Rubber articles with improved fire properties

Patent metadata

Field	Value
Publication number	US-11708482-B2
Application number	US-201816646919-A
Country	US
Kind code	B2
Filing date	Sep 18, 2018
Priority date	Sep 18, 2017
Publication date	Jul 25, 2023
Grant date	Jul 25, 2023

Abstract

Tires and tire components are provided having improved fire properties, as well as the vulcanizable compositions for making the tires and tire components. A vulcanizable composition is provided that includes at least one vulcanizable polymer, a curative, a halogenated hydrocarbon, and expandable graphite. The tires and tire components have improved properties including one or more of improved flame retardancy, reduced smoke density and/or toxicity, and reduced heat release.

First claim

What is claimed is:

1. A tire component prepared by a process comprising the steps of:
(i) preparing a vulcanizable composition that includes at least one vulcanizable polymer, a curative, at least one halogenated hydrocarbon wax, and expandable graphite, where the vulcanizable composition comprises from about 0.5 parts by weight to about 40 parts by weight expandable graphite, based upon one hundred parts by weight rubber;
(ii) fabricating an uncured tire component comprising at least one layer that is formed from said vulcanizable composition; and
(iii) at least partially curing the uncured tire component to form a cured tire component, wherein the cured tire component is selected from the group consisting of tread, belt, sidewall, ply, bead, and inner liner, where the expandable graphite is not expanded during the said process, or is expanded to at most 100% in volume during the said process.

2. The tire component of claim 1 , where the vulcanizable composition further comprises from about 0.1 parts by weight to about 20 parts by weight alumina trihydrate, based upon one hundred parts by weight rubber.

3. The tire component of claim 1 , where the vulcanizable composition further comprises from about 20 parts by weight to about 100 parts by weight clay, based upon one hundred parts by weight rubber.

4. The tire component of claim 1 , where the vulcanizable composition further comprises carbon black.

5. The tire component of claim 1 , where the vulcanizable composition further comprises silica.

6. The tire component of claim 1 , where the vulcanizable composition further comprises factice.

7. The tire component of claim 1 , where the vulcanizable composition further comprises one or more plasticizers.

8. The tire component of claim 1 , where the vulcanizable composition further comprises one or more homogenizing agents.

9. The tire component of claim 1 , where the vulcanizable composition further comprises one or more antioxidants.

10. The tire component of claim 1 , where the vulcanizable composition further comprises zinc oxide.

11. The tire component of claim 1 , where the expandable graphite is characterized by an expansion ratio of at least 10:1.

12. The tire component of claim 1 , where the expandable graphite, if expanded, is expanded to at most 50% in volume during the said process.

13. A tire comprising at least one tire component that includes the vulcanizate of a vulcanizable composition that includes:
(i) a rubber that includes at least one vulcanizable polymer,
(ii) a curative,
(iii) a halogenated hydrocarbon wax, and
(iv) from about 0.5 parts by weight to about 40 parts by weight expandable graphite, based upon one hundred parts by weight rubber, wherein the at least one tire component is selected from the group consisting of tread portion, belt, sidewall, inner liner, bead and ply, and wherein the expandable graphite is not expanded in the tire component, or is expanded to at most 100% in volume in the tire component.

14. The tire of claim 13 , where the total amount of vulcanizable polymer in the vulcanizable composition is from about 25 to about 40 wt. %, based upon the total weight of the composition.

15. The tire of claim 13 , where the at least one vulcanizable polymer comprises polychloroprene.

16. The tire of claim 13 , where the at least one vulcanizable polymer comprises polychloroprene, and where the composition further comprises at least one additional vulcanizable polymer selected from the group consisting of natural rubber, synthetic polyisoprene, polybutadiene, polyisobutylene-co-isoprene, poly(ethylene-co-propylene), poly(styrene-co-butadiene), poly(styrene-co-isoprene), and poly(styrene-co-isoprene-co-butadiene), poly(isoprene-co-butadiene), poly(ethylene-co-propylene-co-diene), polysulfide rubber, acrylic rubber, urethane rubber, nitrile rubber, silicone rubber, epichlorohydrin rubber, and mixtures thereof.

17. The tire of claim 13 , where the at least one halogenated hydrocarbon wax is present in an amount of from about 0.2 parts by weight to about 25 parts by weight, based upon one hundred parts by weight rubber.

18. The tire of claim 13 , where the vulcanizable composition comprises from about 1 part by weight to about 35 parts by weight expandable graphite, based upon one hundred parts by weight rubber.

19. The tire of claim 13 , where the vulcanizable composition further comprises from about 0.1 parts by weight to about 20 parts by weight alumina trihydrate, based upon one hundred parts by weight rubber.

20. The tire of claim 13 , where the vulcanizable composition further comprises from about 20 parts by weight to about 100 parts by weight clay, based upon one hundred parts by weight rubber.

21. A tire component prepared by a process comprising the steps of:
(i) preparing a vulcanizable composition that includes at least one vulcanizable polymer, a curative, at least one halogenated hydrocarbon wax, and expandable graphite, where the vulcanizable composition comprises from about 0.5 parts by weight to about 40 parts by weight expandable graphite, based upon one hundred parts by weight rubber;
(ii) fabricating an uncured tire component comprising at least one layer that is formed from said vulcanizable composition; and
(iii) at least partially curing the uncured tire component to form a cured tire component wherein the cured tire component is selected from the group consisting of tread, belt sidewall, ply, bead, and inner liner, and where the expandable graphite is intercalated with one or more intercalants selected from the group consisting of halogens, alkali metals, sulfates, nitrates, organic acids, aluminum chlorides, ferric chlorides, metal halides, arsenic sulfides, and thallium sulfides.

Assignees

• Bridgestone Americas Tire Operations Llc

Inventors

• Howard Michael C
• Adcock Brandon C
• Li Hang

Classifications

• C08L11/00 Primary

  Compositions of homopolymers or copolymers of chloroprene · CPC title

• B60C1/00 Primary

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08K3/04

  Carbon · CPC title

• C08L23/28

  by reaction with halogens or halogen-containing compounds (C08L23/32 takes precedence) · CPC title