Sequestering carbon dioxide into precursors of bendable engineered cementitious composites

Patent metadata

Field	Value
Publication number	US-11708303-B2
Application number	US-202117912727-A
Country	US
Kind code	B2
Filing date	Mar 17, 2021
Priority date	Mar 20, 2020
Publication date	Jul 25, 2023
Grant date	Jul 25, 2023

Abstract

Methods of preparing engineered cementitious composite precursors include carbonating a fly ash comprising >about 25% by weight of calcium oxide (CaO) and having a water content of >about 12% to <about 18% by weight of water by exposing the fly ash to a first gas stream comprising carbon dioxide to form a carbonated fly ash. A steel slag is also carbonated that comprises >about 40% by weight of calcium oxide (CaO) and having a water content of >about 12% to <about 18% by weight of water by exposing the steel slag to a second gas stream comprising carbon dioxide to form a carbonated steel slag. The carbonated fly ash and the carbonated steel slag are suitable for use as engineered cementitious composite precursors in a bendable engineered cementitious composite composition that further comprises Portland cement, a polymeric fiber, and a superplasticizer.

First claim

What is claimed is:

1. A method of preparing engineered cementitious composite precursors comprising:
carbonating a fly ash comprising greater than or equal to about 25% by weight of calcium oxide (CaO) and having a water content of greater than or equal to about 12% to less than or equal to about 18% by weight of water by exposing the fly ash to a first gas stream comprising carbon dioxide, so that the fly ash has greater than or equal to about 4% by weight of carbon dioxide uptake on a dry basis to form a carbonated fly ash; and
carbonating a steel slag comprising greater than or equal to about 40% by weight of calcium oxide (CaO) and having a water content of greater than or equal to about 12% to less than or equal to about 18% by weight of water by exposing the steel slag to a second gas stream comprising carbon dioxide, so that the steel slag has greater than or equal to about 5% by weight of carbon dioxide uptake on a dry basis to form a carbonated steel slag; wherein the carbonated fly ash and the carbonated steel slag are suitable for use as engineered cementitious composite precursors in an engineered cementitious composite composition that further comprises Portland cement, a polymeric fiber, and a superplasticizer.

2. The method of claim 1 , wherein the carbonating the fly ash occurs until the fly ash has greater than or equal to about 6% by weight of carbon dioxide uptake in the carbonated fly ash and the carbonating the steel slag occurs until the steel slag has greater than or equal to about 8% by weight of carbon dioxide uptake on a dry basis in the carbonated steel slag.

3. The method of claim 1 , further comprising prior to the carbonating the fly ash, introducing water into the fly ash to provide the water content of greater than or equal to about 12% to less than or equal to about 18% by weight of water.

4. The method of claim 3 , wherein after the carbonating the fly ash, the carbonated fly ash is dried so that it has a water content of less than or equal to about 0.5% by weight.

5. The method of claim 4 , further comprising milling the carbonated fly ash.

6. The method of claim 5 , wherein after the milling, the carbonated fly ash has an average particle size of less than or equal to about 30 μm.

7. The method of claim 1 , further comprising prior to the carbonating the steel slag, sieving the steel slag so that steel slag subjected to the carbonating has an average particle size of less than or equal to about 220 μm.

8. The method of claim 1 , further comprising prior to the carbonating steel slag, measuring a water content of the steel slag and adjusting the water content to be greater than or equal to about 12% to less than or equal to about 18% by weight of water.

9. The method of claim 1 , wherein the steel slag further comprises greater than or equal to about 10% to less than or equal to about 35% by weight silicon dioxide (SiO 2 ), less than or equal to about 15% by weight of aluminum oxide (Al 2 O 3 ), less than or equal to about 15% by weight magnesium oxide (MgO), less than or equal to about 35% by weight iron oxide (Fe 2 O 3 ), and less than or equal to about 5% by weight of sulfur oxide (SO 3 ).

10. The method of claim 1 , wherein the fly ash further comprises greater than or equal to about 20% to less than or equal to about 40% by weight silicon dioxide (SiO 2 ), less than or equal to about 20% by weight of aluminum oxide (Al 2 O 3 ), less than or equal to about 10% by weight magnesium oxide (MgO), less than or equal to about 10% by weight iron oxide (Fe 2 O 3 ), and less than or equal to about 5% by weight of sulfur oxide (SO 3 ).

11. The method of claim 1 , wherein at least one of the first gas stream and the second gas stream are generated by an industrial source.

12. A method of preparing engineered cementitious composite comprising:
mixing a carbonated fly ash having greater than or equal to about 6% by weight of carbon dioxide uptake on a dry basis, a carbonated steel slag having greater than or equal to about 8% by weight of carbon dioxide uptake on a dry basis, Portland cement, at least one polymeric fiber, a superplasticizer, and water together to form an admixture that hydrates and forms the engineered cementitious composite having a tensile strain capacity of greater than or equal to about 2% and a uniaxial tensile strength of greater than or equal to about 1 MPa.

13. The method of claim 12 , wherein the engineered cementitious composite has an autogenous crack width of less than or equal to about 100 μm.

14. The method of claim 12 , wherein the uniaxial tensile strength is greater than or equal to about 3 MPa.

15. The method of claim 12 , wherein the engineered cementitious composite contains only the carbonated steel slag as an aggregate.

16. The method of claim 12 , wherein the engineered cementitious composite comprises greater than 0 to less than or equal to about 4 volume % of the at least one polymeric fiber.

17. The method of claim 12 , wherein the engineered cementitious composite comprises the carbonated fly ash and the Portland cement as cementitious binders, wherein the engineered cementitious composite comprises greater than or equal to about 40 weight % to less than or equal to about 75 weight % of the carbonated fly ash and greater 25 weight % to less than or equal to about 60 weight % Portland cement.

18. The method of claim 12 , wherein the admixture comprises the Portland cement at a mass ratio of about 1, the carbonated fly ash at a mass ratio of greater than or equal to about 1.2 to less than or equal to about 2.2, the carbonated steel slag at a mass ratio of greater than or equal to about 0.8 to less than or equal to about 1.2, water at a mass ratio of greater than or equal to about 0.58 to less than or equal to about 0.8, and the superplasticizer at a mass ratio of greater than or equal to about 0.007 to less than or equal to about 0.015.

Assignees

• Univ Michigan Regents

Inventors

• Li Victor C
• Ellis Brian R
• Zhang Duo

Classifications

• C04B2111/00019

  Carbon dioxide sequestration · CPC title

• C04B2111/00017

  Aspects relating to the protection of the environment · CPC title

• C04B18/08 Primary

  Flue dust {, i.e. fly ash} · CPC title

• C04B7/367

  Avoiding or minimising carbon dioxide emissions · CPC title

• C04B16/06

  fibrous · CPC title