Method and device for separating off electrolytes from synthesis gases

Patent metadata

Field	Value
Publication number	US-10245549-B2
Application number	US-201615245476-A
Country	US
Kind code	B2
Filing date	Aug 24, 2016
Priority date	Sep 17, 2015
Publication date	Apr 2, 2019
Grant date	Apr 2, 2019

Abstract

A method and a device for separating off an electrolyte from a first synthesis gas and a second synthesis gas, each containing an electrolyte. The two synthesis gases are each subjected in a scrubbing column to a water scrubbing, in which a substantially electrolyte-free synthesis gas and also a scrubbing water loaded with an electrolyte that has been separated off are obtained. At least a part of the scrubbing water that was loaded with an electrolyte that has been separated off in the scrubbing of the first synthesis gas is used as scrubbing medium in the scrubbing of the second synthesis gas.

First claim

The invention claimed is:

1. A method for separating off an electrolyte from a first synthesis gas and a second synthesis gas, each containing an electrolyte, said method comprising:
subjecting each of the two synthesis gases to a water scrubbing in a first water scrubber column and a second water scrubber column, respectively, wherein a substantially electrolyte-free synthesis gas and a scrubbing water loaded with electrolyte are separated and obtained,
wherein at least a part of the scrubbing water that is loaded with an electrolyte separated off in the scrubbing of the first synthesis gas is used as scrubbing medium for the scrubbing of the second synthesis gas, and
wherein said electrolyte in said first and second synthesis gases is ammonia and/or hydrogen chloride.

2. The method according to claim 1 , wherein the first synthesis gas is scrubbed at a higher pressure than the second synthesis gas and scrubbing water that is loaded in the first water scrubber column is supplied to the second water scrubber column with the aid of the pressure difference.

3. The method according to claim 1 , wherein scrubbing water that is loaded during the scrubbing of the first synthesis gas is fed with the aid of gravity to the second water scrubber column.

4. The method according to claim 1 , wherein, for producing the first synthesis gas and the second synthesis gas, a synthesis gas stream is divided into a first and second substream, wherein the first substream forms the first synthesis gas, whereas the second synthesis gas is formed by converting the second substream by water-gas shift.

5. The method according to claim 1 , wherein said first water scrubber column and said second water scrubber column are each positioned upstream of a methanol scrubber.

6. The method according to claim 1 , wherein said first water scrubber column is positioned above said second water scrubber column.

7. The method according to claim 1 , further comprising introducing non-loaded scrubbing water into the second water scrubber column.

8. The method according to claim 7 , wherein said second water scrubber column contains column trays and said non-loaded scrubbing water is introduced into the second water scrubber column above the uppermost of said column trays, and, at a lower position, part of the scrubbing water loaded in the in the first water scrubber column is introduced, and wherein the remainder of the scrubbing water loaded in the first water scrubber column is combined directly with loaded scrubbing water removed from the second water scrubber column.

9. A method for separating off an electrolyte from a first synthesis gas and a second synthesis gas, each containing an electrolyte, said method comprising:
subjecting each of the two synthesis gases to a water scrubbing in a first water scrubber column and a second water scrubber column, respectively, wherein a substantially electrolyte-free synthesis gas and a scrubbing water loaded with electrolyte are separated and obtained,
wherein at least a part of the scrubbing water that is loaded with an electrolyte separated off in the scrubbing of the first synthesis gas is used as scrubbing medium for the scrubbing of the second synthesis gas, and
wherein said first water scrubber column and said second water scrubber column are each positioned upstream of a methanol scrubber.

Assignees

• Linde Ag

Inventors

• Kerestecioglu Ulvi
• Bohn Jan-Peter

Classifications

• B01D2257/2045

  Hydrochloric acid · CPC title

• B01D2256/16

  Hydrogen · CPC title

• B01D53/14 Primary

  by absorption · CPC title

• B01D2257/406

  Ammonia · CPC title

• B01D53/1406 Primary

  Multiple stage absorption · CPC title