Application of water requirement measurements to approximate specific surface area

Patent metadata

Field	Value
Publication number	US-11685078-B2
Application number	US-201716479056-A
Country	US
Kind code	B2
Filing date	Feb 22, 2017
Priority date	Feb 22, 2017
Publication date	Jun 27, 2023
Grant date	Jun 27, 2023

Abstract

Methods of wellbore cementing are provided. A method of analyzing a solid particulate including: measuring a water requirement of the solid particulate; and determining an approximation of specific surface area of the solid particulate from the water requirement.

First claim

What is claimed is:

1. A method of designing a cement composition based on analyzing a solid particulate comprising:
measuring a water requirement of the solid particulate, wherein the measuring of the water requirement comprises measuring a consistency of an agitated mixture of water and the solid particulate and calculating the water requirement based on a ratio of an amount of water to an amount of solid particulate required to obtain a specified consistency;
determining an approximation of specific surface area of the solid particulate from the water requirement;
estimating a reactivity of the solid particulate based on the measured water requirement of the solid particulate and the determination of specific surface area of the solid particulate;
designing the cement composition based on the estimated reactivity of the solid particulate;
preparing the cement composition; and
allowing the cement composition to cure to form a hardened mass.

2. The method of claim 1 wherein the water requirement is a weight ratio of water to the solid particulate required to obtain a predetermined consistency.

3. The method of claim 1 wherein the measuring the water requirement comprises preparing a blender with a specified amount of water, agitating the blender at a specified blender speed, adding the solid particulate to the water until a predetermined consistency is obtained, and calculating the water requirement based on a weight ratio of the water to the solid particulate to obtain the predetermined consistency.

4. The method of claim 3 wherein the specified consistency is obtained when a vortex formed at a surface in the blender is about 0 mm to about 50 mm in diameter while mixing the solid particulate and the water.

5. The method of claim 1 wherein the determining an approximation of specific surface area comprises inputting the water requirement into an equation to obtain an output of the approximation of the specific surface area.

6. The method of claim 1 wherein the solid particulate comprises a silica source that is alkali soluble.

7. The method of claim 1 wherein the solid particulate comprises at least one silica source selected from the group consisting of fly ash, slag, silica fume, crystalline silica, silica flour, cement kiln dust, volcanic rock, perlite, metakaolin, diatomaceous earth, zeolite, shale, agricultural waste ash, rice husk ash, sugar cane ash, Portland cement, bagasse ash, and combinations thereof.

8. The method of claim 1 further comprising measuring at least one additional property for the solid particulate selected from the group consisting of compressive strength, Young's modulus, and tensile strength.

9. The method of claim 1 further comprising including the solid particulate in a cement composition and allowing the cement composition to set.

10. The method of claim 1 , wherein the agitated mixture comprises between 100 grams and 500 grams of water, wherein the agitated mixture is agitated in a blender at an rpm between 4,000 and 15,000, wherein the agitated mixture comprises between 1 gram and 1,000 grams of the solid particulate, wherein the measuring of the consistency of the agitated mixture comprises observing a vortex formed at a surface of the agitated mixture, wherein the vortex has a size between 0.1 millimeters and 25 millimeters.

11. A method of cementing comprising:
measuring a water requirement of a solid particulate, wherein the measuring of the water requirement comprises measuring a consistency of an agitated mixture of water and the solid particulate and calculating the water requirement based on a ratio of an amount of water to an amount of solid particulate required to obtain a specified consistency;
determining an approximation of specific surface area of the solid particulate from the water requirement;
correlating a reactivity of the solid particulate to the water requirement and the specific surface area of the solid particulate giving an estimated reactivity of the solid particulate;
designing a cement composition based on the estimated reactivity of the solid particulate;
determining an approximation of compressive strength for the cement composition comprising the solid particulate;
preparing the cement composition, wherein the cement composition comprises the solid particulate, one or more additional solid particulates, and water; and
allowing the cement composition to set in a predetermined location.

12. The method of claim 11 further comprising introducing the cement composition into a wellbore.

13. The method of claim 11 wherein the cement composition is used in primary cementing to form a set cement sheath in a wellbore annulus.

14. The method of claim 11 wherein preparing the cement composition comprises mixing components of the cement composition using mixing equipment, the components comprising the solid particulate, the one or more additional solid particulates, and the water.

15. The method of claim 11 wherein the water requirement is a ratio of weight of water to weight of the solid particulate required to obtain a predetermined consistency.

16. The method of claim 11 wherein the measuring the water requirement comprises preparing a blender with a specified amount of water, agitating the blender at a specified blender rpm, adding the solid particulate to the water until a specified consistency is obtained, and calculating the water requirement based on a weight ratio of the water to the solid particulate to obtain the specified consistency.

17. The method of claim 11 wherein the determining an approximation of specific surface area comprises inputting the water requirement into an equation to obtain an output of the approximation of the specific surface area.

18. The method of claim 11 wherein the solid particulate comprises at least one silica source selected from the group consisting of fly ash, slag, silica fume, crystalline silica, silica flour, cement kiln dust, volcanic rock, perlite, metakaolin, diatomaceous earth, zeolite, shale, agricultural waste ash, rice husk ash, sugar cane ash, bagasse ash, and combinations thereof.

19. The method of claim 11 further comprising measuring at least one additional property for the solid particulate selected from the group consisting of compressive strength, Young's modulus, and tensile strength and determining a reactive index for the solid particulate based on the approximation of specific surface area.

20. A system comprising:
a solid particulate;
a blender configured to mix the solid particulate with water;
an analytical equipment configured to measure a water requirement of the solid particulate; and
a computer system configured to accept inputs of a water requirement for the solid particulate, wherein the water requirement is determined based on a ratio of an amount of water to an amount of solid particulate required to obtain a specified consistency, output an approximation of specific surface area and reactivity of the solid particulate, and design a cement which includes the solid particulate based in part on the approximation of the specific surface area and the reactivity of the solid particulate.

21. The system of claim 20 wherein the computer system is configured to input the water requirement into an equation to obtain the output of the approximation of specific surface area.

22. The system of claim 20 wherein the water requirement is a ratio of weight of water to weight of the solid particulate required to obtain a predetermined consist

Assignees

• Halliburton Energy Services Inc

Inventors

• Morgan Ronnie Glen
• Pisklak Thomas Jason
• Riggio Sean William
• Lewis Samuel J

Classifications

• B28C9/004

  Making slurries, e.g. with discharging means for injecting in a well or projecting against a wall · CPC title

• E21B33/13 Primary

  Methods or devices for cementing, for plugging holes, crevices or the like · CPC title

• C04B40/0032

  Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value (B28C7/00 takes precedence) · CPC title

• C09K8/46 Primary

  containing inorganic binders, e.g. Portland cement · CPC title

• B28C7/024 Primary

  by measuring properties of the mixture, e.g. moisture, electrical resistivity, density · CPC title