Powder, method of producing powder and adsorption apparatus

Patent metadata

Field	Value
Publication number	US-11701633-B2
Application number	US-202117474356-A
Country	US
Kind code	B2
Filing date	Sep 14, 2021
Priority date	Sep 28, 2009
Publication date	Jul 18, 2023
Grant date	Jul 18, 2023

Abstract

The present invention provides that powder is mainly constituted from secondary particles of hydroxyapatite. The secondary particles are obtained by drying a slurry containing primary particles of hydroxyapatite and aggregates thereof and granulating the primary particles and the aggregates. A bulk density of the powder is 0.65 g/mL or more and a specific surface area of the secondary particles is 70 m2/g or more. The powder of the present invention has high strength and is capable of exhibiting superior adsorption capability when it is used for an adsorbent an adsorption apparatus has.

First claim

What is claimed is:

1. A powder comprising mainly hydroxyapatite,
wherein the powder is obtained by preparing a slurry containing primary particles of the hydroxyapatite and aggregates thereof, physically crushing the aggregates in the slurry, drying the slurry containing the primary particles of the hydroxyapatite and the crushed aggregates thereof, granulating the dried slurry to obtain granulated particles and sintering the granulated particles at a sintering temperature,
wherein the physically crushing is performed such that the powder has a repose angle of about 22° to about 27°, and
wherein the powder has a bulk density of about 0.65 g/mL or more and a specific surface area of about 25 m 2 /g to about 52 m 2 /g.

2. A powder comprising mainly hydroxyapatite,
wherein the powder is obtained by preparing a slurry containing primary particles of the hydroxyapatite and aggregates thereof, physically crushing the aggregates in the slurry, drying the slurry containing the primary particles of the hydroxyapatite and the crushed aggregates thereof, granulating the dried slurry to obtain granulated particles and sintering the granulated particles at a sintering temperature,
wherein the physically crushing is performed such that the powder has a sphericity of about 0.97 to about 1.00, and
wherein the powder has a bulk density of about 0.65 g/mL or more and a specific surface area of about 25 m 2 /g to about 52 m 2 /g.

3. The powder as claimed in claim 2 ,
wherein the physically crushing is performed such that the powder has a repose angle of about 22° to about 27°.

4. The powder as claimed in claim 1 , wherein when the repose angle is measured, the powder is classified so as to have an average particle size of 40±4 μm.

5. The powder as claimed in claim 1 , wherein the physically crushing is performed such that the powder has a sphericity of about 0.97 to about 1.00.

6. The powder as claimed in claim 1 ,
wherein the sintering temperature is in the range of about 200° C. to 900° C.

7. The powder as claimed in claim 1 ,
wherein the physically crushing is performed such that the powder has a specific surface area of about 1.2 to about 1.4 times larger than those of particles of the dried powder and the sintered powders obtained without said physically crushing of the aggregates in the slurry.

8. An adsorption apparatus provided with the powder defined in claim 1 as an adsorbent.

9. The powder as claimed in claim 3 , wherein when the repose angle is measured, the powder is classified so as to have an average particle size of 40±4 μm.

10. The powder as claimed in claim 2 ,
wherein the sintering temperature is in the range of about 200° C. to 900° C.

11. The powder as claimed in claim 2 ,
wherein the physically crushing is performed such that the powder has a specific surface area of about 1.2 to about 1.4 times larger than those of particles of the dried powder and the sintered powders obtained without said physically crushing of the aggregates in the slurry.

12. An adsorption apparatus provided with the powder defined in claim 2 as an adsorbent.

Assignees

• Hoya Corp

Inventors

• Kobayashi Shintaro

Classifications

• B01J20/048 Primary

  containing phosphorus, e.g. phosphates, apatites, hydroxyapatites · CPC title

• B01J20/281

  Sorbents specially adapted for preparative, analytical or investigative chromatography · CPC title

• B01J20/282

  Porous sorbents (ion exchange B01J39/00 - B01J41/00) · CPC title

• B01J20/2803

  Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products · CPC title

• B01J20/28004

  Sorbent size or size distribution, e.g. particle size · CPC title