Elastomeric articles with improved fire protection properties

Patent metadata

Field	Value
Publication number	US-11111979-B2
Application number	US-201716332855-A
Country	US
Kind code	B2
Filing date	Sep 18, 2017
Priority date	Sep 17, 2016
Publication date	Sep 7, 2021
Grant date	Sep 7, 2021

Abstract

An air spring having an airsleeve, wherein at least one layer of the airsleeve includes the vulcanization product of a composition that includes at least one vuicanizable polymer, a curative, at least one halogenated hydrocarbon wax, and expandable graphite.

First claim

What is claimed is:

1. An air spring having an airsleeve, wherein at least one layer of said airsleeve includes the vulcanization product of a composition that includes
at least one vulcanizable polymer;
a curative;
at least one halogenated hydrocarbon wax; and
expandable graphite, where the total amount of vulcanizable polymer is from about 25 to about 40 wt. %, based upon the total weight of the composition.

2. The air spring of claim 1 , where the at least one vulcanizable polymer comprises polychloroprene.

3. The air spring of claim 1 , where the at least one vulcanizable polymer comprises polychloroprene, and where the composition further comprises at least one additional vulcanizable polymer selected from the group consisting of natural rubber, synthetic polyisoprene, polybutadiene, polyisobutylene-co-isoprene, poly(ethylene-co-propylene), poly(styrene-co-butadiene), poly(styrene-co-isoprene), and poly(styrene-co-isoprene-co-butadiene), poly(isoprene-co-butadiene), poly(ethylene-co-propylene-co-diene), polysulfide rubber, acrylic rubber, urethane rubber, nitrile rubber, silicone rubber, epichlorohydrin rubber, and mixtures thereof.

4. The air spring of claim 1 , where the at least one halogenated hydrocarbon wax is present in an amount of from about 0.2 parts by weight to about 25 parts by weight, based upon one hundred parts by weight rubber.

5. The air spring of claim 1 , where the composition comprises from about 0.5 parts by weight to about 40 parts by weight expandable graphite, based upon one hundred parts by weight rubber.

6. The air spring of claim 1 , where the composition further comprises from about 0.1 parts by weight to about 20 parts by weight alumina trihydrate, based upon one hundred parts by weight rubber.

7. The air spring of claim 1 , where the composition further comprises from about 20 parts by weight to about 100 parts by weight clay, based upon one hundred parts by weight rubber.

8. An air bellow prepared by a process comprising the steps of:
(i) preparing a vulcanizable composition that includes at least one vulcanizable polymer, a curative, at least one halogenated hydrocarbon wax, and expandable graphite, where the total amount of vulcanizable polymer is from about 25 to about 40 wt. %, based upon the total weight of the composition;
(ii) fabricating an uncured air bellow comprising at least one layer that is formed from said vulcanizable composition; and
(iii) at least partially curing the uncured air bellow.

9. The air bellow of claim 8 , where the vulcanizable composition further comprises from about 0.1 parts by weight to about 20 parts by weight alumina trihydrate, based upon one hundred parts by weight rubber.

10. The air bellow of claim 8 , where the composition further comprises from about 20 parts by weight to about 100 parts by weight clay, based upon one hundred parts by weight rubber.

11. The air bellow of claim 8 , where the composition further comprises carbon black.

12. The air bellow of claim 8 , where the composition further comprises silica.

13. The air bellow of claim 8 , where the composition further comprises factice.

14. The air bellow of claim 8 , where the composition further comprises one or more plasticizers.

15. The air bellow of claim 8 , where the composition further comprises one or more homogenizing agents.

16. The air bellow of claim 8 , where the composition further comprises one or more antioxidants.

17. The air bellow of claim 8 , where the composition further comprises zinc oxide.

18. The air bellow of claim 8 , where the composition further comprises one or more tackifiers.

19. An air spring having an airsleeve, wherein at least one layer of said airsleeve includes the vulcanization product of a composition that includes:
(i) at least one vulcanizable polymer that is selected from the group consisting of polychloroprene, polychloroprene copolymers, natural rubber, blends of natural rubber and a diene polymer, and combinations thereof;
(ii) a curative;
(iii) at least one halogenated hydrocarbon wax; and
(iv) expandable graphite, where the total amount of vulcanizable polymer is from about 25 to about 40 wt %, based upon the total weight of the composition.

Assignees

• Firestone Ind Products Co Llc

Inventors

• Howard Michael C
• Adcock Brandon C
• Li Hang

Classifications

• C08L11/00 Primary

  Compositions of homopolymers or copolymers of chloroprene · CPC title

• F16F9/04

  in a chamber with a flexible wall {(producing hollow articles of plastics, e.g. air bellows, B29D22/00)} · CPC title

• C08K2003/2227

  of aluminium · CPC title

• F16F9/0409 Primary

  characterised by the wall structure · CPC title

• C08K3/346

  Clay · CPC title