Electrolytes for magnesium-ion batteries
US-2016294010-A1 · Oct 6, 2016 · US
US11658296B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11658296-B2 |
| Application number | US-201816955024-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 18, 2018 |
| Priority date | Dec 18, 2017 |
| Publication date | May 23, 2023 |
| Grant date | May 23, 2023 |
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Use of nickel in a cathode material of the general formula Li (4/3-2x/3-y/3-z/3)Ni x Co y Al z Mn(2/3- x /3-2 y /3-2 z /3)0 2 wherein x is greater than 0.06 and equal to or less than 0.4; y is equal to or greater than 0 and equal to or less than 0.4; and z is equal to or greater than 0 and equal to or less than 0.05 for suppressing gas evolution during a charge cycle and/or increasing the charge capacity of the material.
Opening claim text (preview).
The invention claimed is: 1. A method comprising: suppressing gas evolution from a cathode material during a charge cycle by incorporating a nickel doped lithium rich cathode material of the general formula: Li ( 4 3 - 2 x 3 - y 3 - z 3 ) Ni x Co y Al z Mn ( 2 3 - x 3 - 2 y 3 - 2 z 3 ) O 2 wherein the cathode material is selected from one of Li 1.15 Co 0.15 Ni 0.2 Mn 0.5 O 2 Li 1.15 Ni 0.2 Co 0.1 Al 0.05 Mn 0.5 O 2 , or Li 1.1333 Ni 0.2 Co 0.15 Al 0.05 Mn 0.4667 O 2 . 2. The method of claim 1 , wherein the gas is at least one of molecular oxygen and carbon dioxide. 3. A method comprising: suppressing gas evolution from a cathode material during a charge cycle by incorporating a nickel doped lithium rich cathode material of the general formula: Li ( 4 3 - 2 x 3 ) Ni x Mn ( 2 3 - x 3 ) O 2 wherein x is equal to or greater than 0.06 and equal to or less than 0.12. 4. A method comprising: suppressing gas evolution from a cathode material during a charge cycle by incorporating a nickel doped lithium rich cathode material, wherein the cathode material is Li 1.066 Ni 0.4 Mn 0.533 O 2 . 5. The method of claim 3 , wherein the gas is at least one of molecular oxygen and carbon dioxide. 6. The method of claim 4 , wherein the gas is at least one of molecular oxygen and carbon dioxide. 7. A method comprising: increasing the charge capacity of a cathode material by incorporating a nickel doped lithium rich cathode material of the general formula: Li ( 4 3 - 2 x 3 - y 3 - z 3 ) Ni x Co y Al z Mn ( 2 3 - x 3 - 2 y 3 - 2 z 3 ) O 2 wherein the cathode material is selected from one of Li 1.15 Co 0.15 Ni 0.2 Mn 0.5 O 2 Li 1.15 Ni 0.2 Co 0.1 Al 0.05 Mn 0.5 O 2 , or Li 1.1333 Ni 0.2 Co 0.15 Al 0.05 Mn 0.4667 O 2 . 8. A method comprising: increasing the charge capacity of a cathode material by incorporating a nickel doped lithium rich cathode material of the general formula: Li ( 4 3 - 2 x 3 ) Ni x Mn ( 2 3
by unit-cell parameters, atom positions or structure diagrams · CPC title
of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title
Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title
Two-dimensional structures · CPC title
of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title
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