Process and plant for separation of concomitants from a raw synthesis gas stream and for producing a sulfur-free by-product

Patent metadata

Field	Value
Publication number	US-11718796-B2
Application number	US-202017004745-A
Country	US
Kind code	B2
Filing date	Aug 27, 2020
Priority date	Sep 6, 2019
Publication date	Aug 8, 2023
Grant date	Aug 8, 2023

Abstract

The invention relates to a process and a plant for staged separation of concomitants from a raw synthesis gas stream to produce synthesis gas and a sulfur-free naphtha product as a by-product, To remove naphtha compounds and sulfur-containing concomitants, raw synthesis gas is treated with a scrubbing medium in a prescrubbing stage and withdrawn from the prescrubbing stage, and the laden scrubbing medium is mixed with water to bring about a phase separation into a scrubbing medium-water mixture and naphtha, wherein sulfur-containing concomitants are in solution in naphtha. To remove the sulfur-containing concomitants the naphtha is heated to obtain sulfur-free naphtha as a by-product of the gas scrubbing.

First claim

What is claimed is:

1. A process for staged separation of concomitants from a raw synthesis gas stream to produce synthesis gas by absorption of the concomitants in a physical scrubbing medium operated countercurrent to the raw synthesis gas stream in a plurality of scrubbing stages at elevated pressure, wherein the concomitants comprise at least carbon dioxide, one or more sulfur compounds of a first type, one or more sulfur compounds of a second type and naphtha, the process comprising:
a) absorbing at least naphtha and sulfur compounds of the first type from a raw synthesis gas stream in a prescrubbing stage thereby producing a scrubbing medium fraction laden at least with naphtha and sulfur compounds of the first type;
b) mixing the laden scrubbing medium fraction obtained in step a) with water to effect a phase separation into two liquid phases, wherein a first liquid phase comprises water and scrubbing medium and a second liquid phase comprises naphtha and sulfur compounds of the first type dissolved therein;
c) heating the second liquid phase obtained in step b) to remove the sulfur compounds of the first type and obtain sulfur-free naphtha;
d) absorbing carbon dioxide and sulfur compounds of the second type from the first liquid phase obtained in step b) in at least one main scrubbing stage arranged downstream of the prescrubbing stage in the gas flow direction to obtain at least one scrubbing medium fraction laden with at least carbon dioxide or sulfur compounds of the second type;
e) regenerating the laden scrubbing medium fraction obtained in step d) and reusing the regenerated scrubbing medium for absorbing concomitants in steps a) and d).

2. The process according to claim 1 , wherein the sulfur compounds of the first type comprise at least one element from the group of alkyl mercaptans, carbon disulfide, and thiophenes.

3. The process according to claim 1 , wherein the sulfur compounds of the second type comprise at least one element from the group of hydrogen sulfide, and carbonyl sulfide.

4. The process according to claim 1 , wherein the scrubbing medium comprises methanol.

5. The process according to claim 1 , wherein the scrubbing medium fraction laden with naphtha and sulfur compounds of the first type is supplied to a decompression stage for recovery of valuable gases.

6. The process according to claim 1 , wherein the first liquid phase is subjected to a thermal separation process for separating naphtha residues from the first liquid phase to obtain naphtha and a water-scrubbing medium mixture as products of the thermal separation process.

7. The process according to claim 6 , wherein the naphtha thermally separated from the first liquid phase is recycled to step b).

8. The process according to claim 6 , wherein the thermally separated water-scrubbing medium mixture is subjected to a further thermal separation process to obtain water and scrubbing medium as products of the thermal separation process and the obtained scrubbing medium is subjected to hot regeneration and subsequently reused for absorbing concomitants in steps a) and/or d).

9. The process according to claim 1 , wherein the sulfur compounds of the first type are removed from the second liquid phase by heating in a stripping column.

10. The process according to claim 1 , wherein the sulfur compounds of the first type are removed from the second liquid phase by introduction of saturated steam into the second liquid phase and the sulfur-free naphtha is subsequently subjected to a further treatment step for separation of water.

11. The process according to claim 1 , wherein the sulfur compounds of the first type removed from the second liquid phase by heating are supplied to a sulfur recovery plant.

Assignees

• Air Liquide

Inventors

• Schmidt Sophia
• Corbet Sharon

Classifications

• C10G5/04 Primary

  with liquid absorbents · CPC title

• B01D53/1406 Primary

  Multiple stage absorption · CPC title

• B01D53/1418

  Recovery of products · CPC title

• B01D53/1425

  Regeneration of liquid absorbents · CPC title

• B01D53/1487

  Removing organic compounds · CPC title