High energy density battery based on complex hydrides

Patent metadata

Field	Value
Publication number	US-9325030-B2
Application number	US-201213629753-A
Country	US
Kind code	B2
Filing date	Sep 28, 2012
Priority date	Sep 28, 2012
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

A battery and process of operating a battery system is provided using high hydrogen capacity complex hydrides in an organic non-aqueous solvent that allows the transport of hydride ions such as AlH 4 − and metal ions during respective discharging and charging steps.

First claim

What is claimed is:

1. A complex hydride battery comprising:
a cathode comprising a metal hydride according to the formula (MH x ) where M is a metal and X further represents an oxidation state of the metal;
an anode comprising a lithium metal; and
an electrolyte comprising a complex hydride, the complex hydride is selected from the group consisting of LiAlH 4 , NaAlH 4 , KAlH 4 , Ca(AlH 4 ) 2 , Mg(AlH 4 ) 2 , LiBH 4 , and NaBH 4 , dissolved in an organic solvent selected from the group consisting of THF, ethers, amines and mixtures thereof to allow for the transport of the complex hydride's corresponding hydride ions selected from the group consisting of AlH 4 ions and BH 4 ions.

2. A complex hydride battery comprising:
a cathode comprising a metal hydride according to the formula (MH x ) where M is a metal and X further represents an oxidation state of the metal;
an anode comprising a lithium metal; and
an electrolyte comprising a compressed complex hydride powder positioned between the anode and the cathode, the complex hydride is selected from the group consisting of LiAlH 4 and LiBH 4 , to allow for the transport of the complex hydride's corresponding hydride ions selected from the group consisting of AlH 4 ions and BH 4 ions.

3. A process for charging and discharging a battery comprising the steps of:
providing a complex hydride battery having:
a cathode comprising a metal hydride according to the formula (MH x ) where M is a metal and X further represents an oxidation state of the metal;
an anode comprising a lithium metal; and
an electrolyte comprising a complex hydride, the complex hydride is selected from the group consisting of LiAlH 4 , NaAlH 4 , KAlH 4 , Ca(AlH 4 ) 2 , Mg(AlH 4 ) 2 , LiBH 4 , and NaBH 4 , dissolved in an organic solvent selected from the group consisting of THF ethers, amines and mixture thereof;
reducing metal ions to the metal during a charging step; and,
transporting a hydride ion, the hydride ion selected from the group consisting of a AlH 4 ion and a BH 4 ion, to the electrolyte and further reacting the hydride ion with the metal at the anode during a discharging step.

4. The complex hydride battery according to claim 1 wherein the organic solvent comprises a polar solvent.

5. The complex hydride battery according to claim 1 wherein the anode of the lithium metal is embedded in a conducting polymer.

6. The process of charging and discharging a battery according to claim 3 wherein the anode of the lithium metal is embedded in a conducting polymer.

7. The process of charging and discharging a battery according to claim 3 wherein the providing step further comprises choosing the complex hydride based on the voltage to be generated by the battery for a specific application.

Assignees

• Zidan Ragaiy
• Savannah River Nuclear Solutions Llc

Inventors

• Zidan Ragaiy

Classifications

• H01M4/58

  of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates · CPC title

• H02J7/007

  Electricity · mapped topic

• H01M10/052 Primary

  Li-accumulators · CPC title

• H01M10/26

  Selection of materials as electrolytes · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title