  Measuring reradiation, e.g. fluorescence, backscatter · CPC title

• G01N2021/135

  Sample holder displaceable · CPC title