Metal-air battery and method of manufacturing the metal-air battery

Patent metadata

Field	Value
Publication number	US-11677112-B2
Application number	US-202017017913-A
Country	US
Kind code	B2
Filing date	Sep 11, 2020
Priority date	Nov 29, 2019
Publication date	Jun 13, 2023
Grant date	Jun 13, 2023

Abstract

A metal-air battery includes an anode layer including a metal, a cathode layer including an electrically conductive metal oxide, a solid electrolyte layer between the anode layer and the cathode layer, and a bonding layer including a metal, where the bonding layer is disposed between the cathode layer and the solid electrolyte layer.

First claim

What is claimed is:

1. A metal-air battery comprising:
an anode layer comprising a metal;
a cathode layer comprising an electrically conductive metal oxide;
a solid electrolyte layer between the anode layer and the cathode layer; and
a bonding layer having a melting point lower than a melting point of the electrically conductive metal oxide, disposed between the cathode layer and the solid electrolyte layer, and bonding the cathode layer to the solid electrolyte layer,
wherein the bonding layer comprises at least one of Pt, Au, Mn, Co, Ni, Cr, V, Fe, Pb, or Sn, and
wherein a thickness of the bonding layer is about 10 nanometers or less.

2. The metal-air battery of claim 1 , wherein the electrically conductive metal oxide is at least one of RuO 2 , indium tin oxide, IrO 2 , OsO 2 , RhO 2 , Ce x O y wherein 0<x≤2 and 0<y≤3, W x O y wherein 0<x≤2 and 0<y≤3, NbO, Eu 2 O 3 , Ti x O y wherein 0<x≤2 and 0<y≤3, Mn 2 O 3 , or PbO 2 .

3. The metal-air battery of claim 1 , wherein the cathode layer is porous.

4. The metal-air battery of claim 3 , wherein a porosity of the cathode layer is about 90 volume percent or less, based on a total volume of the cathode layer.

5. The metal-air battery of claim 3 , wherein a specific surface area of the cathode layer is about 1 square meter per gram or more, based on a total specific surface area of the cathode layer.

6. The metal-air battery of claim 1 , wherein the solid electrolyte layer comprises at least one compound having a NASICON structure, a garnet structure, or a perovskite structure.

7. The metal-air battery of claim 6 , wherein the compound is at least one of Li 1+a Al a Ti 2−a (PO 4 ) 3 wherein 0≤a≤1, Li a La 3 Zr 2 O 12 wherein 5≤a≤9, or La 0.55 Li 0.35 TiO 3 .

8. The metal-air battery of claim 1 , further comprising:
a gas diffusion layer on at least one surface of the cathode layer.

9. The metal-air battery of claim 1 , wherein the cathode layer does not comprise an organic electrolyte.

10. A method of manufacturing a metal-air battery of claim 1 , the method comprising:
providing the solid electrolyte layer;
coating a surface of the solid electrolyte layer with the bonding layer;
disposing the cathode layer comprising the electrically conductive metal oxide on a surface of the bonding layer;
heat-treating the solid electrolyte layer comprising the bonding layer and the cathode layer; and
disposing the anode layer comprising the metal on a surface of the solid electrolyte layer to manufacture the metal-air battery.

11. The method of claim 10 , wherein the cathode layer comprises the electrically conductive metal oxide and a binder.

12. The method of claim 11 , wherein the heat-treating comprises heat-treating at a temperature of about 500° C. to about 800° C.

13. The method of claim 12 , wherein, the heat-treating bonds the electrically conductive metal oxide to the bonding layer.

14. The method of claim 10 , wherein the cathode layer is in the shape of a plate.

15. The method of claim 10 , wherein the electrically conductive metal oxide comprises at least one of RuO 2 , InSnO, IrO, OsO 2 , RhO 2 , Ce x O y wherein 0≤x≤2 and 0≤y≤3, W x O y wherein 0≤x≤2 and 0≤y≤3, NbO, Eu 2 O 3 , Ti x O y wherein 0≤x≤2 and 0≤y≤3, Mn 2 O 3 , or PbO 2 .

16. The method of claim 10 , wherein the solid electrolyte layer comprises at least one compound having a NASICON structure, a garnet structure, or a perovskite structure.

17. The method of claim 16 , wherein the compound is at least one of Li 1+a Al a Ti 2−a (PO 4 ) 3 wherein 0≤a≤1, Li a La 3 Zr 2 O 12 wherein 5≤a≤9, or La 0.55 Li 0.35 TiO 3 .

18. The method of claim 10 , further comprising:
disposing a gas diffusion layer on at least one surface of the cathode layer.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Choi Wonsung
• Kim Hyunjin
• Choi Kyounghwan

Classifications

• H01M10/0562

  Solid materials · CPC title

• H01M4/8605

  Porous electrodes · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M4/8668

  Binders · CPC title