Curing systems for materials that consume carbon dioxide and method of use thereof

Patent metadata

Field	Value
Publication number	US-10016739-B2
Application number	US-201514757786-A
Country	US
Kind code	B2
Filing date	Dec 28, 2015
Priority date	Mar 14, 2013
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

The invention provides a curing system that is useful for curing materials that consume carbon dioxide as a reagent. The system has a curing chamber that contains the material to be cured and a gas that contains carbon dioxide. The system includes apparatus that can deliver carbon dioxide to displace ambient air upon loading the system, that can provide carbon dioxide as it is needed and as it is consumed, that can control carbon dioxide concentration, temperature and humidity in the curing chamber during the curing cycle and that can record and display to a user the variables that occur during the curing process. A method of curing a material which requires CO 2 as a curing reagent is also described.

First claim

What is claimed is:

1. A method of curing a material which requires CO 2 as a curing reagent, comprising the steps of:
providing an apparatus comprising:
a curing chamber configured to contain a material that consumes CO 2 as a reagent and that does not cure in the absence of CO 2 during curing, said curing chamber having at least one port configured to allow said material to be introduced into said curing chamber and to be removed from said curing chamber, and having at least one closure for said port, said closure configured to provide an atmospheric seal when closed so as to prevent contamination of a gas present in said curing chamber by gas outside said curing chamber;
a source of carbon dioxide configured to provide gaseous carbon dioxide to said curing chamber by way of a gas entry port in said curing chamber, said source of carbon dioxide having at least one flow regulation device configured to control a flow rate of said gaseous carbon dioxide into said curing chamber;
a gas flow subsystem configured to circulate said gas through said curing chamber during a time period when said material that consumes CO 2 as a reagent is being cured;
a temperature control subsystem configured to control a temperature of said gas within said chamber;
a humidity control subsystem configured to control a humidity in said gas within said chamber; and
at least one controller in communication with at least one of said source of carbon dioxide, said gas flow subsystem, said temperature control subsystem, and said humidity control subsystem, said at least one controller configured to control independently during a time period when said material that consumes CO 2 as a reagent is being cured at least a respective one of said flow rate of said gaseous carbon dioxide, said circulation of said gas through said curing chamber, said temperature of said gas, and said humidity in said gas;

placing a green ceramic body comprising said material that consumes CO 2 as a reagent and that does not cure in the absence of CO 2 during curing into said curing chamber by way of said at least one port configured to allow said material to be introduced into said curing chamber and to be removed from said curing chamber;
closing said at least one port by operating said closure; and
providing an atmosphere comprising CO 2 within said curing chamber for a period of time sufficient to cure said green ceramic body.

2. The method of curing of claim 1 , wherein said curing chamber is configured to contain a pressure of gas therein that is above atmospheric pressure.

3. The method of curing of claim 1 , wherein said at least one flow regulation device comprises at least one of a pressure regulator and a flow controller configured to supply carbon dioxide gas at a rate substantially equal to a rate of consumption of said carbon dioxide by said material that consumes CO 2 as a reagent during curing.

4. The method of curing of claim 1 , wherein said at least one flow regulation device comprises at least one of a pressure regulator and a flow controller configured to supply carbon dioxide gas at a rate sufficient to purge ambient atmosphere from said curing chamber in a time period between 2-120 minutes to achieve a target CO 2 concentration in a range of 50-90% by volume.

5. The method of curing of claim 1 , wherein said at least one flow regulation device comprises at least one of a pressure regulator and a flow controller configured to supply carbon dioxide gas at a rate substantially equal to a rate of venting of said gas from said curing chamber.

6. The method of curing of claim 1 , wherein said gas flow subsystem includes a measurement apparatus configured to measure an amount of carbon dioxide in said gas present in said curing chamber.

7. The method of curing of claim 1 , wherein said gas flow subsystem includes a measurement apparatus configured to measure a gas velocity of said gas present in said curing chamber.

8. The method of curing of claim 7 , wherein said measurement apparatus configured to measure a gas velocity is a selected one of a pitot tube, an orifice plate, an anemometer, and a laser Doppler detection system.

9. The method of curing of claim 1 , wherein said gas flow subsystem includes a variable speed blower configured to circulate gas at a desired velocity in said curing chamber.

10. The method of curing of claim 1 , wherein said temperature control subsystem includes a temperature sensor configured to measure said temperature of said gas in said curing chamber.

11. The method of curing of claim 1 , wherein said temperature control subsystem includes a heat exchanger to regulate said temperature of said gas in said curing chamber.

12. The method of curing of claim 1 , wherein said temperature control subsystem includes a heat exchanger to control a temperature of said gaseous carbon dioxide provided to said curing chamber by way of said gas entry port in said curing chamber.

13. The method of curing of claim 1 , wherein said humidity control subsystem includes a measurement apparatus configured to determine a relative humidity of said gas within said chamber.

14. The method of curing of claim 1 , wherein said humidity control subsystem includes at least one of a condenser and an exhaust valve configured to reduce said humidity in said gas within said chamber.

15. The method of curing of claim 1 , wherein said humidity control subsystem includes a water supply configured to increase said humidity in said gas within said chamber.

16. The method of curing of claim 1 , wherein said at least one controller is a selected one of a programmable logic controller, a controller having a touch screen display, and a general purpose programmable computer that operates under the control of a set of instructions recorded on a machine-readable medium.

17. The method of curing of claim 1 , wherein said at least one controller includes a display configured to display to a user any of a duration of a curing cycle, said flow rate of said gaseous carbon dioxide, a concentration of carbon dioxide in said curing chamber, a rate of circulation of said gas through said curing chamber, said temperature of said gas, and said humidity in said gas.

18. The method of curing of claim 1 , wherein said at least one controller is configured to record any of a duration of a curing cycle, said flow rate of said gaseous carbon dioxide, a concentration of carbon dioxide in said curing chamber, a rate of circulation of said gas through said curing chamber, said temperature of said gas, and said humidity in said gas.

19. The method of curing of claim 1 , further comprising the step of providing a pre carbon dioxide dwell period.

20. The method of curing of claim 19 , wherein during said pre carbon dioxide dwell period parameters within said curing chamber are controlled.

Assignees

• Solidia Technologies Inc

Inventors

• Kuppler John P
• Atakan Vahit
• Smith Kenneth
• Hu Xudong

Classifications

• B28B11/245 Primary

  Curing concrete articles (B28B11/242 takes precedence) · CPC title

• B28B11/247

  Controlling the humidity during curing, setting or hardening · CPC title

• C04B40/02

  Selection of the hardening environment · CPC title

• F27B5/04

  adapted for treating the charge in vacuum or special atmosphere · CPC title

• C04B28/188

  the Ca-silicates being present in the starting mixture · CPC title