Solid oxide fuel cell using zeolite-templated carbon as electrocatalyst

Patent metadata

Field	Value
Publication number	US-11721826-B2
Application number	US-202117497521-A
Country	US
Kind code	B2
Filing date	Oct 8, 2021
Priority date	Jul 14, 2021
Publication date	Aug 8, 2023
Grant date	Aug 8, 2023

Abstract

A solid oxide fuel cell assembly (SOFC) and a method for making the SOFC are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC). The functionalized ZTC is formed by forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution comprising hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites. The functionalized ZTC is incorporated into electrodes by forming a mixture of the functionalized ZTC with a calcined solid oxide electrolyte and calcining the mixture. The method includes forming an electrode assembly, forming the SOFC assembly, and coupling the SOFC assembly to a cooling system.

First claim

What is claimed is:

1. A method for making a solid oxide fuel cell assembly (SOFC), comprising:
forming a functionalized zeolite templated carbon (ZTC), comprising:
forming a CaX zeolite;
depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite;
treating the carbon/zeolite composite with a solution comprising hydrofluoric acid to form a ZTC; and
treating the ZTC to add catalyst sites, forming the functionalized ZTC; and

incorporating the functionalized ZTC into electrodes, comprising:
forming a mixture of the functionalized ZTC with a calcined solid oxide electrolyte; and
calcining the mixture;

forming an electrode assembly;
forming the SOFC assembly; and
coupling the SOFC assembly to a cooling system.

2. The method of claim 1 , wherein the CaX zeolite is formed by ion exchanging a NaX zeolite with calcium ions.

3. The method of claim 1 , wherein the CVD process uses propylene, ethanol, or acetylene, or any combinations thereof, as an organic precursor gas.

4. The method of claim 1 , wherein the CVD process uses acetylene as an organic precursor gas.

5. The method of claim 4 , wherein the acetylene is added as a 2 vol. % solution in helium.

6. The method of claim 1 , wherein the CVD process is performed at a temperature of between 823 K and 1123 K.

7. The method of claim 1 , wherein the CVD process comprises:
depositing carbon in a matrix of the CaX zeolite at a first temperature using a gas stream comprising acetylene;
switching the gas stream to a helium stream; and
increasing the temperature to a second temperature.

8. The method of claim 7 , wherein the first temperature is less than 875 K.

9. The method of claim 7 , wherein the first temperature is about 823 K.

10. The method of claim 7 , wherein the second temperature is greater than 1120 K.

11. The method of claim 7 , wherein the second temperature is about 1123 K.

12. The method of claim 7 , comprising repeating the CVD process by cooling back to the first temperature;
switching the gas stream back to the gas stream comprising acetylene;
depositing carbon in the matrix of the CaX zeolite at the first temperature;
switching the gas stream to the helium stream; and
increasing the temperature to the second temperature.

13. The method of claim 1 , comprising forming the functionalized ZTC using an incipient wetness technique.

14. The method of claim 1 , comprising:
dissolving an active metal precursor to form an aqueous solution;
adding an amount of the aqueous solution to the ZTC corresponding to a pore volume of the ZTC forming a metal/ZTC composite;
drying the metal/ZTC composite; and
sintering the metal/ZTC composite to form the functionalized ZTC.

15. The method of claim 1 , comprising incorporating the functionalized ZTC onto an anode, a cathode, or both by sputtering.

16. The method of claim 1 , comprising forming the electrode assembly by:
firing the anode with the incorporated functionalized ZTC to form a ceramic anode;
firing the solid oxide electrolyte (SOE) to form a ceramic SOE;
firing the cathode with the incorporated functionalized ZTC to form a ceramic cathode;
assembling the ceramic anode, ceramic SOE, and ceramic cathode into an assembly; and
firing the assembly to form the electrode assembly.

17. A solid oxide fuel cell (SOFC), comprising:
an electrode assembly (EA), comprising:
an anode;
a solid oxide electrolyte; and
a cathode, wherein the anode, the cathode, or both comprises functionalized zeolite templated carbon (ZTC);

a housing comprising:
an inlet for a mixture of hydrogen and carbon monoxide; and
an outlet for a mixture of steam and carbon dioxide;

a power line coupled to the cathode to provide current from the SO fuel cell to an external power user; and
a return line from external power supply coupled to the anode.

18. The SOFC of claim 17 , comprising a cooling system to remove heat from the SOFC.

19. The SOFC of claim 17 , comprising a layer of functionalized zeolite template carbon disposed at the interface between the anode and the SO, the interface between the cathode and the SO, or both.

20. The SOFC of claim 17 , wherein the solid oxide electrolyte comprises yttria-stabilized zirconia (YSZ).

Assignees

• Saudi Arabian Oil Co

Inventors

• Hammad Ahmad D
• Amr Issam T
• Wang Yuguo
• Lithoxoos Georgios
• Othman Rashid M

Classifications

• H01M8/1246 Primary

  the electrolyte consisting of oxides · CPC title

• C23C16/26 Primary

  Deposition of carbon only · CPC title

• H01M8/04007

  related to heat exchange · CPC title

• H01M8/04089

  of gaseous reactants · CPC title

• H01M8/04701

  Temperature · CPC title