System and method for preservation, transport, and analysis of water samples

Patent metadata

Field	Value
Publication number	US-11726015-B2
Application number	US-202117392326-A
Country	US
Kind code	B2
Filing date	Aug 3, 2021
Priority date	Apr 26, 2016
Publication date	Aug 15, 2023
Grant date	Aug 15, 2023

Abstract

A device for collecting contaminants from water samples is provided. The device includes a solid sorbent that collects and stores the contaminants from water samples. The solid sorbent is configured to allow for the preservation of the stored contaminants. The concentrations of the contaminants in the water samples are determined via analysis of the solid sorbent or via elution of the stored contaminants from the sorbent and analysis of the eluate solution.

First claim

What is claimed is:

1. A method of collecting and releasing at least one target contaminant from a water sample, a volume, V, of the water sample picked as follows: 250 mL≤V≤1 L, the method comprising:
providing a water sampling device having at least one solid sorbent, wherein the at least one solid sorbent comprises a plurality of particles, and wherein size of each of the plurality of particles is picked to influence adsorption kinetics of the at least one target contaminant when the water sampling device is inserted in the water sample, wherein the size of the plurality of panicles are picked to be within the following range: 300 μm-650 μm;
exposing the device to the water sample;
allowing the at least one solid sorbent to: (1) adsorb the at least one target containment, (2) preserve the at least one target contaminant for extended periods of time, and (3) release the at least one target contaminant for subsequent analysis, wherein the at least one target contaminant is preserved in a compact or dry form, wherein a concentration, C, of the target contaminant is in the following range: 0 mg/L<C≤0.25 mg/L, the plurality of particles having size 300 μm-650 μm adsorbing all of the target contaminant within 20 minutes;
removing the water sampling device from contact with the water sample;
releasing the at least one contaminant from the at least one solid sorbent at a later time; and
performing analysis on the released at least one contaminant.

2. The method in claim 1 , wherein the device is packaged for storage or transportation before the release step.

3. The method as in claim 1 , wherein the device dries after the removal step and before the release step.

4. The method as in claim 1 , wherein the duration between the removal step and the analysis step is at least 24 hours.

5. The method as in claim 1 , wherein the duration between the removal step and the analysis step is at least 7 days.

6. The method as in claim 1 , wherein the duration between the removal step and the analysis step is at least 30 days.

7. The method in claim 1 , wherein the at least one solid sorbent comprises at least one of an ion exchange resin, xerogel, or cellulose.

8. The method of claim 1 , wherein the device is stored in a package to prevent contamination.

9. The method in claim 1 , wherein the one more contaminant is adsorbed by manually stirring the device in the water sample.

10. The method in claim 1 , wherein the one or more contaminants are adsorbed by flowing the water sample through the device.

11. The method in claim 1 , wherein the one or more contaminants are adsorbed by immersing the device in the water sample.

12. The method in claim 1 , wherein the one or more contaminants are released by flowing a release solution through the device.

13. The method in claim 1 , wherein the one or more contaminants are released by immersing the device in a release solution.

14. The method of claim 1 , wherein the one or more contaminants adsorption step requires less than 15 minutes.

15. The method of claim 1 , wherein the one or more contaminants adsorption step requires less than 3 minutes.

16. The method in claim 1 , wherein the device is transported to another location after adsorption for storage or analysis.

17. The method in claim 16 , wherein the device is transported via the postal service or a commercial shipping service.

18. The method in claim 1 , wherein the device is stored at the same location after adsorption for analysis at a later date.

19. A method of collecting and releasing at least one target contaminant from a fluid sample, a volume, V, of the fluid sample picked as follows: 250 mL≤V≤1 L, the method comprising:
providing a fluid sampling device containing at least one solid sorbent, wherein the at least one solid sorbent comprises a plurality of particles, and wherein size of each of the plurality of particles is picked to influence adsorption kinetics of the at least one target contaminant when the fluid sampling device is inserted in the fluid sample, wherein the size of the plurality of particles are picked to be within the following range: 300 μm-650 μm;
exposing the device to the fluid sample;
allowing the at least one solid sorbent to:
(1) adsorb the at least one target containment, (2) preserve the at least one target contaminant for extended periods of time, and (3) release the at least one target contaminant for subsequent analysis, wherein the at least one target contaminant is preserved in a compact or dry form, wherein a concentration, C, of the target contaminant is in the following range: 0 mg/L<C≤0.25 mg/L, the plurality of particles having size 300 μm-650 μm adsorbing all of the target contaminant within 20 minutes;
removing the fluid sampling device from contact with the fluid sample;
releasing the at least one target contaminant from the at least one solid sorbent; and
performing analysis on the released at least one target contaminant.

20. A method for collecting and releasing at least a first target contaminant and a second target contaminant from a water sample, a volume, V, of the water sample picked as follows: 250 mL≤V≤1 L, the method comprising:
(a) providing a water sampling device fabricated from a mesh or a fabric, the water sampling comprising at least a first compartment and second compartment;
(b) providing a first solid sorbent enclosed within the first compartment, the first solid sorbent capable of adsorbing a first target contaminant;
(c) providing a second solid sorbent enclosed within the second compartment, the second solid sorbent capable of adsorbing a second target contaminant;
(d) exposing the water sampling device to the water sample;
(e) allowing the first solid sorbent enclosed within the first compartment to: (1) adsorb the first target contaminant, (2) preserve the first target contaminant for extended periods of time, and (3) release the first target contaminant for subsequent analysis, wherein the first target contaminant is preserved in a compact or dry form, wherein a first concentration, C1, of the first target contaminant is in the following range: 0 mg/L<C1≤0.25 mg/L;
(f) allowing the second solid sorbent enclosed within the second compartment to: (1) adsorb the second target contaminant, (2) preserve the second target contaminant for extended periods of time, and (3) release the second target contaminant for subsequent analysis, wherein the second target contaminant is preserved in a compact or dry form, wherein a second concentration, C2, of the second target contaminant is in the following range of 0 mg/L<C2≤0.25 mg/L;
(g) removing the water sampling device from contact with the water sample;
(h) releasing the first and second target contaminants from the first and second solid sorbents at a later time; and
(i) performing analysis on the released first and second target contaminants;
wherein the first solid sorbent comprises a first plurality of particles enclosed within the first compartment, and wherein size of each of the first plurality of particles is picked to influence adsorption kinetics of the first target contaminant when the device is inserted in the water sample,
wherein the second solid sorbent comprises a second plurality of particles enclosed within the second compartment, and wherein size of each of the second plurality of particles is picked to influence adsorption kinetics of the second target contaminant when the device is inserted in the water sample,
wherein the size of the first plurality of particles or the size of t

Assignees

• Massachusetts Inst Technology

Inventors

• Hanhauser Emily
• Bono Michael
• Hart Anastasios John
• Karnik Rohit
• Ren Xiaoyuan
• Vaishnav Chintan

Classifications

• G01N1/405 Primary

  by adsorption or absorption · CPC title

• B01D15/1892

  the sorbent material moving as a whole, e.g. continuous annular chromatography, true moving beds or centrifugal chromatography · CPC title

• B01J20/264

  derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers · CPC title

• B01J20/2805

  Sorbents inside a permeable or porous casing, e.g. inside a container, bag or membrane · CPC title

• B01J20/3425

  of sorbents or filter aids comprising organic materials · CPC title